Thermoplastic elastomer composition, thermoplastic elastomer, and method for producing thermoplastic elastomer

    公开(公告)号:US10259940B2

    公开(公告)日:2019-04-16

    申请号:US15542904

    申请日:2016-01-12

    Inventor: Yuki Hayashi

    Abstract: The present invention provides a thermoplastic elastomer (TPE), in particular a polyurethane-based thermoplastic elastomer (TPU), that has exceptional elongation, strength, and wear resistance, and in particular has exceptional wear resistance. The present invention provides: a thermoplastic elastomer composition containing A) a thermoplastic urethane elastomer composition having A1) at least one polyol selected from the group consisting of polyether polyols, polyesterpolyols, and polycarbonate polyols, A2) a diisocyanate, and A3) a chain extender, and B) polyrotaxane formed by arranging blocking groups, at both ends of pseudo-polyrotaxane formed by inclusion of the openings of cyclic molecules in a shape skewered by linear molecules, so that the cyclic molecules are not eliminated; and a thermoplastic elastomer derived from this composition.

    Method for manufacturing polyrotaxane
    23.
    发明授权
    Method for manufacturing polyrotaxane 有权
    聚轮烷的制造方法

    公开(公告)号:US09487630B2

    公开(公告)日:2016-11-08

    申请号:US14428917

    申请日:2013-09-09

    Abstract: The present invention aims to provide a method for producing a polyrotaxane which enables industrially advantageous production of a polyrotaxane with a high inclusion rate.The present invention relates to a method for producing a polyrotaxane that includes a cyclodextrin; a compound having a repeating structural unit represented by the following formula (1), and threading through a cavity of the cyclodextrin in a skewered manner to be included in the cyclodextrin; and capping groups individually placed at each end of a molecule of the compound having a repeating structural unit represented by the formula (1) to prevent the cyclodextrin from separating, the method comprising: a step 1 of mixing the compound having a repeating structural unit represented by the formula (1) and the cyclodextrin in an aqueous medium to prepare an aqueous dispersion of pseudopolyrotaxan particles in which the compound having a repeating structural unit represented by the formula (1) is included in a cavity of a cyclodextrin molecule in a skewered manner; and a step 2 of mixing a triazine compound represented by the formula (2), a compound having at least one tertiary amino group, the aqueous dispersion of pseudopolyrotaxane particles prepared in the step 1, and a capping agent to introduce capping groups individually at each end of a molecule of the compound having a repeating structural unit represented by the formula (1) in the pseudopolyrotaxane particles, wherein, in the formula (2), R1 and R2 are each independently a C1-C4 alkyl group or a C6-C8 aryl group, and X represents a halogen atom.

    METHOD FOR PRODUCING PSEUDOPOLYROTAXANE AQUEOUS DISPERSION

    公开(公告)号:CA2821905C

    公开(公告)日:2018-07-10

    申请号:CA2821905

    申请日:2011-12-05

    Abstract: The present invention aims to provide an industrially advantageous method for producing an aqueous dispersion of pseudopolyrotaxane enabling to produce an aqueous dispersion of pseudopolyrotaxane having good fluidity and excellent dispersion stability of the pseudopolyrotaxane particles therein. The present invention relates to a method for producing an aqueous dispersion of pseudopolyrotaxane. The method includes: a mixing step of a dissolving polyethylene glycol and a cyclodextrin in an aqueous medium to prepare a mixed solution; and a cooling step of continuously or intermittently cooling the mixed solution in a state of flux to precipitate pseudopolyrotaxane particles. The pseudopolyrotaxane particles contain the polyethylene glycol which is included in the cavities of the cyclodextrin molecules in a skewered manner.

    METHOD FOR MANUFACTURING POLYROTAXANE

    公开(公告)号:CA2884974A1

    公开(公告)日:2014-03-27

    申请号:CA2884974

    申请日:2013-09-09

    Abstract: The purpose of the present invention is to provide a method for manufacturing polyrotaxane that can produce polyrotaxane with a high inclusion rate using an industrially advantageous method. The present invention is a method for manufacturing polyrotaxane, the polyrotaxane having: cyclodextrin; a compound having repeating structural units expressed by formula (1) that penetrates and is trapped in a skewered form in the openings of the cyclodextrin; and a blocking group located on both ends of the compound having repeating structural units expressed by formula (1), the blocking group preventing removal of the cyclodextrin. The method has: a first step for mixing cyclodextrin and the compound having repeating structural units expressed by formula (1) in an aqueous solvent, and obtaining a pseudo-polyrotaxane aqueous dispersion containing pseudo-polyrotaxane particles where the compound having repeating structural units expressed by formula (1) is trapped in skewered form in the openings of the cyclodextrin molecule; and a second step where a triazine compound expressed by formula (2), a compound having at least one tertiary amino group, the pseudo-polyrotaxane aqueous dispersion obtained in the first step, and a blocking agent are mixed together and a blocking group is introduced to both ends of the compound having repeating structural units expressed by formula (1) in the pseudo-polyrotaxane. In formula (2), R1 and R2 each independently represent an alkyl group with 1 to 4 carbon atoms, or an aryl group with 6 to 8 carbon atoms, and X represents a halogen atom.

    COMPOSICION QUE CONTIENE POLIROTAXANO.

    公开(公告)号:MX377478B

    公开(公告)日:2025-03-10

    申请号:MX2016004404

    申请日:2016-04-06

    Abstract: La presente invención se refiere a una composición que contiene polirotaxano que tiene excelente transparencia. La presente invención se refiere a una composición que contiene polirotaxano que incluye: un polirotaxano que tiene una molécula cíclica, una molécula lineal enhebrada a través de una cavidad de molécula cíclica de una manera ensartada, y grupos de tapado para tapar ambos extremos de la molécula lineal; y un (met) acrilato de alquilo que tiene un grupo alquilo C4-C18, el polirotaxano tiene al menos una molécula cíclica que tiene un grupo alquilo C4-C18.

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