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    METHOD OF PREPARING POLYASPARTIC ACID
    21.
    发明申请
    METHOD OF PREPARING POLYASPARTIC ACID 审中-公开
    用于生产聚天冬氨酸

    公开(公告)号：WO1995002007A1

    公开(公告)日：1995-01-19

    申请号：PCT/EP1994002083

    申请日：1994-06-27

    Applicant: BASF AKTIENGESELLSCHAFT ,  KRONER, Matthias ,  MEYER, Thomas ,  SCHORNICK, Gunnar ,  HOFMANN, Jürgen

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C08G69/10

    CPC classification number: C08G69/00 ,  C08G73/1092

    Abstract: Described is a method of preparing polymers of aspartic acid by heating (a) maleic acid anhydride with (b) acid derivatives of ammonia or adsorption media charged with ammonia, essentially to form hemi-amides of maleic acid or fumaric acid or ammonium salts of the hemi-amides of these acids, followed by thermal condensation of the hemi-amides or their salts, optionally in the presence of co-condensable compounds.

    Abstract translation: 一种通过加热制备天冬氨酸的聚合物的方法（a）中Maleinsäureanhydrit与形成马来酸或富马酸或这些酸和随后的单酰胺的铵盐的单酰胺的氨或吸附剂（b）的酸衍生物，装载有氨，在物质 在cocondensable化合物的存在单酰胺或其盐任选的热凝结。

    POLYMERS CONTAINING CYCLODEXTRIN GROUPS, PROCESS FOR THEIR PREPARATION AND THEIR USE
    25.
    发明申请
    POLYMERS CONTAINING CYCLODEXTRIN GROUPS, PROCESS FOR THEIR PREPARATION AND THEIR USE 审中-公开
    环糊精组含氯聚合物，其制造方法相同，它们的用途

    公开(公告)号：WO1997036948A1

    公开(公告)日：1997-10-09

    申请号：PCT/EP1997001278

    申请日：1997-03-14

    Applicant: BASF AKTIENGESELLSCHAFT ,  HUFF, Jürgen ,  KISTENMACHER, Axel ,  SCHORNICK, Gunnar ,  WEICKENMEIER, Meik ,  WENZ, Gerhard

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C08G81/00

    CPC classification number: A61K8/042 ,  A61K8/738 ,  A61Q19/00 ,  C08B37/0012 ,  C11D3/222 ,  D06M15/03

    Abstract: The invention concerns polymers which contain cyclodextrin groups and are obtained by: (a) deprotonation of cyclodextrins or modified cyclodextrins with bases, with the exclusion of water; and (b) reaction of the deprotonated cyclodextrins or cyclodextrin derivatives obtained in (a) with polymers containing reactive groups in the absence of water. The invention further concerns a process for preparing the polymers containing cyclodextrin groups and the use of the polymers containing cyclodextrin groups as gel-forming agents and thickeners for the molecular encapsulation of active substances in the field of pharmacy, cosmetics and plant protection, as well as detergent additives, softener additives and as textile and laundry after-treatment agents.

    Abstract translation: 含基团的环糊精，其是通过（a）环糊精或与在没有水存在下的碱改性环糊精的去质子化而得到的聚合物，和（b）使根据（a）中去质子化，用含有在不存在水的聚合物反应性基团的环糊精或环糊精衍生物获得。 一种制备含有聚合物和利用含基团环糊精聚合物作为胶凝剂和增稠剂，用于活性物质的中的药品，化妆品，植物保护领域以及洗涤剂添加剂分子包封的环糊精基团，作为用于织物软化剂中的添加剂的方法，和作为纺织衣物的后处理组合物。

    WATER-ABSORBENT CELLULAR CROSSLINKED HYDROGEL POLYMERS
    26.
    发明申请
    WATER-ABSORBENT CELLULAR CROSSLINKED HYDROGEL POLYMERS 审中-公开
    吸水，膨胀，交联的水凝胶聚合物

    公开(公告)号：WO1997017397A1

    公开(公告)日：1997-05-15

    申请号：PCT/EP1996004644

    申请日：1996-10-25

    Applicant: BASF AKTIENGESELLSCHAFT ,  HÄHNLE, Hans-Joachim ,  WALTER, Manfred ,  TROPSCH, Jürgen ,  SCHORNICK, Gunnar ,  ANSTOCK, Thomas

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C08J09/30

    CPC classification number: C08F220/06 ,  A61L15/425 ,  A61L15/60 ,  C08L33/02

    Abstract: The invention concerns water-absorbent cellular crosslinked-polymer materials produced by (I) foaming a polymerizable aqueous mixture containing: (a) acid-group-containing monoethylenically unsaturated monomers which have been neutralized to at least 50 mol %; (b) optionally, other monoethylenically unsaturated monomers; (c) crosslinking agents; (d) initiators; (e) 0.1 to 20 % by wt. of at least one surfactant; (f) optionally, at least one solubilizer and (g) optionally, thickeners, foam stabilizers, polymerization-control agents, fillers and/or cell-nucleation agents, the foaming being carried out by dispersing throughout the mixture fine bubbles of a gas which is inert to radicals, and (II) polymerizing the foamed mixture to form a cellular hydrogel and adjusting the water content of the cellular hydrogel to 1 to 45 % by wt. The invention also concerns methods of producing such polymer materials and their use in personal-hygiene articles used to absorb body fluids and in bandage material used to cover injuries.

    Abstract translation: 这可以通过含有（I）发泡包含（a）的酸基团单烯被中和到至少50mol％的不饱和单体的可聚合的含水混合物而获得吸水，膨胀，交联聚合物; （B）任选的其它单烯键式不饱和单体; （C）交联剂; （D）的引发剂; （E）0.1〜20重量％的至少一种表面活性剂的％; （F）任选地，至少一种增溶剂和（g）任选的增稠剂，泡沫稳定剂，聚合调节剂，填料和/或细胞的成核剂，其中，所述发泡通过分散这是朝向自由基呈惰性的气体的微小气泡发生; 和（II）聚合的发泡混合物，以形成膨胀的水凝胶和调节所述膨胀聚合物的水含量以1〜45重量％，它们的制备方法和它们在用于吸收体液，并用于修整材料的卫生制品中使用 覆盖伤口。

    BIOLOGICALLY DEGRADABLE POLYMERS, PROCESSES FOR MANUFACTURING THE SAME AND THE USE THEREOF FOR PRODUCING BIODEGRADABLE MOULDED ARTICLES
    27.
    发明申请
    BIOLOGICALLY DEGRADABLE POLYMERS, PROCESSES FOR MANUFACTURING THE SAME AND THE USE THEREOF FOR PRODUCING BIODEGRADABLE MOULDED ARTICLES 审中-公开
    生物降解聚合物，方法的生产和使用，其用于制造生物可降解成型

    公开(公告)号：WO9621689A2

    公开(公告)日：1996-07-18

    申请号：PCT/EP9502493

    申请日：1995-06-27

    Applicant: BASF AG ,  WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

    Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

    IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

    CPC classification number: C08G69/44 ,  C08G18/606 ,  Y02W30/43

    Abstract: The invention concerns biologically degradable polyester amides P1 obtainable through reaction of a mixture consisting essentially of the following: (a1) a mixture consisting essentially of: 35-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-65 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0-5 mol % a compound containing sulphonate groups (the sum of the individual molar percentages is 100); (a2) a mixture consisting essentially of: (a21) 99.5-0.5 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols, (a22) 0.5-99.5 mol % an amino C2-C12 alkanol or an amino-C5-C10 cycloalkanol, (a23) 0-50 mol % a diamino C1-C8 alkane; and (a24) 0-50 mol % a 2,2`-bisoxazoline of general formula (I), in which R is a single bond, a (CH2)q-alkylene group in which q = 2, 3 or 4, or a phenylene group (the sum of the individual molar percentages is 100 and the molar ratio of a1 to a2 is in the range 0.4:1 - 1.5:1). The polyester amides P1 will have a molecular weight (Mn) in the range 4000-40,000 g/mol, a viscosity number in the range 30-350 g/ml (measured in o-dichlorobenzene/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyester amide P1 at a temperature of 25 DEG C) and a melting point in the range 50-220 DEG C; and a quantity of a compound D equivalent to 0-5 mol % of the molar quantity of components (a1) must also be used for the production of the polyester amides P1, said compound D having at least three groups capable of ester formation. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, processes for manufacturing the same, the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles, foams and blends with starch which can be obtained from the polymers or moulding materials according to the invention.

    Abstract translation: 可生物降解的聚酯酰胺通过基本上由混合物反应P1获得（a1）的基本上35由〜95摩尔％的己二酸或它们的酯形成性衍生物或者它们的混合物，5〜65摩尔％的对苯二甲酸或其酯形成性衍生物的混合物 或其混合物，和0〜5摩尔％磺酸酯化合物的，单独的摩尔百分比的总和为100摩尔％，和（a2）从99.5基本上由（A21）〜0.5摩尔的混合物 - （A22）0.5选自C2-C6烷二醇和C5-C10-环烷二醇的组中选择的二羟基化合物，的％至99.5摩尔％的氨基C2-C12链烷醇或氨基-C5的 C10-环烷醇，以及（A23）0〜50摩尔％的二氨基C1-C8烷烃，（A24）0〜50摩尔％通式（I）的2,2'-二恶唑啉，其中R <1 >一个单键，（CH 2）●亚烷基其中q = 2，3或4，或亚苯基，其中装置 各个摩尔百分比的总和为100摩尔％，并且其中的（a1）至（A2）的范围为0.4的摩尔比：1至1.5：1种选择，条件是该聚酯酰胺P1的分子量 （Mn）的范围为4000至40,000克/摩尔，在30至350范围内的粘度数克/毫升（在以0.5重量％的浓度的邻二氯苯/苯酚（50/50重量比）进行测定。 - ％聚酯酰胺P1在25℃的温度），并在50至220℃的范围内的熔点，并与一个从0〜5摩尔％基于组分的摩尔量进一步的条件（A1 ），与能够对聚酯酰胺的制备酯的形成至少三个基团的化合物D P1中使用的以及其它可生物降解的聚合物和热塑性模塑组合物，涉及它们的制备方法，它们用于制备可生物降解的模制品和粘合剂，生物可降解的成型品使用， 泡沫和从本发明的聚合物或模塑组合物获得的淀粉混合物。

    METHOD OF PREPARING MODIFIED POLYASPARTIC ACIDS
    28.
    发明申请
    METHOD OF PREPARING MODIFIED POLYASPARTIC ACIDS 审中-公开
    用于生产改性聚天冬氨酸

    公开(公告)号：WO1996010050A1

    公开(公告)日：1996-04-04

    申请号：PCT/EP1995003621

    申请日：1995-09-14

    Applicant: BASF AKTIENGESELLSCHAFT ,  KRONER, Matthias ,  SCHORNICK, Gunnar

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C08G69/10

    CPC classification number: C08G73/1092 ,  C11D3/3719

    Abstract: Described is a method for the preparation of modified polyaspartic acids by condensing aspartic acid with polybasic carboxylic acids or anhydrides of polybasic carboxylic acids and ammonia, essentially at temperatures of at least 140 DEG C in the absence of inorganic acids.

    Abstract translation: 通过在不存在无机酸在至少140℃的温度下冷凝天冬氨酸与多元羧酸或散装多元羧酸和氨酸酐用于改性聚天冬氨酸的制备方法。

    METHOD FOR PRODUCING CONDENSATION POLYMERS OF ASPARTIC ACID AND THEIR USE IN WASHING AND CLEANING PRODUCTS
    29.
    发明申请
    METHOD FOR PRODUCING CONDENSATION POLYMERS OF ASPARTIC ACID AND THEIR USE IN WASHING AND CLEANING PRODUCTS 审中-公开
    用于生产天门冬氨酸的缩聚物和它们在洗涤和清洁剂

    公开(公告)号：WO1996005243A1

    公开(公告)日：1996-02-22

    申请号：PCT/EP1995003005

    申请日：1995-07-28

    Applicant: BASF AKTIENGESELLSCHAFT ,  KRONER, Matthias ,  GEBHARDT, Norbert ,  SCHWENDEMANN, Volker ,  SCHORNICK, Gunnar

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C08G69/10

    CPC classification number: C08G73/1092 ,  C02F5/12 ,  C11D3/3719

    Abstract: Disclosed is a method for producing condensation polymers of aspartic acid by means of condensation polymerization of aspartic acid at temperatures of 140 DEG C in the presence of, relative to aspartic acid, from 1 to less than 5 mol % phosphorous acid or hypophosphorous acid catalyst, and the use of the resulting condensation polymers of aspartic acid as additives in washing and cleaning products, amounting to 0.1 to 10 wt % relative to the washing and cleaning products.

    Abstract translation: 一种用于通过天冬氨酸中的1存在的缩聚制备天冬氨酸的缩聚物为小于5摩尔％的亚磷酸或次磷酸，基于天冬氨酸作为在140℃下的温度的催化剂和使用天冬氨酸的这样产生的缩聚物的过程 作为添加剂，以洗涤剂和清洁剂中的0.1的量至10重量％，基于洗涤剂和清洗剂。

    METHOD FOR PRODUCING CONDENSATION POLYMERS OF ASPARTIC ACID AND USE OF THE CONDENSATION POLYMERS
    30.
    发明申请
    METHOD FOR PRODUCING CONDENSATION POLYMERS OF ASPARTIC ACID AND USE OF THE CONDENSATION POLYMERS 审中-公开
    用于生产天门冬氨酸和缩聚物的使用的缩聚物

    公开(公告)号：WO1996005242A1

    公开(公告)日：1996-02-22

    申请号：PCT/EP1995003004

    申请日：1995-07-28

    Applicant: BASF AKTIENGESELLSCHAFT ,  KRONER, Matthias ,  SCHORNICK, Gunnar

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C08G69/10

    CPC classification number: C02F5/12 ,  C08G73/0611 ,  C08G73/1092 ,  C11D3/3719

    Abstract: Diclosed is a method for producing condensation polymers of aspartic acid by means of condensation polymerization of aspartic acid at temperatures of 140 to 300 DEG C in the presence of a sulfuric acid catalyst partially neutralized with ammonia and/or amines and the use of the reaction mixtures thus produced or of the reaction mixtures neutralized with alkali metal bases or alkaline earth metal bases as additives in phosphate-free or low-phosphate detergents and cleaners.

    Abstract translation: 一种用于在140温度下的部分的存在下与氨和/或胺硫酸作为由此获得或与碱金属或碱土金属碱的反应混合物中和的反应混合物中的催化剂和使用中和的由天门冬氨酸的缩聚制备天冬氨酸的缩聚物至300℃的过程 到不含磷酸盐的添加剂或降低的磷酸洗涤剂和清洁剂。

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