公开(公告)号：KR1020040082067A

公开(公告)日：2004-09-24

申请号：KR1020030016683

申请日：2003-03-18

Applicant: 한국과학기술연구원

Inventor： 이병권 ,  임종성 ,  문동주 ,  한만석

IPC: C09K5/04

CPC classification number: C09K5/045 ,  C09K2205/122 ,  C09K2205/22 ,  C09K2205/47

Abstract: PURPOSE: A cooling fluid composition for low temperature is provided, to obtain a novel cooling fluid composition which contains no CFC and HCFC and can replace R-502 destroying the ozone layer. CONSTITUTION: The cooling fluid composition comprises 10-60 wt% of difluoromethane (CH2F2, HFC-32); 5-75 wt% of pentafluoroethane (CHF2CF3, HFC-125); and 15-35 wt% of 1,1,2,2-tetrafluoroethane (CHF2CHF2, HFC-134). Also the cooling fluid composition comprises 10-70 wt% of difluoromethane (CH2F2, HFC-32); 10-82 wt% of pentafluoroethane (CHF2CF3, HFC-125); and 8-20 wt% of 1,1-difluoroethane (CH3CHF2, HFC-152a).

Abstract translation: 目的：提供一种用于低温的冷却液组合物，以获得不含CFC和HCFC的新型冷却液组合物，可代替破坏臭氧层的R-502。 构成：冷却液组合物包含10-60重量％的二氟甲烷（CH 2 F 2，HFC-32）; 5-75重量％的五氟乙烷（CHF 2 CF 3，HFC-125）; 和15-35重量％的1,1,2,2-四氟乙烷（CHF 2 CHF 2，HFC-134）。 冷却流体组合物还包含10-70重量％的二氟甲烷（CH 2 F 2，HFC-32）; 10-82重量％的五氟乙烷（CHF 2 CF 3，HFC-125）; 和8-20重量％的1,1-二氟乙烷（CH 3 CHF 2，HFC-152a）。

公开(公告)号：KR1020030030753A

公开(公告)日：2003-04-18

申请号：KR1020010063114

申请日：2001-10-12

Applicant: 한국과학기술연구원

Inventor： 임종성 ,  이윤우 ,  김재덕 ,  김용호

IPC: B22F3/04

CPC classification number: B22F3/225 ,  B22F3/1025 ,  B22F2998/00 ,  B22F2999/00 ,  C04B35/63 ,  C04B35/632 ,  C04B35/634 ,  C04B35/63408 ,  C04B35/638 ,  C04B2235/3847 ,  C04B2235/405 ,  C04B2235/5436 ,  C04B2235/6022 ,  B22F2202/03 ,  B22F2201/04

Abstract: PURPOSE: Provided is a defatting method of waxes from molded products using complex fluid which uses complex fluid of carbon dioxide and propane to eliminate low molecular binders like waxes from the molded products beyond critical temperature and pressure so that it improves the flow of minute solid powder among the binders. CONSTITUTION: The defatting method of the waxes from the molded products using complex fluid comprises the steps of: (i) putting a sample of the molded products to a defatting vessel; (ii) using a high pressure liquid pump to compress the complex fluid of 90wt% of carbon dioxide and 10wt% of propane with keeping temperature constant; and (iii) when the complex fluid reaches an ultracritical condition, beginning to eliminate the wanted binder among the sample.

Abstract translation: 目的：提供使用复杂流体的成型产品的蜡的脱脂方法，其使用二氧化碳和丙烷的复杂流体来消除低分子粘合剂如来自模制产品的蜡超过临界温度和压力，从而改善了分散固体粉末的流动 在粘合剂中。 构成：使用复杂流体的来自成型制品的蜡的脱脂方法包括以下步骤：（i）将模制产品的样品放入脱脂容器中; （ii）使用高压液体泵压缩90重量％二氧化碳和10重量％丙烷的复合流体，保持温度恒定; 和（iii）当复合流体达到超临界状态时，开始消除样品中所需的粘合剂。

公开(公告)号：KR1020020067354A

公开(公告)日：2002-08-22

申请号：KR1020010007884

申请日：2001-02-16

Applicant: 한국과학기술연구원

Inventor： 이병권 ,  임종성 ,  김홍곤 ,  김창년

IPC: C09K5/04

CPC classification number: C09K5/045 ,  C09K2205/12 ,  C09K2205/43

Abstract: PURPOSE: A mixture coolant composition is provided, which can replace chlorodifluoromethane(CHClF2, referred as HCFC-22), does not destroy an ozone layer and is used in a refrigerator and an air conditioner for a car. CONSTITUTION: The mixture coolant composition comprises 50-60 wt% of difluoromethane(HFC-32); 10-30 wt% of 1,1,1,2-tetrafluoroethane(HFC-134a); 10-20 wt% of 1,1,1,2,3,3,3,-heptafluoropropane(HFC-227ea); and 5-15 wt% of isobutane(R-600a). The mixture coolant composition comprises 50-70 wt% of HFC-32; 10-30 wt% of HFC-134a; 10-20 wt% of HFC-227ea; and 5-15 wt% of 1,1,1,2,3,3-hexafluoropropane(HFC-2363a). The mixture coolant composition comprises 50-70 wt% of HFC-32; 10-30 wt% of HFC-134a; 10-20 wt% of HFC-227ea; and 5-12 wt% of butane(R-600). Also the mixture coolant composition comprises 40-70 wt% of HFC-32; 10-40 wt% of 1,1-difluoroethane(HFC-152a); 10-20 wt% of HFC-227ea; and 5-15 wt% of one selected from the group consisting of R-600a. The mixture coolant composition comprises 50-70 wt% of HFC-32; 10-40 wt% of HFC-152a; 10-20 wt% of HFC-227ea; and 5-15 wt% of HFC-2363a. The mixture coolant composition comprises 40-70 wt% of HFC-32; 10-40 wt% of HFC-152a; 10-20 wt% of HFC-227ea; and 5-12 wt% of R-600.

Abstract translation: 目的：提供混合的冷却剂组合物，其可以替代氯二氟甲烷（CHClF 2，称为HCFC-22），不破坏臭氧层，并用于冰箱和汽车空调。 构成：混合物冷却剂组合物包含50-60重量％的二氟甲烷（HFC-32）; 10-30重量％的1,1,1,2-四氟乙烷（HFC-134a）; 10-20重量％的1,1,1,2,3,3,3， - 七氟丙烷（HFC-227ea）; 和5-15重量％的异丁烷（R-600a）。 混合物冷却剂组合物包含50-70重量％的HFC-32; 10-30重量％的HFC-134a; 10-20重量％的HFC-227ea; 和5-15重量％的1,1,1,2,3,3-六氟丙烷（HFC-2363a）。 混合物冷却剂组合物包含50-70重量％的HFC-32; 10-30重量％的HFC-134a; 10-20重量％的HFC-227ea; 和5-12重量％的丁烷（R-600）。 混合冷却剂组合物还包含40-70重量％的HFC-32; 10-40重量％的1,1-二氟乙烷（HFC-152a）; 10-20重量％的HFC-227ea; 和5-15重量％的选自R-600a的一种。 混合物冷却剂组合物包含50-70重量％的HFC-32; 10-40重量％的HFC-152a; 10-20重量％的HFC-227ea; 和5-15重量％的HFC-2363a。 混合物冷却剂组合物包含40-70重量％的HFC-32; 10-40重量％的HFC-152a; 10-20重量％的HFC-227ea; 和5-12重量％的R-600。

公开(公告)号：KR100340275B1

公开(公告)日：2002-06-12

申请号：KR1019990048069

申请日：1999-11-02

Applicant: 한국과학기술연구원

Inventor： 임종성 ,  이병권 ,  김재덕 ,  이상득 ,  김훈식

IPC: C09K5/04

CPC classification number: C09K5/045 ,  C09K2205/12 ,  C09K2205/43

Abstract: 본발명은제1 성분으로서디플루오로메탄(CHF, 이하 HFC-32), 제2 성분으로서펜타플루오로에탄(CHFCF, 이하 HFC-125), 제3 성분으로서 1,1,1,2-테트라플루오로에탄 (CHFCF, 이하 HFC-134a)을포함하고, 제4 성분으로서사이클로프로판 (CH, 이하 RC-270), 1,1-디플루오로에탄(CHCHF, 이하 HFC-152a), 1,1,1,2,3,3,3-헵타플루오로프로판 (CFCHFCF, 이하 HFC-227ea), 1,1,1,2,2-펜타플루오로프로판 (CHCFCF, 이하 HFC-245cb), 옥타플루오로사이클로부탄 (CF, 이하 RC-318), 1,1,1,2,3,3-헥사플루오로프로판(CHFCHFCF, 이하 HFC-236ea), 비스(디플루오로메틸)에테르(CHFOCHF, 이하 HFE-134), 펜타플루오로에틸메틸에테르(CFCFOCH, HFE-245), n-펜탄(CH, 이하 R601), 이소펜탄((CH)CHCHCH, 이하 R-601a) 중한 성분을포함하는 HCFC-22 대체용새로운냉매혼합물에관한것이다. 본발명에따른냉매혼합물은오존층파괴의위험이전혀없으면서동등한작용효과를보유하여 HCFC-22 대체냉매로서사용할수 있다.

公开(公告)号：KR100305079B1

公开(公告)日：2001-09-12

申请号：KR1019980057664

申请日：1998-12-23

Applicant: 한국과학기술연구원

Inventor： 이병권 ,  임종성 ,  박건유 ,  안병성 ,  이상득

IPC: C09K5/04

Abstract: 본 발명은 제 1 성분으로 디플루오로메탄(CH
3 F
2 , HFC-32)을 포함하고, 제 2 성분 및 제 3 성분으로 퍼플루오로프로판(C
3 F
8 , PFC-218)과 1,1-디플루오로에탄(CH
3 CHF
2 , HFC-152a), 또는 사이클로프로판(C
3 H
6 , RC-270)과 1,1,1,2,2-펜타플루오로프로판(CH
3 CF
2 CF
3 , HFC-245cb), 또는 부탄(C
4 H
10 , R-600)과 비스(디플루오로메틸)에테르(CHF
2 OCHF
2 , HFE-134)를 포함하는 HCFC-22 대체용 냉매 혼합물을 제공한다.

公开(公告)号：KR1020010038267A

公开(公告)日：2001-05-15

申请号：KR1019990046182

申请日：1999-10-23

Applicant: 한국과학기술연구원

Inventor： 김재덕 ,  이윤우 ,  임종성 ,  황경엽 ,  이윤용

IPC: A62D1/02

CPC classification number: A62D1/0092

Abstract: PURPOSE: A compositon of a clean agent for a fire extinguisher containing CO2 and trifluoroiodinemethan(HFC-23) is provided, whose fire extinguisher efficiency is excellent and whose global warming index and price are low. CONSTITUTION: A clean agent for a fire extinguisher containing CO2 and trifluoroiodinemethan(HFC-23) is composed of 0.1-99.9mol% of CO2 and 99.9-0.1mol% of HFC-23. And the agent is stored in the type of high-press liquefied gas so that a storage tank can be minimized and the price can be lowered.

Abstract translation: 目的：提供含有二氧化碳和三氟碘甲烷（HFC-23）灭火器的清洁剂组合物，其灭火剂效率优良，全球变暖指数和价格较低。 规定：含有二氧化碳和三氟碘甲烷（HFC-23）的灭火器的清洁剂由0.1-99.9mol％的二氧化碳和99.9〜0.1mol％的HFC-23组成。 并且该试剂储存在高压液化气体的类型中，使得储罐可以最小化并且可以降低价格。

公开(公告)号：KR100543526B1

公开(公告)日：2006-01-31

申请号：KR1020030024497

申请日：2003-04-17

Applicant: 한국과학기술연구원

Inventor： 김재덕 ,  임종성 ,  이윤우 ,  김영래

IPC: C07C51/285

CPC classification number: Y02P20/544

Abstract: 본 발명은 반응매체로서 240 내지 400 ℃의 온도 범위 및 220 내지 300 bar의 압력 범위에 있는 과량의 고온고압수를 사용하고, 일체의 촉매를 사용하지 아니하며, 산화제로서 과산화수소 또는 산소를 사용하여 파라크실렌(para-xylene)을 산화시킴으로써 테레프탈산을 합성하는 방법에 관한 것으로, 기존의 테레프탈산 합성방법과 비교하여, 인체에 미치는 독성이 적고, 장치의 부식 속도가 감소하여, 보다 안전하고 경제적으로 테레프탈산을 제조할 수 있는 테레프탈산 합성방법을 제공한다.

公开(公告)号：KR100454805B1

公开(公告)日：2004-11-03

申请号：KR1020020064740

申请日：2002-10-23

Applicant: 한국과학기술연구원

Inventor： 이병권 ,  임종성 ,  최대기 ,  이상득

IPC: C01B3/22

Abstract: PURPOSE: Provided is a thermal decomposition method of methane to simultaneously produce hydrogen gas and carbon black, the method capable of preventing deposit of carbon black on a reactor, thereby preventing operation stop of a reactor and operating a reactor for long time. CONSTITUTION: In an apparatus having a perforated inner pipe(11), an outer pipe(12) coaxially surrounding the inner pipe, and a heater(13) installed on the outside of the outer pipe for heating the inner and outer pipes, the method comprises steps of introducing methane to the inner pipe while introducing hydrogen to a space between the inner pipe and the outer pipe, and heating the pipes at a temperature of 950 to 1300°C. wherein residence time of the methane in a reactor is 0.5 to 3 minutes.

Abstract translation: 目的：提供一种甲烷热分解方法，用于同时生产氢气和炭黑，该方法能够防止炭黑在反应器上沉积，从而防止反应器停止运行并长时间运行反应器。 本发明涉及一种具有穿孔内管（11），同轴环绕内管的外管（12）和安装在外管外侧用于加热内管和外管的加热器（13）的装置， 包括以下步骤：将甲烷引入内管，同时将氢引入内管和外管之间的空间，并且在950-1300℃的温度下加热管。 其中甲烷在反应器中的停留时间为0.5至3分钟。

公开(公告)号：KR1020040082066A

公开(公告)日：2004-09-24

申请号：KR1020030016682

申请日：2003-03-18

Applicant: 한국과학기술연구원

Inventor： 이병권 ,  임종성 ,  이상득 ,  한만석

IPC: C09K5/04

CPC classification number: C09K5/045 ,  C09K2205/12 ,  C09K2205/122 ,  C09K2205/47

Abstract: PURPOSE: A cooling fluid composition is provided, to obtain a novel cooling fluid composition which contains no CFC and HCFC and can replace R-502 destroying the ozone layer. CONSTITUTION: The cooling fluid composition comprises 5-32 wt% of difluoromethane (CH2F2, HFC-32); 5-60 wt% of pentafluoroethane (CHF2CF3, HFC-125); and 35-63 wt% of cyclopropane (C3H6, RC-270). Also the cooling fluid composition comprises 2-15 wt% of difluoromethane (CH2F2, HFC-32); 8-40 wt% of pentafluoroethane (CHF2CF3, HFC-125); and 55-70 wt% of propane (C3H6, R-290).

Abstract translation: 目的：提供一种冷却液组合物，以获得不含CFC和HCFC的新型冷却液组合物，可代替破坏臭氧层的R-502。 构成：冷却液组合物包含5-32重量％的二氟甲烷（CH 2 F 2，HFC-32）; 5-60重量％的五氟乙烷（CHF 2 CF 3，HFC-125）; 和35-63重量％的环丙烷（C 3 H 6，RC-270）。 冷却流体组合物还包含2-15重量％的二氟甲烷（CH 2 F 2，HFC-32）; 8-40重量％的五氟乙烷（CHF 2 CF 3，HFC-125）; 和55-70重量％的丙烷（C 3 H 6，R-290）。

公开(公告)号：KR100402050B1

公开(公告)日：2003-10-17

申请号：KR1020030033617

申请日：2003-05-27

Applicant: 한국과학기술연구원

Inventor： 이병권 ,  임종성 ,  김홍곤 ,  김창년

IPC: C09K5/04

Abstract: PURPOSE: Provided is a mixed coolant composition having new composition, which can show similar ability to that of the existing HCFC-22, and does not have the danger such as destruction of the ozone layer. CONSTITUTION: The mixed coolant composition for low temperature freezers, containing a mixture of fluorinated hydrocarbons, comprises a mixture containing 40-70 wt% of difluoromethane(HFC-32), 10-40 wt% of 1,1-difluoroethane(HFC-152a), and 10-20 wt% of 1,1,1,2,3,3,3-heptafluoropropane(HFC-227ea); and 5-15 wt% of isobutane(R-600a). Also, the mixed coolant composition comprises a mixture containing 50-70 wt% of difluoromethane(HFC-32), 10-30 wt% of 1,1-difluoroethane(HFC-152a), and 10-20 wt% of 1,1,1,2,3,3,3-heptafluoropropane(HFC-227ea); and 5-15 wt% of 1,1,1,2,3,3-hexafluoropropane(HFC-236ea).

Abstract translation: 目的：提供具有新组成的混合冷却剂组合物，其能够显示与现有HCFC-22相似的能力，并且不具有破坏臭氧层的危险。 构成：含有氟化烃混合物的低温冷冻机用混合冷却剂组合物包含含有40-70重量％二氟甲烷（HFC-32），10-40重量％1,1-二氟乙烷（HFC-152a ）和10-20重量％的1,1,1,2,3,3,3-七氟丙烷（HFC-227ea）; 和5-15重量％的异丁烷（R-600a）。 此外，混合冷却剂组合物包含含有50-70重量％二氟甲烷（HFC-32），10-30重量％1,1-二氟乙烷（HFC-152a）和10-20重量％1,1 ，1,2,3,3,3-七氟丙烷（HFC-227ea的）; 和5-15重量％的1,1,1,2,3,3-六氟丙烷（HFC-236ea）。