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公开(公告)号：KR100566672B1
公开(公告)日：2006-03-31
申请号：KR1020040039737
申请日：2004-06-01
Applicant: 재단법인서울대학교산학협력재단 , 동우 화인켐 주식회사
IPC: G01N31/22
Abstract: 본 발명의 휘발성 유기 증기를 검출하는 화학센서는 하기 구조식으로 표시되는 BPPCES를 인지물질로 사용하는 것을 특징으로 한다.
휘발성 유기 증기, 검출, CN-MBE, BPPCES, 센서, 스위칭-
公开(公告)号：KR1020050114525A
公开(公告)日：2005-12-06
申请号：KR1020040039760
申请日：2004-06-01
Applicant: 재단법인서울대학교산학협력재단 , 동우 화인켐 주식회사
IPC: C09K11/06
Abstract: 본 발명에 따른 플루오렌 기를 함유하고 그 플루오렌 기의 양단에 황 원자를 포함하는 화합물로서 고체 및 용액 상태에서 청색 발광을 하여 유기 전자발광 장치에 사용되는 발광 화합물은 하기의 구조식 1로 표시된다:
[구조식 1]
상기 식에서, R
1 및 R
2 는 각각 독립된 탄소수 1 내지 20의 알킬기 또는 탄소수 1 내지 20의 알콕시기이고, R
3 은 같거나 다른 알릴기, 헤테로사이클기 또는 알리파틱 탄화수소기이며, 그리고 R
4 는 탄소수 1 내지 20의 알킬기, 탄소수 6 내지 20의 아릴기, 탄소수 1 내지 20의 알킬기를 갖는 탄소수 6 내지 20의 아릴기, 또는 탄소수 1 내지 20의 알콕시기를 갖는 탄소수 6 내지 20의 알릴기이고, n은 0 내지 2의 정수이고, m은 1 내지 3의 정수이다.-
公开(公告)号：KR1020040005261A
公开(公告)日：2004-01-16
申请号：KR1020020039751
申请日：2002-07-09
Applicant: 재단법인서울대학교산학협력재단 , 동우 화인켐 주식회사
IPC: C07D401/12
CPC classification number: C07D215/20
Abstract: PURPOSE: Quinoline compounds showing excited-state intramolecular proton transfer(ESIPT) are provided. The compounds show various colors in electroluminescence as insertion of a functional group into a quinoline structure, improve the luminescence efficient and increase the luminescence period. CONSTITUTION: A quinoline monomer represented by the formula(2) is provided, wherein X is -OH or -OCH3. A quinoline dendrimer represented by the formula(3a) is provided, wherein X is selected from a compound of the formulas(3b to 3d); and Y is -H or a compound of the formula(3b). A quinoline polymer represented by the formula(4) is provided, wherein X and Y are independently -H or -OH. A method for producing the quinoline monomer of the formula(2) comprises the steps of: mixing metacresol and P2O5; and adding bisaminoketone and 2-hydroxy-4-methoxyacetophenone.
Abstract translation: 目的：提供显示激发态分子内质子转移（ESIPT）的喹啉化合物。 该化合物在电致发光中显示出各种颜色，将官能团插入到喹啉结构中，提高发光效率并增加发光周期。 构成：提供由式（2）表示的喹啉单体，其中X为-OH或-OCH 3。 提供由式（3a）表示的喹啉树枝状聚合物，其中X选自式（3b-3d）的化合物; Y为-H或式（3b）的化合物。 提供由式（4）表示的喹啉聚合物，其中X和Y独立地为-H或-OH。 制备式（2）的喹啉单体的方法包括以下步骤：将甲酚与P 2 O 5混合; 并加入双氨基酮和2-羟基-4-甲氧基苯乙酮。
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公开(公告)号：KR1020100133359A
公开(公告)日：2010-12-21
申请号：KR1020107016378
申请日：2007-12-21
Applicant: 동우 화인켐 주식회사 , 재단법인서울대학교산학협력재단
CPC classification number: G06F12/0246 , G06F8/65 , G06F2212/1004 , G06F2212/1016 , G06F2212/7202 , G06F2212/7206 , G06F2212/7207 , G11C16/102
Abstract: PURPOSE: An iridium complex is provided to enable use as excellent red emitting material with ELmax in 600~660 nm wavelength area and to ensure excellent property. CONSTITUTION: An iridium complex is represented by chemical formula 1. In chemical formula 1, R1, R2, and R3 are C1~10 aliphatic or aromatic hydrocarbon; and R4 and R5 are independently selected from hydrogen, halogen, cyano, C1-20 alkyl, alkoxy, alkylthio, alkylamino, heteroalkyl, C2-20 alkenyl and alkynyl, C6-30 aryl, arylthio, aryloxy, arylamino, C3-30 heteroaryl, heteroaryloxy, heteroarylthio, and heteroaryl amino group; and X is oxygen(O) or sulfur(S).
Abstract translation: 目的：提供铱络合物，以在600〜660nm波长范围内使用ELmax的优异红色发光材料，并确保优异的性能。 构成：铱络合物由化学式1表示。在化学式1中，R 1，R 2和R 3为C 1-10脂族或芳族烃; 并且R 4和R 5独立地选自氢，卤素，氰基，C 1-20烷基，烷氧基，烷硫基，烷基氨基，杂烷基，C 2-20烯基和炔基，C 6-30芳基，芳硫基，芳氧基，芳基氨基，C 3-30杂芳基， 杂芳氧基，杂芳硫基和杂芳基氨基; X为氧（O）或硫（S）。
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公开(公告)号：KR100900332B1
公开(公告)日：2009-06-02
申请号：KR1020070073212
申请日：2007-07-23
Applicant: 재단법인서울대학교산학협력재단
Abstract: 디브로모벤젠을 -78℃ THF 용액에서
n -BuLi으로 리튬처리한 후 실온의 THF 용액에서 디메시틸보론 플루오라이드로 처리하여 보릴 페닐 브롬마이드를 생성하고, 이를 다시 2-(tributylstannyl)pyridine과 Pd(PPh
3 )
4 와 함께 톨루엔에 용해시켜 환류시키면서 Pd-촉매 Stille 반응을 통하여 킬레이트 리간드로 변형하고, 이를 다시 아르곤(Ar) 포화 상태에서 140 ℃의 2-EtOEtOH:H
2 O 용액에서 리간드와 IrCl
3 ·xH
2 O와의 Nonoyama 반응을 통하여
μ -클로라이드-브릿지 Ir(Ⅲ) 다이머(dimer)를 생성한 후, 아르곤(Ar) 포화 상태에서 140 ℃의 2-EtOEtOH 용액에서 탄산나트륨의 도움으로 염소를 2,4-펜탄디온으로 치환시켜 보릴 기-함유 헤테로렙틱(heteroleptic) Ir(Ⅲ) 착체(1)를 얻는다. 본 발명의 이리듐(Ⅲ) 착체(1)는 톨루엔, 이염화클로로포름(CH
2 Cl
2 ), 디옥산, 아세토니트릴과 같은 일반 유기 용매에 상당히 높은 용해도를 나타낸다.
플루오르 이온 검출, 인광성 이리듐 착체, 음이온 센싱-
Patent Agency Ranking
公开(公告)号：KR1020090013870A
公开(公告)日：2009-02-06
申请号：KR1020070077967
申请日：2007-08-03
Applicant: 재단법인서울대학교산학협력재단
IPC: C09K11/06
Abstract: An organic fluorescent compound is provided to improve the fluorescence by external stimulus such as pressure, heat and light or to diversify the fluorescence color by changing only the molecular arrangement. An organic fluorescent compound is indicated as the following chemical formula (I) and is improved by the external stimulus, or is indicated as the following chemical formula (II) and is changed with the external stimulus. In the chemical formula (I), R is C-CF3, R1 is CN, R2 is H; or R is C-CF3, R1 is H, R2 is CN; or R is N, R1 is H, R2 is CN. In the chemical formula (II), R is O-(CH2)4, R1 is CN, R2 is H; or R is O-(CH2)4, R1 is H, R2 is CN.
Abstract translation: 提供有机荧光化合物以通过诸如压力，热和光的外部刺激来改善荧光，或通过仅改变分子排列来使荧光颜色多样化。 有机荧光化合物由下列化学式（I）表示，并通过外部刺激改善，或以下列化学式（II）表示，并用外部刺激改变。 在化学式（I）中，R为C-CF 3，R 1为CN，R 2为H; 或R为C-CF 3，R 1为H，R 2为CN; 或R为N，R 1为H，R 2为CN。 在化学式（Ⅱ）中，R为O-（CH2）4，R1为CN，R2为H; 或R为O-（CH 2）4，R 1为H，R 2为CN。
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公开(公告)号：KR1020090010263A
公开(公告)日：2009-01-30
申请号：KR1020070073212
申请日：2007-07-23
Applicant: 재단법인서울대학교산학협력재단
CPC classification number: C07F15/0033 , G01N21/64
Abstract: The iridium(Ir)(III)-based high degree phosphorescent fluoride receptor is provided to increase solubility in organic solvent such as toluene, methylene chloride(CH2Cl2), dioxane and acetonitrile, and detect fluoride with high selectivity and sensitivity in the solution state at room temperature. A method for manufacturing the iridium(Ir)(III)-based high degree phosphorescent fluoride receptor comprises the steps of: lithium-treating dibromobenzene in THF(tetrahydrofuran) solution at -78 deg. C with n-BuLi and treating it in THF at room temperature with dimethyl boron fluoride to create boryl phenyl bromide; dissolving the boryl phenyl bromide together with 2-(tributylstenyl)pyridine and Pd(PPh3)4 in toluene, and converting it into chelate ligand through Pd-catalyst Stille reaction; reacting the chelate ligand with IrCl3.xH2O through Nonoyama in 2-EtOEtOH:H2O solution at 140 deg. C under argon(Ar) saturated condition to create mu-chloride-bridge Ir(III) dimer; and substituting chloride by 2,4- pentanedione by aid of sodium carbonate in 2-EtOEtOH solution at 140 deg. C under argon(Ar) saturated condition.
Abstract translation: 提供基于铱（Ir）（III）的高度磷光氟化物受体以增加在有机溶剂如甲苯，二氯甲烷（CH 2 Cl 2），二恶烷和乙腈中的溶解度，并且在溶液状态下以高选择性和灵敏度检测氟化物 室内温度。 制备基于铱（Ir）（III）的高度磷光氟化物受体的方法包括以下步骤：在-78℃下在THF（四氢呋喃）溶液中将二溴苯锂处理。 用正丁基锂处理，并在室温下用二氟化硼氟化物在THF中处理，得到苯基溴苯基; 将硼烷基苯基溴与2-（三丁基苯乙烯基）吡啶和Pd（PPh 3）4在甲苯中溶解，并通过Pd催化剂Stille反应转化成螯合配体; 将螯合配体与IrCl 3·xH 2 O通过Nonoyama在140℃下在2-EtOEtOH:H 2 O溶液中反应。 在氩（Ar）饱和条件下生成氯化铵桥Ir（III）二聚体; 并用2,4-戊二酮在140℃在2-乙酸乙酯溶液中借助碳酸钠代替氯化物。 在氩气（Ar）饱和条件下。
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28.发明授权
公开(公告)号：KR100837577B1
公开(公告)日：2008-06-12
申请号：KR1020060137429
申请日：2006-12-29
Applicant: 재단법인서울대학교산학협력재단
CPC classification number: G11B7/00455 , G11B7/0052 , G11B7/00552 , G11B7/245 , G11B2007/24624
Abstract: A rewritable fluorescence memory film, and a non-destructive writing/reading/erasing method using the same are provided to repeat data recording and erasing on a fluorescence memory film of polymer composite containing fluorescent material with high Stokes' shift and BTE photochromic compound. A rewritable fluorescence memory film is formed by applying coating material on a substrate, wherein the coating material contains 10 to 30wt.% composite of fluorescent material and photochromic compound and 90 to 70wt.% matrix polymer dissolved. The fluorescent material, which is excited-state intramolecular proton transfer compound, has a maximum absorption wavelength in a range of 410 to 430nm, a maximum fluorescence emission wavelength in a range of 450 to 700nm, and a difference between the maximum absorption wavelength and maximum fluorescence emission wavelength(Stokes' Shift) in a range of 20 to 290nm. The photochromic compound emits color under irradiation of ultraviolet rays having a wavelength of 400nm or less.
Abstract translation: 提供了可重写荧光存储器膜以及使用该可擦写荧光存储膜的非破坏性写入/读出/擦除方法，以在含有高斯托克斯位移和BTE光致变色化合物的含有荧光材料的聚合物复合物的荧光存储膜上重复数据记录和擦除。 通过在基材上涂覆涂料来形成可重写荧光记忆膜，其中涂料含有10至30重量％的荧光材料和光致变色化合物的复合物和溶解的90至70重量％的基质聚合物。 作为激发态分子内质子转移化合物的荧光材料具有410〜430nm的最大吸收波长，450〜700nm范围内的最大荧光发射波长，最大吸收波长与最大吸收波长的最大值 荧光发射波长（Stokes'Shift）在20到290nm的范围内。 光致变色化合物在波长为400nm以下的紫外线的照射下发色。
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公开(公告)号：KR1020070067775A
公开(公告)日：2007-06-29
申请号：KR1020050128988
申请日：2005-12-23
Applicant: 동우 화인켐 주식회사 , 재단법인서울대학교산학협력재단
IPC: C09K11/06
Abstract: Provided are an iridium complex compound, which is capable of color control over the full luminescence region and has an excellent luminous efficiency, and an organic electrophosphorescent device using the same, which embodies full visible colors and white color through a photophysical process system. The iridium complex compound having a structure of a formula 1 follows a photophysical process luminescence mechanism in which an excitation from an iridium to a singlet state(MLCT^1, metal to ligand charge transfer) of the ligand(L) in the formula 1 occurs, inter-system crossing from the singlet state to a triplet state(MLCT^3) is generated by strong spin-orbit coupling, and inter-ligand energy transfer(ILET) to an energy level of an ancillary ligand(A) lower than the triplet state occurs.
Abstract translation: 本发明提供一种能够对整个发光区域进行颜色控制并且具有优异的发光效率的铱络合物，以及使用该铱络合物的有机电致发光器件，其通过光物理过程系统体现全部可见的颜色和白色。 具有式1结构的铱配位化合物遵循光物理过程发光机理，其中发生式1中配体（L）的铱至单重态（MLCT 1，金属与配体电荷转移）的激发 通过强自旋轨道耦合产生从单重态到三重态的系统间交叉（MLCT ^ 3），并且配体间能量转移（ILET）到辅助配体（A）的能级低于 发生三线态。
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公开(公告)号：KR100496502B1
公开(公告)日：2005-06-22
申请号：KR1020020082108
申请日：2002-12-21
Applicant: 재단법인서울대학교산학협력재단 , 동우 화인켐 주식회사
IPC: C09K19/34
Abstract: 본 발명은 하기 화학식 1로 표시되는, 벤젠 코어(core)의 1,3,5-위치에 옥사디아졸 및 에티닐 기로 공역된(conjugated) 막대형태의 치환체를 갖는, 스타형태의 디스크형 액정과 그의 제조 방법을 제공한다.
[화학식 1]
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