公开(公告)号：KR1020040014765A

公开(公告)日：2004-02-18

申请号：KR1020020047422

申请日：2002-08-12

Applicant: 제일모직주식회사

Inventor： 최규성 ,  정봉재 ,  박응서

IPC: C08F255/00

Abstract: PURPOSE: A thermoplastic resin composition and its preparation method are provided, to improve the impact resistance, the transparency and the moisture resistance. CONSTITUTION: The method comprises the steps of inputting 40-60 parts by weight of a monomer mixture comprising an acrylonitrile monomer, a styrene-based monomer and an alkyl methacrylate and 0.1-0.5 parts by weight of a hydroperoxide-based oil-soluble initiator to a reactor in the presence of 40-60 parts by weight of a rubbery polymer latex with an average particle diameter of 0.2-0.5 micrometers, adding an emulsifier and an auxiliary initiator and graft polymerizing the monomers; inputting 0.3-0.8 parts by weight of a water-soluble initiator to the reactor when the polymerization conversion rate reaches 90 %, inputting the monomer mixture continuously or several times for 1-3 hours and graft polymerizing the monomers; and coagulating the graft polymerized latex at a coagulation bath containing a metal-based electrolyte coagulant and a strong acid coagulant. The monomer mixture comprises 30-80 wt% of an alkyl methacrylate, 10-40 wt% of an aromatic vinyl compound and 1-20 wt% of an unsaturated nitrile compound, and 10-30 wt% of the monomer mixture is inputted at the first step and the rest (70-90 wt%) is at the second step.

Abstract translation: 目的：提供热塑性树脂组合物及其制备方法，以提高耐冲击性，透明性和耐湿性。 方案：该方法包括以下步骤：输入40-60重量份的包含丙烯腈单体，苯乙烯基单体和甲基丙烯酸烷基酯的单体混合物和0.1-0.5重量份基于氢过氧化物的油溶性引发剂， 在40-60重量份平均粒径为0.2-0.5微米的橡胶状聚合物胶乳的存在下加入反应器，加入乳化剂和辅助引发剂并使单体接枝聚合; 当聚合转化率达到90％时，向反应器输入0.3-0.8重量份的水溶性引发剂，连续输入单体混合物或多次1-3小时，接枝聚合单体; 并在含有金属基电解质凝结剂和强酸凝结剂的凝固浴中使接枝聚合的胶乳凝结。 单体混合物包含30-80重量％的甲基丙烯酸烷基酯，10-40重量％的芳族乙烯基化合物和1-20重量％的不饱和腈化合物，并且10-30重量％的单体混合物在 第一步，其余（70-90重量％）处于第二步。

公开(公告)号：KR1020030042625A

公开(公告)日：2003-06-02

申请号：KR1020010073350

申请日：2001-11-23

Applicant: 제일모직주식회사

Inventor： 정봉재 ,  최규성 ,  김성열

IPC: C08F279/02

CPC classification number: C08F279/02 ,  C08F2/24

Abstract: PURPOSE: A thermoplastic resin composition having excellent impact resistance under high humidity, and improved transparency, natural colors and moisture resistance is provided. CONSTITUTION: The thermoplastic resin composition is produced by the process comprising the steps of: (a) introducing 40 to 60 wt% of a monomer mixture(B) consisting of an acrylonitrile monomer, styrene monomer and alkyl methacrylate in the presence of 60 to 40 wt%(based on solid contents) of an elastomeric polymer latex(A) having an average particle diameter of 0.2 to 0.5 micrometers, together with ion exchanged water, 0.5 to 1.0 parts by weight of an emulsifier, 0.1 to 1.0 parts by weight of a molecular weight modifier and 0.05 to 0.5 parts by weight of an oil-soluble peroxide initiator into a reactor, raising the temperature to 50 to 80 deg.C and adding a mixture of an initiation catalyst, a reducing agent and a complexing agent to perform a graft polymerization; and (b) introducing 0.3 to 1.0 parts by weight of a water soluble polymerization initiator when the conversion in the preceding step is more than 90%, and further introducing the monomer mixture(B) for 1 to 5 hours divisionally at several times or continuously to perform a graft polymerization.

Abstract translation: 目的：提供在高湿度下具有优异的耐冲击性，透明性，天然色泽和耐湿性的热塑性树脂组合物。 构成：热塑性树脂组合物的制造方法包括以下步骤：（a）在60〜40的存在下，引入40〜60重量％的由丙烯腈单体，苯乙烯单体和甲基丙烯酸烷基酯组成的单体混合物（B） 平均粒径为0.2〜0.5微米的弹性体聚合物胶乳（A）与离子交换水，0.5〜1.0重量份乳化剂，0.1〜1.0重量份的乳化剂， 分子量调节剂和0.05〜0.5重量份的油溶性过氧化物引发剂加入到反应器中，将温度升至50至80℃，并加入起始催化剂，还原剂和络合剂的混合物进行 接枝聚合; 和（b）当上述步骤中的转化率大于90％时，引入0.3至1.0重量份的水溶性聚合引发剂，并且进一步将该单体混合物（B）分几次或连续引入1至5小时 进行接枝聚合。

公开(公告)号：KR1020080062499A

公开(公告)日：2008-07-03

申请号：KR1020060138397

申请日：2006-12-29

Applicant: 제일모직주식회사

Inventor： 정봉재 ,  하두한

IPC: G11B7/245 ,  G11B7/241

Abstract: A compact disk using MABS(methylmethacrylate-acrylonitrile-butadiene-styrene) copolymer resin is provided to increase fluidity, rigidity, and elongation of the compact disk, and data storage as well as to reduce manufacturing costs of the disk. A compact disk is made out of MABS(methylmethacrylate-acrylonitrile-butadiene-styrene) copolymer resin. Rubber of the MABS copolymer resin is selected from a group consisting of polybutadiene, butadiene-styrene copolymer, polyisoprene, butadiene-acrylonitrile copolymer, isobutylene-isoprene copolymer, ethylene-propylene rubber, acrylic rubber, urethane rubber, and silicon rubber, wherein the content of rubber in the MABS copolymer resin is 12 to 18 weight%.

Abstract translation: 提供使用MABS（甲基丙烯酸甲酯 - 丙烯腈 - 丁二烯 - 苯乙烯）共聚物树脂的光盘，以增加光盘的流动性，刚性和伸长率，以及数据存储以及降低盘的制造成本。 光盘由MABS（甲基丙烯酸甲酯 - 丙烯腈 - 丁二烯 - 苯乙烯）共聚物树脂制成。 MABS共聚物树脂的橡胶选自聚丁二烯，丁二烯 - 苯乙烯共聚物，聚异戊二烯，丁二烯 - 丙烯腈共聚物，异丁烯 - 异戊二烯共聚物，乙烯 - 丙烯橡胶，丙烯酸橡胶，聚氨酯橡胶和硅橡胶，其中含量 的MABS共聚物树脂中的橡胶为12〜18重量％。

公开(公告)号：KR1020070108008A

公开(公告)日：2007-11-08

申请号：KR1020060040708

申请日：2006-05-04

Applicant: 제일모직주식회사

Inventor： 하두한 ,  정봉재

IPC: C08L33/08 ,  C08L15/00

CPC classification number: C08L33/04 ,  C08F285/00 ,  C08L51/003 ,  C08L51/04 ,  C08F220/12 ,  C08L2666/24 ,  C08L2666/04

Abstract: A resin composition having good scratch resistance is provided to ensure well-balanced physical properties such as a coloring property, weather resistance, gloss, impact resistance, and etc. A resin composition having good scratch resistance has an outer shell comprising 5-50 parts by weight of a core-shell structure graft resin(A) containing a (meth)acrylic acid alkyl ester component and 95-50 parts by weight of a resin(B) containing 40-100% of a (meth)acrylic acid alkyl ester component. The outer shell is a polymethylmethacrylate resin. In the core-shell structure graft resin(A), the core is butadiene rubber or butadiene/styrene rubber polymer.

Abstract translation: 提供具有良好耐擦伤性的树脂组合物，以确保良好平衡的物理性能如着色性，耐候性，光泽，耐冲击性等。具有良好耐擦伤性的树脂组合物具有外壳，其包含5-50份 含有（甲基）丙烯酸烷基酯组分的核 - 壳结构接枝树脂（A）和95-50重量份含有40-100％（甲基）丙烯酸烷基酯组分的树脂（B） 。 外壳是聚甲基丙烯酸甲酯树脂。 在核 - 壳结构接枝树脂（A）中，芯是丁二烯橡胶或丁二烯/苯乙烯橡胶聚合物。

公开(公告)号：KR100714905B1

公开(公告)日：2007-05-04

申请号：KR1020050133133

申请日：2005-12-29

Applicant: 제일모직주식회사

Inventor： 정봉재 ,  하두한

IPC: C08L55/02 ,  C08L91/00

Abstract: 본 발명에 따른 열가소성 수지 조성물은 (A) 투명 ABS 수지 100 중량부; (B) 글리세릴계 포화지방산 0.1∼10 중량부; 및 (C) 미네랄 오일 0.05∼0.5 중량부로 이루어지는 것을 특징으로 한다.
메틸메타아크릴레이트-아크릴로니트릴-부타디엔-스티렌 수지, 투명 ABS 수지, 글리세릴계 포화지방산, 미네랄 오일, 투명성, 내습성

Abstract translation: 根据本发明的热塑性树脂组合物包含（A）100重量份的透明ABS树脂; （B）甘油饱和脂肪酸0.1〜10重量份; （C）0.05〜0.5重量份的矿物油。

公开(公告)号：KR100507336B1

公开(公告)日：2005-08-08

申请号：KR1020020080431

申请日：2002-12-16

Applicant: 제일모직주식회사

Inventor： 정봉재 ,  최규성

IPC: C08F279/02

Abstract: 본 발명의 내열성과 내충격성이 우수한 열가소성 수지의 제조방법은 평균입경이 0.2-0.5 ㎛인 부타디엔계 고무라텍스에 그라프트 단량체로 방향족비닐 화합물, 불포화니트릴 화합물, 메타크릴산알킬에스테르 및 알킬아크릴레이트의 조합비율이 각각 10∼40 중량%, 1∼20 중량%, 50∼80 중량% 및 1∼10중량%인 단량체 혼합물 및 유용성 산화환원 중합개시제를 투입하여 그라프트 중합하는 제1단계; 및 제1단계 그라프트중합의 전환율이 90% 이상에 이르면 수용성 열분해성 중합개시제 및 상기 단량체 혼합물을 투입하여 그라프트 공중합하는 제2단계로 이루어지고, 상기 단량체 혼합물은 제1단계에서 10-30 중량%, 제2단계에서 90-70 중량%로 투입하는 것을 특징으로 한다.

公开(公告)号：KR100469864B1

公开(公告)日：2005-02-02

申请号：KR1020010086696

申请日：2001-12-28

Applicant: 제일모직주식회사

Inventor： 최규성 ,  김태욱 ,  정봉재

IPC: C08F279/02

Abstract: PURPOSE: A thermoplastic resin composition having improved laser marking property for white letters, impact resistance, formability, whiteness and sharpness is provided. CONSTITUTION: The thermoplastic resin composition comprises: (A) 20 to 50 parts by weight of a rubbery polymer comprising 30 to 60 parts by weight (based on solid content) of a rubber(a1) having an average particle diameter of 0.1 to 0.2 micrometers and 70 to 40 wt% (based on solid content) of a rubber(a2) having an average particle diameter of 0.3 to 0.6 micrometers; (B) 80 to 50 parts by weight of a monomer mixture comprising 10 to 40 wt% of an aromatic vinyl monomer, 3 to 20 wt% of an unsaturated nitrile monomer and 40 to 80 wt% of an alkyl methacrylate monomer; (C) 0.5 to 1.5 parts by weight of a molecular weight modifier comprising a mixture of mercaptan and terpinolene or alpha-methyl styrene oligomer; (D) 0.2 to 1.0 parts by weight of a coloring pigment; and (E) 0.2 to 1.0 parts by weight of a silicate compound.

Abstract translation: 目的：提供一种具有改进的用于白色字母，耐冲击性，可成形性，白度和清晰度的激光标记性能的热塑性树脂组合物。 本发明的热塑性树脂组合物包含：（A）20-50重量份的橡胶状聚合物，该橡胶状聚合物包含30-60重量份（基于固体含量）的平均粒径为0.1-0.2微米的橡胶（a1） 和70-40重量％（基于固体含量）的平均粒径为0.3-0.6微米的橡胶（a2） （B）80至50重量份的包含10至40重量％的芳族乙烯基单体，3至20重量％的不饱和腈单体和40至80重量％的甲基丙烯酸烷基酯单体的单体混合物; （C）0.5-1.5重量份的包含硫醇和萜品油烯或α-甲基苯乙烯低聚物的混合物的分子量调节剂; （D）0.2至1.0重量份的着色颜料; 和（E）0.2-1.0重量份硅酸盐化合物。

公开(公告)号：KR100418494B1

公开(公告)日：2004-02-14

申请号：KR1020000083861

申请日：2000-12-28

Applicant: 제일모직주식회사

Inventor： 정봉재 ,  이시춘

IPC: C08L55/02

Abstract: PURPOSE: Provided is a styrene-based thermoplastic composite material with improved impact strength and flame retardancy, which contains a rubber modified styrene-based graft copolymer and a styrene-based copolymer. CONSTITUTION: The styrene-based thermoplastic composite material comprises: (A) 5-95pts.wt. of the rubber modified styrene-based graft copolymer obtained by graft-polymerizing (a1) 5-95pts.wt. of a monomer mixture comprising 50-95wt% of styrene, alpha-methyl styrene, halogen or alkyl substituted styrene and 50-5wt% of acrylonitrile, methacrylonitrile, C1-C8 methacrylic acid alkyl ester, maleic anhydride, and etc. and (a2) 95-5pts.wt. of a polymer selected from butadiene rubber, acryl rubber, ethylene/propylene rubber, styrene/ butadiene rubber, and etc.; (B) 95-5pts.wt. of the styrene-based copolymer, obtained by copolymerizing (b1) 50-95wt% of styrene, alpha-methyl styrene, halogen or alkyl substituted styrene and (b2) 5-50wt% of acrylonitrile, methacrylonitrile, C1-C8 methacrylic acid alkyl ester, maleic anhydride, and etc., or a mixture thereof; (C) 5-50pts.wt.(based on the (A)+(B) of 100pts.wt.) of glass fiber treated by a silane-based coupling agent; (D) 0.05-5pts.wt.(based on the (A)+(B) of 100pts.wt.) of an amino silane-based coupling agent; (E) 5-30pts.wt.(based on the (A)+(B) of 100pts.wt.) of a fused halogen compound; 1-10pts.wt.(based on the (A)+(B) of 100pts.wt.) of antimony trioxide.

Abstract translation: 目的：提供一种具有改进的冲击强度和阻燃性的苯乙烯基热塑性复合材料，其包含橡胶改性的苯乙烯基接枝共聚物和苯乙烯基共聚物。 构成：苯乙烯基热塑性复合材料包含：（A）5-95pts.wt。 的由（a1）5-95pts.wt。接枝聚合得到的橡胶改性苯乙烯基接枝共聚物。 苯乙烯，α-甲基苯乙烯，卤素或烷基取代的苯乙烯和50-5重量％的丙烯腈，甲基丙烯腈，C1-C8甲基丙烯酸烷基酯，马来酸酐等的单体混合物和（a2） 95-5pts.wt。 的选自丁二烯橡胶，丙烯酸橡胶，乙烯/丙烯橡胶，苯乙烯/丁二烯橡胶等的聚合物; （B）95-5pts.wt。 （b1）50-95wt％的苯乙烯，α-甲基苯乙烯，卤素或烷基取代的苯乙烯和（b2）5-50wt％的丙烯腈，甲基丙烯腈，C1-C8甲基丙烯酸烷基酯共聚得到的苯乙烯基共聚物 ，马来酸酐等，或其混合物; （C）基于硅烷基偶联剂处理的玻璃纤维的5-50重量份（基于100重量份的（A）+（B））; （D）0.05-5重量份（基于100重量份的（A）+（B））氨基硅烷基偶联剂; （E）5-30pts.wt。（基于（A）+（B）100pts.wt。）的稠合卤素化合物; （基于（A）+（B）100pts.wt。）三氧化锑。

公开(公告)号：KR1020030095539A

公开(公告)日：2003-12-24

申请号：KR1020020032786

申请日：2002-06-12

Applicant: 제일모직주식회사

Inventor： 정봉재 ,  최규성

IPC: C08F279/04

CPC classification number: C08F279/04 ,  C08F2/24

Abstract: PURPOSE: Provided is a thermoplastic resin composition, which has excellent impact strength, efflorescence resistance and transparency suitable to be used in an electronic or automobile component, an office instrument and a toy material. CONSTITUTION: The thermoplastic resin composition is produced by the method comprising the steps of: (i) introducing 60-40 parts by weight of a monomer mixture(B) containing an acrylonitrile monomer, a styrene monomer and an alkyl methacrylate together with deionized water, an emulsifier, a molecular weight modifier and a peroxide based oil soluble initiator, in the presence of 40-60 part by weight (solid content basis) of a rubbery polymer latex(A) having an average particle diameter of 0.07-0.15 micrometers, into a reactor, increasing the temperature to 50-80 deg.C, and adding a initiation catalyst, a reducing agent and a complexing agent to perform the graft polymerization; and (ii) introducing a water soluble initiator and adding the monomer mixture(B) for 1-5 hours to perform the graft polymerization, when the polymerization conversion reaches 90% or more in the step (i), wherein 10-30 wt% of the monomer mixture(B) is introduced in the step (i) and 90-70 wt% of the monomer mixture(B) is introduced in the step (ii).

Abstract translation: 目的：提供一种热塑性树脂组合物，其具有优异的冲击强度，耐风化性和适用于电子或汽车部件，办公用品和玩具材料的透明性。 构成：通过包括以下步骤的方法制备热塑性树脂组合物：（i）将60-40重量份含有丙烯腈单体，苯乙烯单体和甲基丙烯酸烷基酯的单体混合物（B）与去离子水一起引入， 在40-60重量份（基于固体含量）的平均粒径为0.07-0.15微米的橡胶状聚合物胶乳（A）的存在下，将乳化剂，分子量调节剂和基于过氧化物的油溶性引发剂进入 反应器，将温度升至50-80℃，并加入起始催化剂，还原剂和络合剂进行接枝聚合; 在步骤（i）中，当聚合转化率达到90％以上时，引入水溶性引发剂并加入单体混合物（B）1-5小时进行接枝聚合，其中10-30重量％ 的单体混合物（B）引入步骤（i）中，并且在步骤（ii）中引入90-70重量％的单体混合物（B）。

公开(公告)号：KR1020030056479A

公开(公告)日：2003-07-04

申请号：KR1020010086696

申请日：2001-12-28

Applicant: 제일모직주식회사

Inventor： 최규성 ,  김태욱 ,  정봉재

IPC: C08F279/02

CPC classification number: C08F279/02 ,  C08F2/38

Abstract: PURPOSE: A thermoplastic resin composition having improved laser marking property for white letters, impact resistance, formability, whiteness and sharpness is provided. CONSTITUTION: The thermoplastic resin composition comprises: (A) 20 to 50 parts by weight of a rubbery polymer comprising 30 to 60 parts by weight (based on solid content) of a rubber(a1) having an average particle diameter of 0.1 to 0.2 micrometers and 70 to 40 wt% (based on solid content) of a rubber(a2) having an average particle diameter of 0.3 to 0.6 micrometers; (B) 80 to 50 parts by weight of a monomer mixture comprising 10 to 40 wt% of an aromatic vinyl monomer, 3 to 20 wt% of an unsaturated nitrile monomer and 40 to 80 wt% of an alkyl methacrylate monomer; (C) 0.5 to 1.5 parts by weight of a molecular weight modifier comprising a mixture of mercaptan and terpinolene or alpha-methyl styrene oligomer; (D) 0.2 to 1.0 parts by weight of a coloring pigment; and (E) 0.2 to 1.0 parts by weight of a silicate compound.

Abstract translation: 目的：提供具有白色字母，耐冲击性，成形性，白度和清晰度的改善的激光标记性能的热塑性树脂组合物。 构成：热塑性树脂组合物包含：（A）20〜50重量份的包含平均粒径为0.1至0.2微米的橡胶（a1）30-60重量份（基于固体含量）的橡胶状聚合物 和70〜40重量％（基于固体成分）的平均粒径为0.3〜0.6微米的橡胶（a2）; （B）80〜50重量份含有10〜40重量％芳族乙烯基单体，3〜20重量％的不饱和腈单体和40〜80重量％的甲基丙烯酸烷基酯单体的单体混合物; （C）0.5至1.5重量份的包含硫醇和萜品油烯或α-甲基苯乙烯低聚物的混合物的分子量调节剂; （D）0.2〜1.0重量份着色颜料; 和（E）0.2〜1.0重量份的硅酸盐化合物。