Abstract:
신규한 엑스모양 공액형 유기 화합물, 이를 이용한 염료감응 광전변환소자 및 염료감응 태양전지가 개시된다. 본 발명에 따른 엑스모양 공액형 유기 화합물은 2개의 전자공여체(electron donor)와, 금속 산화물에 흡착을 위한 -COOH 그룹을 포함하는 2개의 전자수용체(electron acceptor)가 각각 벤젠을 중심으로 π-컨쥬게이션을 이룰 수 있게 결합된 것을 특징으로 하며, 이를 염료감응 태양전지의 유기염료로 이용하는 경우 금속산화물과 강한 흡착력을 가지며, 몰흡광계수 및 광전기 변환효율을 향상시킬 수 있어, 기존에 사용되는 고가의 금속 착체를 대체하는 것이 가능하다. 염료감응태양전지
Abstract:
PURPOSE: Photocrosslinkable electrically conductive polymers and compositions including the polymers are provided to manufacture films using wet processing since a crosslinkable photoreactable group is included and the polymers can be dissolved in an aqueous solution. CONSTITUTION: A copolymer comprises repeating units of formula 1 and formula 2, wherein A and B are independently at least one member selected from the group consisting of phenylene, phenylene vinylene, pyrrolylene, pyrrolylene vinylene, thienylene, thienylene vinylene, fluorenylene, fluorenylene vinylene, furanylene, furanylene vinylene, phenothiazinylene, phenothiazinylene vinylene, phenazinylene, phenazinylene vinylene, phenoxazinylene and phenoxazinylene vinylene, which are unsubstituted or substituted with one or more substituents; R1 is Y or L-Y, wherein Y is a photoreactive group and L is a linker; the ratio of the repeating unit of formula 1 and the repeating unit of formula 2 is 1:0.1 to 1:0.3; the copolymer has a degree of polymerization of 100 to 1,000; and the copolymer is optionally doped with one or more polymeric acids.
Abstract:
PURPOSE: A polyacene derivative is provided to improve solubility, crystallinity and stability by introducing benzyl acetylene and thiophenylacetylene substituent structure to a polyacene derivative containing an anthracene structure. CONSTITUTION: A polyacene derivative is represented by chemical formula 1 or 2. In chemical formulas, Ar1 is selected from the group consisting of naphthalene, anthracene, tetracene or pentacene; Ar2 and Ar3 are independently selected from (C6-C60) arylene, (C3-C60) heteroarylene, 5 or 6-membered heterocycloalkene, (C3-C60) cycloalkenylene, adamantylene, (C7-C60) bicycloalkylene, (C2-C60) alkenylene, (C2-C60) alkynylene, (C6-C60) ar (C1-C60) alkenylene, (C1-C60) alkylenethio, (C1-C60) alkyleneoxy, (C6-C60) aryleneoxy or (C6-C60) arylene thio.
Abstract:
The present invention relates to a porphyrin derivative, an organic thin film transistor including the same, and a photoelectric element comprising the same which has excellent solubility and improved oxidation resistance for a solvent, and has electrical properties such as excellent thermal stability and high field effect mobility.
Abstract:
PURPOSE: A photochromic dye is provided to enable fast conversion in an aqueous solution and slow conversion in a hard environment such as a hard polymer. CONSTITUTION: A photochromic dye comprises: at least two photo-reactive groups, wherein a first photo-reactive group is configured to undergo a first photochromic reaction in response to radiation having first wavelength, and a second photo-reactive group is configured to undergo a second photochromic reaction in response to radiation having second wavelength. The at least two photo-reactive groups are coupled to one another by a non-conjugated linkage selected from the group consisting of C1-12 alkylene, C1-12 heteroalkylene, C1-12 alkoxy, C1-6 alkylenoxy, C1-6 alkylenedioxy, C1-6 phenyleneoxy, and C1-6 phenylenedioxy.
Abstract translation:目的:提供一种光致变色染料,使其能够在水溶液中快速转化,并在硬质环境如硬聚合物中缓慢转化。 构成:光致变色染料包括:至少两个光反应性基团,其中第一光反应性基团被配置为响应于具有第一波长的辐射进行第一光致变色反应,并且第二光反应性基团被配置为经历 响应于具有第二波长的辐射的第二光致变色反应。 所述至少两个光反应性基团通过非共轭键彼此偶联,所述非共轭键选自C1-12亚烷基,C1-12杂亚烷基,C1-12烷氧基,C1-6亚烷基氧基,C1-6亚烷基二氧基, C 1-6亚苯基氧基和C 1-6亚苯基二氧基。
Abstract:
PURPOSE: Water-soluble electrically conductive polymers are provided to allow the polymer to be stable at high temperature since hydrophilic side chains are covalently bonded to the conductive polymers, thereby prolonging the stability of electrical conductivity and to enable the change of the conductivity depending on the concentration of hydrophilic side chains. CONSTITUTION: A polymer comprises at least one repeating unit of formula 1 and formula 2, wherein A and B are independently at least one member selected from the group consisting of phenylene, phenylene vinylene, pyrrolylene, pyrrolylene vinylene, thienylene, thienylene vinylene, fluorenylene, fluorenylene vinylene, furanylene, furanylene vinylene, phenothiazinylene, phenothiazinylene vinylene, phenazinylene, phenazinylene vinylene, phenoxazinylene and phenoxazinylene vinylene, which are unsubstituted or substituted with one or more substituents; R1 represents formula A and R2 represents formula B; R3, R4, R5, R6, R7 and R8 are independently hydrogen, alkyl, ammonium or formula C with the proviso that at least one of R3, R4, R5, R6, R7 and R8 is ammonium or formula D; K represents alkylene having one or two carbon; d is 1 to 3; R9 is hydroxyl, carboxylic acid, sulfonic acid, or a straight or branched alkyl which is unsubstituted or substituted with hydroxyl; and the polymer has a degree of polymerization of 100 to 1,000.
Abstract:
PURPOSE: An X-shape conjugated organic compound and dye sensitive photoelectric conversion device and solar cell are provided to ensure strong adsorption with a metal oxide and to improve photoelectric conversion efficiency. CONSTITUTION: An X-shape conjugated organic compound contains two electron donors and two electron acceptors having -COOH group for adsorbing to a metal oxide. The electron donor is carbazole, phenoxyazine, thiophene, trianylamine, or a derivative thereof. The electron acceptor is cyanoacrylic acid, rhodanin-3-acetic acid, or a derivative thereof. The X-shape conjugated organic compound is denoted by chemical formula 1 or 2. A dye sensitive photoelectric conversion device contains an oxide semiconductor microsphere. The dye sensitive solar cell contains the device.
Abstract:
A phosphorescence material is provided to improve a melting property of a dopant and a miscibility between a dopant and a host, and to form an organic light emitting layer through a vacuum deposition process or wet process. A phosphorescence material has a structure represented by the following formula 1, wherein each of R1 to R10 is any one selected from hydrogen, halogen, substituted or unsubstituted C1-18 alkyl groups, and C1-18 alkoxy groups, at least any one of R1 to R10 is any one of C1-18 alkyl groups containing a carbazole group and C1-18 alkoxy groups containing a carbazole group, M is a transition metal, and n is an integer of 1-4.
Abstract:
A light emitting dendrimer intermediate, a method for preparing the light emitting dendrimer intermediate, a novel light emitting dendrimer, a method for preparing the light emitting dendrimer, and an organic light emitting diode device prepared from the dendrimer are provided to improve luminous efficiency and to allow an organic light emitting layer to be prepared by a wet process. A light emitting dendrimer intermediate comprises any one selected from an azine-based derivative, a carbazole-based derivative and their mixture and is represented by the formula 1 or 2, wherein X is S or O, and R is a C1-C10 alkyl group. The light emitting dendrimer comprises a core which comprises a light emitting compound; and a dendron which comprises the light emitting dendrimer intermediate of the formula 1 or 2, and surrounds the core.