Abstract:
PROBLEM TO BE SOLVED: To form a uniform and protective film which does not contain such a substance as to form detectable harmful hexavalent chromium, and has both adequate appearance and adequate corrosion resistance, on the surface of zinc or a zinc alloy, and to satisfy the corrosion resistance, design characteristics and a cost performance, which are bottlenecks for a replaceable technology such as a conventional trivalent-chromium-based rust preventive film to be commercialized. SOLUTION: This treatment agent has a liquid composition comprising: (A) a trivalent chromium ion; (B) one or more anions selected from the group consisting of a chlorine ion, a fluorine ion, a sulfate ion and a nitrate ion; (C) one or more elements selected from the group consisting of Ni, Pd, Pt, Sc, Y, V, Nb, Ta, Cu, Ag and Au; and (D) one or more compounds selected from the group consisting of Si, Al, a compound thereof and an organic acid. The rust preventive film is formed by using the liquid composition. COPYRIGHT: (C)2006,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To provide a treatment liquid which stably forms a uniform film having both satisfactory black appearance and corrosion resistance without using harmful hexavalent chromium when a protective film is formed on the surface of metal, in particular, on the surface of zinc or a zinc alloy, and to provide a method therefor. SOLUTION: The hexavalent chromium-free black film treatment liquid contains: tervalent chromium; one or more kinds selected from an anionic group composed of sulfate ions, chlorine ions and nitrate ions; and a sulfuric compound. In the method of forming a hexavalent chromium-free black film, a substrate is brought into contact with the treatment liquid once or more times. COPYRIGHT: (C)2005,JPO&NCIPI
Abstract:
PROBLEM TO BE SOLVED: To stably remove chromium to an effluent standard or below without using special chemicals and costly facility from effluent waste water containing tervalent chromium and organic acids. SOLUTION: The method for treating the flushing water, waste liquid or waste water comprises satisfying the following three conditions in treating the flushing water, waste liquid or waste water containing the organic acids discharged from a chemical conversion treatment after galvanizing and zinc alloy plating: (I) To add an alkaline earth metal or its salt to the flushing water, waste liquid or waste water, (II) to maintain the pH of the flushing water, waste liquid or waste water at ≥9, and (III) to heat the flushing water, waste liquid or waste water to a temperature above 25°C. COPYRIGHT: (C)2004,JPO