公开(公告)号：KR1020090070423A

公开(公告)日：2009-07-01

申请号：KR1020070138435

申请日：2007-12-27

Applicant: 제일모직주식회사

Inventor： 장기보 ,  하두한 ,  정동욱 ,  김유호

IPC: C08F279/06 ,  C08F265/06

CPC classification number: C08F279/06 ,  C08F265/06

Abstract: An acrylic resin is provided to ensure excellent transparency and softness, good weather resistance, and low toxicity compared with a soft polyvinylchloride, and to be applied to auto parts, housing of electric and electronic appliance, films, sheets and tubes. A method for manufacturing a transparent and soft acrylic resin comprises the steps of: polymerizing a monomer mixture including a methacrylate-based monomer, an alkyl acrylate-based monomer and a styrene-based monomer to prepare a first polymer having a refractive index of 1.49 ± 0.005 and a glass transition temperature of 10-20 °C; adding the monomer mixture to the first polymer to become a glass transition temperature of 0-10 °C and performing graft growth reaction of the added mixture; injecting the monomer mixture in the second polymer to become a glass transition temperature of 60-90 °C and performing polymerization to prepare the third polymer.

Abstract translation: 提供丙烯酸树脂以确保优异的透明度和柔软性，良好的耐候性和与柔性聚氯乙烯相比的低毒性，并且应用于汽车部件，电气和电子设备的壳体，薄膜，片材和管材。 一种制造透明和软性丙烯酸树脂的方法包括以下步骤：使包含甲基丙烯酸酯基单体，丙烯酸烷基酯单体和苯乙烯基单体的单体混合物聚合，制备折射率为1.49± 0.005，玻璃化转变温度10-20℃; 将单体混合物加入到第一聚合物中以变成0-10℃的玻璃化转变温度并进行所加混合物的接枝生长反应; 将第一聚合物中的单体混合物注入到玻璃化转变温度为60-90℃并进行聚合以制备第三聚合物。

公开(公告)号：KR1020090062488A

公开(公告)日：2009-06-17

申请号：KR1020070129779

申请日：2007-12-13

Applicant: 제일모직주식회사

Inventor： 전재욱 ,  하두한 ,  정동욱

IPC: C08F279/04 ,  C08F279/00

CPC classification number: C08F279/04 ,  C08F2/24 ,  C08F2/38 ,  C08F4/34

Abstract: A graft copolymer is provided to minimize volatile organic compounds, to ensure excellent flowabillity, outer appearance, mechanical strength and thermal stability, good polymerization stability and excellent degree of grafting. A method for preparing a graft copolymer minimizing emission of volatile organic compounds comprises the steps of: polymerizing rubbery polymer latex and a graft monomer mixture in the presence of a polymerization initiator to prepare a first graft copolymer latex; injecting the balance of a graft monomer mixture in the first graft copolymer latex and at the same time, injecting a first polymerization initiator through 2-5 hours and then injecting a second polymerization initiator to perform polymerization .

Abstract translation: 提供接枝共聚物以使挥发性有机化合物最小化，以确保优异的流动性，外观，机械强度和热稳定性，良好的聚合稳定性和优异的接枝度。 一种制备接枝共聚物使挥发性有机化合物的排放最小化的方法包括以下步骤：在聚合引发剂存在下聚合橡胶状聚合物胶乳和接枝单体混合物以制备第一接枝共聚物胶乳; 在第一接枝共聚物胶乳中注入接枝单体混合物的余量，同时将第一聚合引发剂注入2-5小时，然后注入第二聚合引发剂进行聚合。

公开(公告)号：KR1020090058745A

公开(公告)日：2009-06-10

申请号：KR1020070125483

申请日：2007-12-05

Applicant: 제일모직주식회사

Inventor： 정동욱 ,  장기보 ,  김유호

IPC: C08F279/00 ,  C08F279/06

CPC classification number: C08F279/06 ,  C08F2/24 ,  C08L51/04

Abstract: An impact reinforcing copolymer is provided to increase chemical affinity by copolymerizing an epoxide compound to an intermediate layer and a hard part and to improve impact reinforcement of polyvinyl chloride, polycarbonate, polyethyl terephthalate and polyamide. A method for manufacturing an impact reinforcing copolymer comprises the steps of: graft-polymerizing a diene-based rubber and an aromatic vinyl-based monomer to prepare a first graft polymer; adding an epoxide compound to the first graft polymer and then polymerizing the materials to prepare a second graft polymer; and injecting alkyl(meth)acrylate in the second graft polymer and then polymerizing the materials. The thermoplastic resin composition comprises (A) thermoplastic resin 70-99 weight% and (B) the impact reinforcing copolymer 1-30 weight%.

Abstract translation: 提供抗冲击增强共聚物以通过将环氧化合物与中间层和硬部分共聚来提高化学亲和力，并改善聚氯乙烯，聚碳酸酯，聚对苯二甲酸乙二醇酯和聚酰胺的冲击强化。 一种冲击增强共聚物的制造方法，其特征在于，使二烯类橡胶和芳族乙烯基系单体接枝聚合，制备第一接枝聚合物。 向第一接枝聚合物中加入环氧化合物，然后聚合该材料以制备第二接枝聚合物; 并在第二接枝聚合物中注入（甲基）丙烯酸烷基酯，然后使该材料聚合。 热塑性树脂组合物包含（A）70-99重量％的热塑性树脂和（B）1-30重量％的冲击增强共聚物。

公开(公告)号：KR100865497B1

公开(公告)日：2008-10-27

申请号：KR1020060137126

申请日：2006-12-28

Applicant: 제일모직주식회사

Inventor： 장기보 ,  하두한 ,  정동욱 ,  정재훈

IPC: C08F279/02 ,  C08F279/00 ,  C08L55/00

CPC classification number: C08F279/02 ,  C08F265/04 ,  C08F265/06 ,  C08L33/12 ,  C08L51/003 ,  C08L51/04 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/04

Abstract: 본 발명은 모노머인 본 발명의 충격보강제는 디엔계 모노머 30∼45 중량% 및 알킬 아크릴레이트 55∼70 중량%가 산화방지제 존재 하에서 중합된 중합된 고무질 중합체 45∼70 중량부에 메타크릴레이트계 모노머 30∼55 중량부가 그라프트 중합되어 이루어지는 내스크래치 수지의 충격보강제에 관한 것이다. 본 발명에 따른 충격보강제를 적용한 메타크릴레이트계 수지 조성물은 투명성 및 내충격성을 향상시키면서 우수한 표면 특성을 발현한다.
고무질 중합체, 메틸메타크릴레이트, 개시제, 가교제, 분자량 조절제, 전해질, 유화제, 산화 방지제, 내충격성, 투명성