公开(公告)号：KR1020120102984A

公开(公告)日：2012-09-19

申请号：KR1020110020942

申请日：2011-03-09

Applicant: 서울대학교산학협력단

Inventor： 송인규 ,  홍웅기 ,  박해웅

IPC: B01J23/46 ,  B01J37/02 ,  B01J37/08 ,  C07D307/33

CPC classification number: B01J23/462 ,  B01J37/0009 ,  C07D307/33

Abstract: PURPOSE: A ruthenium catalyst supported on porous carbon support synthesized by a surfactant-templating method, a method for preparing the same, and a method for producing gamma-butyrolactone using the catalyst are provided to activate the hydrogenation of succinic acid. CONSTITUTION: A method for preparing a ruthenium catalyst supported on porous carbon support includes the following: a carbon precursor and a surfactant are dissolved in an acid solution, and a silica precursor is added into the dissolved solution to obtain a carbon/surfactant/silica complex; the complex is dried and aged at a temperature between 80 and 120 deg C under an air condition to obtain partially carbonated carbon/surfactant/silica complex; the partially carbonized complex is treated with a sulfuric acid aqueous solution; the treated complex is washed, filtered, and carbonated at a temperature between 800 and 1000 deg C; silica template components are eliminated from the carbonated complex based on hydrofluoric acid to obtain a porous carbon support; and a ruthenium precursor is impregnated in the porous carbon support. [Reference numerals] (AA,BB,CC) Sucrose; (DD) Hydrothermal synthesis; (EE) Silica precursor; (FF,HH) Heat; (GG) Surfactant silica precursor; (II) Carbon slurry; (JJ) Carbon/silica slurry; (KK) Carbon/silica/surfactant slurry; (LL,MM,OO) Carbonization; (NN,PP) Hydrofluoric acid treatment; (QQ) Carbon support manufactured by a hydrothermal method; (RR) Carbon support manufactured by a templating method; (SS) Carbon support manufactured by a surfactant-templating method

Abstract translation: 目的：提供负载在通过表面活性剂模板法合成的多孔碳载体上的钌催化剂，其制备方法和使用该催化剂制备γ-丁内酯的方法，以活化琥珀酸的氢化。 构成：负载在多孔碳载体上的制备钌催化剂的方法包括：将碳前体和表面活性剂溶解在酸溶液中，并将二氧化硅前体加入溶解的溶液中，得到碳/表面活性剂/二氧化硅复合物 ; 在空气条件下将复合物干燥并在80至120℃的温度下老化，得到部分碳酸化的碳/表面活性剂/二氧化硅复合体; 部分碳化的复合物用硫酸水溶液处理; 将处理的复合物在800至1000℃的温度下进行洗涤，过滤和碳酸化; 基于氢氟酸从碳酸化复合物中除去二氧化硅模板成分，得到多孔碳载体; 并且钌前体浸渍在多孔碳载体中。 （AA，BB，CC）蔗糖; （DD）水热合成; （EE）二氧化硅前体; （FF，HH）热; （GG）表面活性剂二氧化硅前体; （二）碳浆; （JJ）碳/二氧化硅浆液; （KK）碳/二氧化硅/表面活性剂浆料; （LL，MM，OO）碳化; （NN，PP）氢氟酸处理; （QQ）通过水热法制造的碳载体; （RR）通过模板法制造的碳载体; （SS）通过表面活性剂模板法制造的碳载体

公开(公告)号：KR101088100B1

公开(公告)日：2011-11-29

申请号：KR1020100052651

申请日：2010-06-04

Applicant: 서울대학교산학협력단

Inventor： 송인규 ,  홍웅기 ,  서정길 ,  박선영

IPC: B01J23/44 ,  B01J37/02 ,  B01J37/08 ,  C07D307/32

CPC classification number: B01J23/44 ,  B01J21/04 ,  B01J37/08 ,  C07D307/33

Abstract: PURPOSE: A palladium catalyst supported on an alumina xerogel support with controlled acidity and a method for preparing γ-butyrolactone based on the hydrogenation of succinic acid using the catalyst are provided to thermo-chemically stabilize a catalytic process by optimally combining the acid characteristic of the support and the hydrogenation activity of palladium. CONSTITUTION: A palladium catalyst supported on an alumina xerogel support with controlled acidity is obtained by gelating an aluminum precursor based on a sol-gel method and implementing a thermal treatment. The average pore size of the palladium catalyst is between 2 and 10nm. The surface area of the palladium catalyst is between 100 and 300m^2/g. The temperature of the thermal treatment is between 700 and 900 degrees Celsius. 1-10 parts by weight of the palladium catalyst is supported by 100 parts by weight of the alumina xerogel support.

Abstract translation: 目的：提供负载在具有受控酸性的氧化铝干凝胶载体上的钯催化剂和基于使用该催化剂的琥珀酸氢化制备γ-丁内酯的方法，以通过最佳地组合催化剂的酸特性来热化学稳定催化过程 支持和钯的氢化活性。 构成：通过基于溶胶 - 凝胶法凝胶化铝前体并实施热处理，获得负载在具有受控酸度的氧化铝干凝胶载体上的钯催化剂。 钯催化剂的平均孔径在2和10nm之间。 钯催化剂的表面积为100-300m 2 / g。 热处理的温度在700-900摄氏度之间。 1-10重量份的钯催化剂由100重量份的氧化铝干凝胶载体负载。

公开(公告)号：KR1020110010190A

公开(公告)日：2011-02-01

申请号：KR1020090067620

申请日：2009-07-24

Applicant: 서울대학교산학협력단

Inventor： 송인규 ,  홍웅기 ,  박동률 ,  서정길

IPC: B01J27/19 ,  B01J27/20 ,  B01J35/08 ,  C07C45/29

CPC classification number: B01J27/19 ,  B01J27/20 ,  B01J31/18 ,  B01J35/08 ,  B01J37/08 ,  B01J37/16

Abstract: PURPOSE: A heteropoly acid support catalyst fixed on a porous spherical carbon containing nitrogen is provided to enhance support amount of the heteropoly acid. CONSTITUTION: A heteropoly acid support catalyst fixed on a porous spherical carbon containing nitrogen is prepared by synthesizing, thermal treating and reducing a carbon precursor containing a nitrogen ingredient with a spherical resin. The catalyst is fixed by reacting a porous spherical carbon with heteropoly acid in a weight ratio of 1 : 0.01-2 in an ion form of amine group and heteropoly acid. The carbon precursor is selected from melamine-formaldehyde resin, polypyrrole, polyanyline and polythiophene.

Abstract translation: 目的：提供固定在含氮多孔球状碳上的杂多酸载体催化剂，以增强杂多酸的支持量。 构成：通过用球形树脂合成热处理和还原含有氮成分的碳前体来制备固定在含氮多孔球状碳上的杂多酸载体催化剂。 通过使多孔球形碳与杂多酸以离子形式的胺基和杂多酸的重量比为1:0.01-2进行反应来固定催化剂。 碳前体选自三聚氰胺 - 甲醛树脂，聚吡咯，聚苯胺和聚噻吩。