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公开(公告)号:CA2836998A1
公开(公告)日:2013-01-03
申请号:CA2836998
申请日:2012-06-28
Applicant: STAMICARBON BV DBA MT INNOVATION CT , UNIV STUTTGART
Inventor: TRAA YVONNE , GEISS DANIEL
IPC: C07C2/76 , C07C15/02 , C07C15/27 , C07D213/06
Abstract: Disclosed is a process for the direct alkylation of aromatic compounds with alkanes. To this end a judicious catalyst combination is provided. The composition comprises palladium as a catalytically active metal, and zinc as a promoter, or a metal such as tin having a comparable promoting action. The metals are contained in a zeolite support, or a similar support of a metal organic framework type or a silico alumino phosphate type.
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公开(公告)号:FR2214762A1
公开(公告)日:1974-08-19
申请号:FR7401906
申请日:1974-01-21
Applicant: STAMICARBON , STAMICARBON BV NL
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公开(公告)号:CA2842913A1
公开(公告)日:2013-01-31
申请号:CA2842913
申请日:2012-07-26
Applicant: STAMICARBON BV DBA MT INNOVATION CT
Inventor: IAQUANIELLO GAETANO , PALO EMMA , CONTALDO PALMA
Abstract: The present invention relates to a process for producing a hydrogen containing gas mixture comprising the following steps: (i) providing a preheated mixture comprising a fossil fuel, preferably methane, and steam, (ii) conducting an adiabatic reaction between the fossil fuel and the steam, in the presence of a catalyst, wherein a first reaction product mixture is formed comprising methane, hydrogen and carbon dioxide, and (iii) conducting an oxygen-assisted reforming reaction in the presence of a catalyst between said first reaction product mixture and an oxygen comprising stream, wherein the oxygen comprising stream comprises at least 40 vol% oxygen, forming a second reaction product mixture comprising hydrogen and carbon monoxide. The invention also relates to a system suitable for hydrogen production from a hydrocarbon feed according to the present invention.
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公开(公告)号:CA2837773A1
公开(公告)日:2012-12-27
申请号:CA2837773
申请日:2012-06-25
Applicant: STAMICARBON BV DBA MT INNOVATION CT
Inventor: IAQUANIELLO GAETANO , CUCCHIELLA BARBARA , ANTONETTI ELENA
IPC: C01B3/38 , C01B3/48 , C07C273/04
Abstract: Disclosed is a process for the production of a syngas mixture by catalytic partial oxidation. The syngas mixture is suitable as an intermediate in the production of hydrogen. According to the invention, the syngas is cooled, prior to a water gas shift reaction, with liquid water. This has the advantage of avoiding the problem of metal dusting, and it presents a gas mixture comprising water vapor that is particularly suitable for a water gas shift reaction in the production of hydrogen.
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公开(公告)号:CA2835470A1
公开(公告)日:2012-12-20
申请号:CA2835470
申请日:2012-06-15
Applicant: STAMICARBON BV DBA MT INNOVATION CT
Inventor: IAQUANIELLO GAETANO , CUCCHIELLA BARBARA , ANTONETTI ELENA
Abstract: The present invention relates to a method for hydrogen production and to a method of hydrogen and/or carbon dioxide production from syngas. The method comprises the steps of: (i) providing a gas stream comprising hydrogen and carbon monoxide, (ii) separating at least part of hydrogen from the stream yielding a hydrogen-depleted stream, (iii) subjecting the hydrogen- depleted stream to a water-gas shift reaction, and (iv) separating hydrogen from the stream resulting from step (iii). The method according to the invention improves the conversion of carbon monoxide in the water gas shift reaction and allows to increase the hydrogen production by 10-15% and to increase the overall energy efficiency of the system by 5-7%. The invention further relates to a plant for hydrogen and/or carbon dioxide production suitable for the method of the invention.
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公开(公告)号:CA2835150A1
公开(公告)日:2012-11-15
申请号:CA2835150
申请日:2012-05-07
Applicant: STAMICARBON BV DBA MT INNOVATION CT
Inventor: MOLINARI LUCIO , ANGELINI FABIO , BARBATO LUCIA
Abstract: Disclosed is a process for the concurrent production of hydrogen and sulphur from a H2S-containing gas stream, with zero emissions. The method comprises the thermal oxidative cracking of H2S so as to form H2 and S2. Preferably, the oxidation is conducted using oxygen-enriched air, preferably pure oxygen. The ratio H2S/O2 in the feedstock is higher than 2:1, preferably in the range of 3:1-5: 1.
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公开(公告)号:FR2174269A1
公开(公告)日:1973-10-12
申请号:FR7307476
申请日:1973-03-02
Applicant: STAMICARBON , STAMICARBON BV NL
Inventor: SCHAFFSMA S E , DEUMENS J J M
IPC: C07D311/74 , C07D7/18
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