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    EPOXY NOVOLAC RESINS HAVING REDUCED 2-FUNCTIONAL COMPONENTS AND A PROCESS FOR REDUCING 2-FUNCTIONAL COMPONENTS IN NOVOLAC RESINS
    261.
    发明申请
    EPOXY NOVOLAC RESINS HAVING REDUCED 2-FUNCTIONAL COMPONENTS AND A PROCESS FOR REDUCING 2-FUNCTIONAL COMPONENTS IN NOVOLAC RESINS 审中-公开
    具有还原性的2-官能组分的环氧基NOVOLAC树脂和用于还原NOVOLAC树脂中2-官能组分的方法

    公开(公告)号：WO1986004075A1

    公开(公告)日：1986-07-17

    申请号：PCT/US1986000052

    申请日：1986-01-13

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  BERTRAM, James, L. ,  WALKER, Louis, L. ,  MCCRARY, Avis, L. ,  CORTEZ, Fermin, M.

    IPC: C08L63/04

    CPC classification number: C08G59/621 ,  C08G8/08 ,  C08G59/08 ,  C08G59/3218

    Abstract: Epoxy novolac resins having reduced 2-functional components and a process for reducing 2-functional components in novolac resin which may be used to prepare the epoxy novolac resins. When 2-functional and 3-functional components are present in an epoxy phenol-formaldehyde novolac resin, the weight ratio of the 2-functional component to the 3-functional component is less than 1.1:1. When 2-functional and 3-functional components are present in an epoxy cresol-formaldehyde novolac resin, the weight ratio of the 2-functional component to the 3-functional component is less than 0.5:1. The epoxy novolac resins of this invention when cured exhibit increased glass transition temperature. These resins are useful in the preparation of composites, molding, castings, coating, adhesives and laminates.

    Abstract translation: 具有降低的2-功能组分的环氧酚醛清漆树脂和可用于制备环氧酚醛清漆树脂的酚醛清漆树脂中2-官能组分的还原方法。 当环氧苯酚 - 甲醛酚醛清漆树脂中存在2-官能和3-官能组分时，2-官能组分与3-官能组分的重量比小于1.1:1。 当环氧甲酚 - 甲醛酚醛清漆树脂中存在2-官能和3-官能组分时，2-官能组分与3-官能组分的重量比小于0.5:1。 本发明的环氧酚醛清漆树脂固化时玻璃化转变温度升高。 这些树脂可用于复合材料，模塑，铸件，涂料，粘合剂和层压材料的制备。

    A METHOD FOR DETERMINING THE MIXING RATIO OF TWO OR MORE COMPOSITIONS EMPLOYED TO PREPARE A POLYMER
    263.
    发明申请
    A METHOD FOR DETERMINING THE MIXING RATIO OF TWO OR MORE COMPOSITIONS EMPLOYED TO PREPARE A POLYMER 审中-公开
    一种确定用于制备聚合物的两种或多种组合物的混合比的方法

    公开(公告)号：WO1986001818A1

    公开(公告)日：1986-03-27

    申请号：PCT/US1984001494

    申请日：1984-09-20

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  HILLSHAFER, Douglas, K.

    IPC: C09K03/00

    CPC classification number: G01N33/442

    Abstract: The method comprises adding a separate tracer compounds to each composition, mixing the compositions to form a polymer, curing the polymer, extracting the tracer compounds from the cured polymer, analyzing the extracts for the tracer compounds, and calculating the mixing ratio of the compositions.

    Abstract translation: 该方法包括向每种组合物中加入单独的示踪剂化合物，混合组合物以形成聚合物，固化聚合物，从固化聚合物中提取示踪剂化合物，分析示踪剂化合物的提取物，以及计算组合物的混合比。

    AN ACTIVE HYDROGEN-CONTAINING COMPOSITION CONTAINING A DIALKANOL TERTIARY AMINE AND A PROCESS FOR PREPARING A POLYURETHANE FOAM
    264.
    发明申请
    AN ACTIVE HYDROGEN-CONTAINING COMPOSITION CONTAINING A DIALKANOL TERTIARY AMINE AND A PROCESS FOR PREPARING A POLYURETHANE FOAM 审中-公开
    含有二氢甘油酯胺的活性含氢组合物和制备聚氨酯泡沫的方法

    公开(公告)号：WO1986001522A1

    公开(公告)日：1986-03-13

    申请号：PCT/US1985001599

    申请日：1985-08-23

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  NICHOLS, Jerram, B.

    IPC: C08G18/32

    CPC classification number: C08G18/6535 ,  C08G18/3275 ,  C08G18/3287 ,  C08G18/329

    Abstract: Active hydrogen-containing composition and a process for preparing a polyurethane foam using said composition. The active hydrogen-containing composition comprises (a) at least one polyahl having at least three active hydrogens per molecule and which is not a dialkanol tertiary amine, (b) a minor amount of water, and (c) a dialkanol tertiary amine present in an amount sufficient to improve the flowability of a foaming reaction mixture prepared from the active hydrogen-containing composition and a polyisocyanate, characterized in that the isocyanate-reaction materials present in said active hydrogen-containing composition have an average functionality of at least 3.0. The compressive strength of rigid foams prepared by the process of this invention is generally equal or superior to rigid foams prepared by previously known compositions.

    Abstract translation: 含活性氢的组合物和使用所述组合物制备聚氨酯泡沫的方法。 活性含氢组合物包含（a）至少一种每分子具有至少三个活性氢的多烯烃，并且不是二烷醇叔胺，（b）少量的水，和（c）存在于 足以改善由含活性氢的组合物和多异氰酸酯制备的发泡反应混合物的流动性的量，其特征在于存在于所述含活性氢的组合物中的异氰酸酯反应材料的平均官能度为至少3.0。 通过本发明方法制备的刚性泡沫的抗压强度通常等于或优于先前已知组合物制备的刚性泡沫。

    COMPOSITIONS OF POLYEPOXIDE/POLYAMINE ADDUCTS AND BLOCKED ISOCYANATES
    267.
    发明申请
    COMPOSITIONS OF POLYEPOXIDE/POLYAMINE ADDUCTS AND BLOCKED ISOCYANATES 审中-公开
    聚氧化乙烯/聚氨基甲酸酯和阻塞异氰酸酯的组合物

    公开(公告)号：WO1986000630A1

    公开(公告)日：1986-01-30

    申请号：PCT/US1985000490

    申请日：1985-03-25

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  HICKNER, Richard, A. ,  CAVITT, Michael, B.

    IPC: C08L63/00

    CPC classification number: C08G18/807 ,  C08G18/584 ,  C08G18/643 ,  C08G18/8061

    Abstract: Automotive primer surfaces require fast cure times, resistance to chipping and lower volatile solvent contents due to environmental considerations. A coating composition capable of curring within 15 minutes which is suitably chip resistant and has acceptable higher solids levels has been formulated from (A) an adduct of (1) an epoxy resin having an average epoxide equivalent weight of from 140 to 1000 and (2) a polyamine having at least two primary and/or secondary amine groups, and (B) a substantially fully blocked polyisocyanate being blocked with ketoximes, aldoximes, lactams, N-hydroxy-imides or alcohols. The composition contains from 0.9 to 20 moles of polyamine per epoxide equivalent and from 0.75:1 to 2:1 ratios of latent NCO groups in component (B) per amine group in component (A). These formulations can additionally be employed as coil coatings and exterior coatings for beverage cans.

    Abstract translation: 由于环境考虑，汽车底漆表面需要快速固化时间，耐碎裂和挥发性溶剂含量较低。 由（A）平均环氧当量为140〜1000的环氧树脂和（2）的（2）的加合物配制能够在15分钟内卷曲的涂层组合物，该组合物适当地抗碎屑并具有可接受的较高固体含量 ）具有至少两个伯和/或仲胺基团的多胺，和（B）用酮肟，醛肟，内酰胺，N-羟基 - 酰亚胺或醇封闭的基本上完全封闭的多异氰酸酯。 该组合物含有每个环氧当量0.9至20摩尔多胺和组分（A）中每个胺基组分（B）中的潜在NCO基团的0.75:1至2:1的比例。 这些制剂还可以用作饮料罐的卷材涂层和外部涂层。

    HEAT INSULATING STRUCTURES FOR LOW-TEMPERATURE OR CRYOGENIC PIPINGS
    269.
    发明申请
    HEAT INSULATING STRUCTURES FOR LOW-TEMPERATURE OR CRYOGENIC PIPINGS 审中-公开
    用于低温或低温管道的热绝缘结构

    公开(公告)号：WO1986000122A1

    公开(公告)日：1986-01-03

    申请号：PCT/US1984000892

    申请日：1984-06-07

    Applicant: THE DOW CHEMICAL COMPANY ,  ASAHI CHEMICAL INDUSTRY CO., LTD ,  NAKAMURA, Masao ,  TONOKAWA, Hiroshi

    Inventor： THE DOW CHEMICAL COMPANY ,  ASAHI CHEMICAL INDUSTRY CO., LTD

    IPC: F17C07/02

    CPC classification number: F16L59/141 ,  F16L59/029 ,  Y10T428/1376

    Abstract: A heat insulating structure for low-temperature or cryogenic pipings (1), comprising at least one heat insulating barrier (3) and at least one moisture barrier (2) which are laid on the outer surface of a piping to be heat-insulated, and at least one sheathing layer (6), wherein said heat insulating barrier comprises an extruded styrenic resin foam and wherein, as expressed in terms of the three-dimensional coordinates X (circumferential direction), Y (thicknesswise direction) and Z (longitudinal direction), said heat insulating barrier has a Y-axial water vapor permeability Py of 1.5 g/m .hr or less and at least the heat insulating barrier most adjacent to said piping has X-axial and Z-axial elongations at rupture Ex and Ez in the range of 8 to 40 percent.

    Abstract translation: 一种用于低温或低温管道（1）的隔热结构，包括至少一个隔热屏障（3）和至少一个防潮层（2），其被放置在要被隔热的管道的外表面上， 和至少一个护套层（6），其中所述隔热屏障包括挤出的苯乙烯树脂泡沫体，其中，如三维坐标X（圆周方向），Y（厚度方向）和Z（纵向方向 ），所述隔热屏障具有1.5g / m 2·hr或更小的Y轴水蒸汽渗透性Py，并且至少与所述管道最相邻的隔热屏障在断裂时具有X轴和Z轴伸长率 Ex和Ez在8到40％的范围内。

    ADVANCED EPOXY RESINS HAVING IMPROVED IMPACT RESISTANCE WHEN CURED AND COATING COMPOSITIONS PREPARED THEREFROM
    270.
    发明申请
    ADVANCED EPOXY RESINS HAVING IMPROVED IMPACT RESISTANCE WHEN CURED AND COATING COMPOSITIONS PREPARED THEREFROM 审中-公开
    先进的环氧树脂在固化和涂料组合物时具有改善的耐冲击性

    公开(公告)号：WO1985005371A1

    公开(公告)日：1985-12-05

    申请号：PCT/US1985000937

    申请日：1985-05-20

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  CAVITT, Michael, B. ,  WASSBERG, Neal, L.

    IPC: C08L63/02

    CPC classification number: C08G59/38 ,  C08G59/066

    Abstract: Advanced epoxy resin compositions comprising a product resulting from reacting (A) a mixture containing (1) at least one polyglycidyl ether of a material having at least two aliphatic hydroxyl groups per molecule, (2) at least one epoxy resin having an average of from 2.6 to 6 glycidyl ether groups per molecule attached to one or more aromatic rings and optionally (3) one or more glycidyl ethers of a dihydric phenol; with (B) at least one dihydric phenol in the presence of a suitable quantity of a suitable catalyst; and wherein components (A) and (B) are present in quantities which provide an epoxy to phenolic hydroxyl ratio of from 1.4:1 to 4:1 and wherein the number of epoxy equivalents contributed by components (A-3) to the number of epoxy equivalents contributed by component (A-2) to the number of epoxy equivalents contributed by component (A-1) is from 0:0.05:1 to 0.3:0.6:1. Coating compositions containing the aforementioned advanced epoxy resins have improved chip resistance, chemical resistance or pencil hardness when cured.

    Abstract translation: 先进的环氧树脂组合物，其包含通过使（A）含有（1）至少一种每分子具有至少两个脂族羟基的材料的至少一种聚缩水甘油醚的混合物，（2）至少一种平均来自 每个分子连接到一个或多个芳环上的2.6至6个缩水甘油醚基团和任选的（3）一个或多个二元酚的缩水甘油醚; 与（B）至少一种二元酚在合适量的合适的催化剂存在下反应; 并且其中组分（A）和（B）以提供环氧树脂与酚羟基比为1.4:1至4:1的量存在，并且其中由组分（A-3）贡献的环氧当量数与 组分（A-2）对由组分（A-1）贡献的环氧当量数的环氧当量为0：0.05：1至0.3：0.6：1。 含有上述高级环氧树脂的涂料组合物在固化时具有改进的耐碎屑性，耐化学性或铅笔硬度。

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