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公开(公告)号：KR1020140079219A
公开(公告)日：2014-06-26
申请号：KR1020120148930
申请日：2012-12-18
Applicant: 제일모직주식회사
CPC classification number: C08G69/26 , C08G69/265 , C08G69/32 , C08J5/00 , C08L77/06
Abstract: The present invention relates to a polyamide resin that is obtained by copolymerizing: (A) a dicarboxylic acid component including (a1) an aromatic dicarboxylic acid component; and (B) a diamine component including (b1) 75 to 85 mol% of an aliphatic diamine component and (b2) 15 to 25 mol% of toluene diamine. The polyamide resin according to the present invention has a repeating structure of a dicarboxylic acid part derived from the dicarboxylic acid component (A) and a diamine part derived from the diamine component (B). The polyamide resin has excellent processability, heat-resistance, and dimensional stability.
Abstract translation: 本发明涉及聚酰胺树脂，其通过以下方法获得：（A）包含（a1）芳族二羧酸组分的二羧酸组分; 和（B）包含（b1）75〜85摩尔％的脂肪族二胺成分和（b2）15〜25摩尔％的甲苯二胺的二胺成分。 本发明的聚酰胺树脂具有来自二羧酸成分（A）的二羧酸部分和由二胺成分（B）衍生的二胺部分的重复结构。 聚酰胺树脂具有优异的加工性，耐热性和尺寸稳定性。
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公开(公告)号：KR101393281B1
公开(公告)日：2014-05-09
申请号：KR1020110031525
申请日：2011-04-06
Applicant: 제일모직주식회사
Abstract: 본발명은지방족디아민단량체혼합물(A) 및폴리에스테르수지(B)를중합하여제조된폴리아미드수지에있어서, 상기지방족디아민단량체혼합물(A)은탄소수가 2개내지 6개이하를갖는지방족디아민단량체 (a1), 및상기지방족디아민단량체(a1)와탄소수가상이한단량체로서탄소수가 6개내지 12개이하인지방족디아민단량체 (a2)를포함하는것을특징으로하는폴리아미드수지및 그제조방법에관한것이다. 본발명의폴리아미드수지는내열성이우수하며, 저흡습성과색상이우수한특성을갖는다.
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公开(公告)号：KR1020130073773A
公开(公告)日：2013-07-03
申请号：KR1020110141789
申请日：2011-12-23
Applicant: 제일모직주식회사
CPC classification number: C08G69/265 , C08L77/06
Abstract: PURPOSE: A polyamide resin is provided to have excellent refractivity, excellent moldability, and melt processability. CONSTITUTION: A polyamide resin is formed by polymerization of an aromatic dicarboxylic acid, aliphatic linear diamine, and alicyclic diamine. The amount of the alicyclic diamine is 15-35 mol% with regard to 100 mol% of the sum of the aromatic dicarboxylic acid and aliphatic linear diamine. The glass transition temperature of the polyamide resin is 140 °C or more. The polyamide resin is a semi-crystalline-shaped resin. The glass transition temperature of the polyamide resin is 150 °C or more. The ratio of the melting temperature of the polyamide resin with regard to the glass transition temperature is 1.9-2.3.
Abstract translation: 目的：提供聚酰胺树脂以具有优异的折射率，优异的成型性和熔融加工性。 构成：通过芳族二羧酸，脂肪族线性二胺和脂环族二胺的聚合形成聚酰胺树脂。 相对于芳族二羧酸和脂肪族线性二胺的总和的100摩尔％，脂环族二胺的量为15〜35摩尔％。 聚酰胺树脂的玻璃化转变温度为140℃以上。 聚酰胺树脂是半结晶树脂。 聚酰胺树脂的玻璃化转变温度为150℃以上。 聚酰胺树脂的熔融温度相对于玻璃化转变温度的比例为1.9〜2.3。
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24.发明公开
公开(公告)号：KR1020130072513A
公开(公告)日：2013-07-02
申请号：KR1020110139975
申请日：2011-12-22
Applicant: 제일모직주식회사
CPC classification number: C08G69/265 , C08G69/44 , C08G69/48 , C08L77/06 , C08L77/12
Abstract: PURPOSE: A modified polyamide-based resin is provided to have excellent heat resistance, moldability, and whiteness, and to have low moisture absorption rate. CONSTITUTION: A modified polyamide-based resin includes a repeating unit derived from a dicarboxylic acid represented by chemical formula 1; and a repeating unit derived from an aliphatic saturated diamine represented by chemical formula 2. The repeating unit derived from the aliphatic saturated diamine has a carbon number different from a repeating unit derived from C2-6 aliphatic saturated diamine and a repeating unit derived from the C2-6 aliphatic saturated diamine, and includes C6-12 aliphatic saturated diamine.
Abstract translation: 目的：提供改性的聚酰胺类树脂以具有优异的耐热性，成型性和白度，并且具有低的吸湿率。 构成：改性聚酰胺类树脂包括衍生自化学式1表示的二羧酸的重复单元; 衍生自由化学式2表示的脂肪族饱和二胺的重复单元。衍生自脂肪族饱和二胺的重复单元的碳原子数不同于来自C2-6脂肪族饱和二胺的重复单元和来自C2的重复单元 -6脂肪族饱和二胺，并且包括C 6-12脂肪族饱和二胺。
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公开(公告)号：KR101236755B1
公开(公告)日：2013-02-25
申请号：KR1020090133468
申请日：2009-12-29
Applicant: 제일모직주식회사
Abstract: 본 발명에 따른 저광 특성이 우수한 내후성 열가소성 수지는 (메타)아크릴산 알킬 에스테르계 중합체(A), 폴리우레탄 예비중합체(B) 및 방향족 비닐-시안화 비닐계 공중합체(C)를 포함하며, 상기 (메타)아크릴산 알킬 에스테르계 중합체(A)와 폴리우레탄 예비중합체(B)는 우레탄 결합에 의해 연결되어 분산상을 이루고, 상기 방향족 비닐-시안화 비닐계 공중합체(C)는 연속상을 이룸으로서, 상기 열가소성 수지는 내후성, 내충격성, 내열성, 박리특성 등이 우수할 뿐만 아니라 뛰어난 저광 특성을 갖는다.
저광 특성, 내후성, 열가소성 수지, 네트워크 형상, 분산상-
Patent Agency Ranking
公开(公告)号：KR1020120040069A
公开(公告)日：2012-04-26
申请号：KR1020100101595
申请日：2010-10-18
Applicant: 제일모직주식회사
CPC classification number: C08G69/26 , C08G69/265 , C08G69/42 , C08L77/06
Abstract: PURPOSE: A polyamide resin is provided to enhance physical properties including heat resistance, mechanical strength, and brightness, thereby being suitable for a plastic joint among auto parts. CONSTITUTION: A polyamide resin is a polymer of dicarboxylic acid and an aliphatic diamine. The aliphatic diamine comprises one or more of aliphatic diamine monomers which is selected from an aliphatic diamine having 4,6,8, and 10 carbon numbers and one or more of aliphatic diamine monomers selected from aliphatic diamine having 12, 14, 16 and 18 carbon numbers. The aliphatic diamine monomers are included 0.1-70 mol% among whole aliphatic diamine components. A ratio of total moles of aliphatic diamine monomer(a1) and aliphatic diamine monomer(a2) to total moles of diamine monomers is 0.90-1.30.
Abstract translation: 目的：提供聚酰胺树脂，以提高包括耐热性，机械强度和亮度在内的物理性能，从而适用于汽车零件之间的塑料接头。 构成：聚酰胺树脂是二羧酸和脂族二胺的聚合物。 脂族二胺包含一种或多种选自具有4,6,8,10碳数的脂肪族二胺和一种或多种脂族二胺单体的脂族二胺单体，所述脂族二胺单体选自具有12,14,16和18碳的脂肪族二胺 数字。 脂肪族二胺单体的总脂肪族二胺成分含有0.1-70摩尔％。 脂肪族二胺单体（a1）和脂肪族二胺单体（a2）的总摩尔数与二胺单体的总摩尔数的比例为0.90〜1.30。
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公开(公告)号：KR101593745B1
公开(公告)日：2016-02-12
申请号：KR1020130062737
申请日：2013-05-31
Applicant: 제일모직주식회사
Abstract: 본발명의폴리아미드에스테르수지는디카르복실산; 디아민; 및선형지방족디올;의중합체이며, 상기선형지방족디올의함량은상기디아민 100 몰부에대하여, 1 내지 25 몰부이고, 용융온도(Tm)가 280 내지 320℃이고, 결정화온도(Tc)가 260 내지 290℃인것을특징으로한다. 상기폴리아미드에스테르수지는내열성, 내변색성및 성형성이우수하다.
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公开(公告)号：KR1020150026386A
公开(公告)日：2015-03-11
申请号：KR1020130105143
申请日：2013-09-02
Applicant: 제일모직주식회사
CPC classification number: C08G69/28 , C07C231/02 , C08G69/265 , C08J3/12 , C07C233/78
Abstract: 본 발명의 예비중합체 입자의 제조방법은 용액상의 예비중합체를 아래에서 위로 분사하여, 상기 용액상의 예비중합체로부터 용매를 제거하고 예비중합체 입자를 형성하는 단계를 포함하는 것을 특징으로 한다. 상기 예비중합체 입자의 제조방법은 상향식(bottom-up type) 플래시(flash) 방법을 적용하여 고상중합에 사용 가능한 예비중합체 입자를 제조할 수 있다.
Abstract translation: 预聚物颗粒的制造方法技术领域本发明涉及预聚物颗粒的制造方法，该方法包括通过从底部至顶部喷雾溶液状态预聚物，然后从溶液状态预聚物中除去溶剂来形成预聚物颗粒的步骤，其中， 预聚物颗粒使用自下而上型闪速法，因此制造用于固态聚合的预聚物。
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公开(公告)号：KR1020140141232A
公开(公告)日：2014-12-10
申请号：KR1020130062737
申请日：2013-05-31
Applicant: 제일모직주식회사
Abstract: 본 발명의 폴리아미드에스테르 수지는 디카르복실산; 디아민; 및 선형 지방족 디올;의 중합체이며, 상기 선형 지방족 디올의 함량은 상기 디아민 100 몰부에 대하여, 1 내지 25 몰부이고, 용융 온도(Tm)가 280 내지 320℃이고, 결정화 온도(Tc)가 260 내지 290℃인 것을 특징으로 한다. 상기 폴리아미드에스테르 수지는 내열성, 내변색성 및 성형성이 우수하다.
Abstract translation: 本发明的聚酰胺酯树脂是以下的聚合物：二羧酸; 二胺; 和直链脂族二醇，其中线性脂肪族二醇的含量相对于100摩尔二胺为1〜25摩尔份; 熔融温度（Tm）为280〜320℃; 结晶温度（Tc）为260〜290℃。 聚酰胺酯树脂具有优异的耐热性，耐变色性和成型性。
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公开(公告)号：KR1020140086769A
公开(公告)日：2014-07-08
申请号：KR1020120157671
申请日：2012-12-28
Applicant: 제일모직주식회사
CPC classification number: C08G69/44 , C08L67/02 , C09J177/12 , C08F283/02 , C08J5/00 , C08L77/12
Abstract: A polyamide ester resin of the present invention has a structure whereby a dicarboxylic acid part induced from a dicarboxylic acid ingredient (A), a diamine ingredient part induced from a diamine ingredient (B), and a cycloaliphatic diol part induced from a cycloaliphatic diol ingredient (C) are repeated by copolymerizing the dicarboxylic acid ingredient (A), the diamine ingredient (B) and the cycloaliphatic diol ingredient (C). A mole ratio ((B):(C)) of the diamine ingredient (B) and the cycloaliphatic diol ingredient (C) is 80-99:1-20. A melting temperature (Tm) is 280-320°C, and a crystallization temperature (Tc) is 260-290°C. The crystalline polyamide ester resin has excellent heat resistance, discoloration resistance, and formability.
Abstract translation: 本发明的聚酰胺酯树脂具有由二羧酸成分（A）诱导的二羧酸成分，由二胺成分（B）诱导的二胺成分成分和脂环族二醇成分的脂环族二醇成分 （C）通过使二羧酸成分（A），二胺成分（B）和脂环族二醇成分（C）共聚而重复。 二胺成分（B）和脂环族二醇成分（C）的摩尔比（（B）:( C））为80-99：1-20。 熔融温度（Tm）为280〜320℃，结晶温度（Tc）为260〜290℃。 结晶性聚酰胺酯树脂具有优异的耐热性，耐变色性和成形性。
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