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    ADHESIVE COMPOSITIONS COMPRISING A SILSESQUIOXANE POLYMER CROSSLINKER, ARTICLES AND METHODS
    26.
    发明申请
    ADHESIVE COMPOSITIONS COMPRISING A SILSESQUIOXANE POLYMER CROSSLINKER, ARTICLES AND METHODS 审中-公开

    公开(公告)号：US20170321088A1

    公开(公告)日：2017-11-09

    申请号：US15306200

    申请日：2015-06-08

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： Joon Chatterjee ,  Jitendra Rathore ,  Babu N. Gaddam ,  Jayshree Seth ,  Corinne E. Lipscomb

    IPC: C09J4/06 ,  C09J11/04

    CPC classification number: C09J4/06 ,  C08F220/10 ,  C08G77/442 ,  C08K5/101 ,  C09J11/04 ,  C09J133/06 ,  C09J183/10 ,  C09J2201/606 ,  C09J2205/106 ,  C09J2433/00 ,  C09J2483/00

    Abstract: Pressure sensitive adhesive compositions are described comprising at least one low Tg ethylenically unsaturated monomer, and at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The low Tg ethylenically unsaturated monomer typically has a Tg no greater than 10° C. In some embodiments, the composition comprises at least 50, 55, 60, 65, or 70 wt-% of low Tg ethylenically unsaturated monomer. The low Tg ethylenically unsaturated monomer is typically an alkyl (meth)acrylate comprising 4 to 20 carbon atoms. In another embodiment, an adhesive composition is described comprising a syrup. The syrup comprising i) a free-radically polymerizable solvent monomer; ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers, and iii) at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The free-radically polymerizable solvent monomer, polymerized units of the solute (meth)acrylic polymer, or a combination thereof comprise a low Tg ethylenically unsaturated monomer. Also described are pressure sensitive adhesive articles and method of preparing adhesive articles.

    ADHESIVES COMPRISING GRAFTED ISOBUTYLENE COPOLYMER
    28.
    发明申请
    ADHESIVES COMPRISING GRAFTED ISOBUTYLENE COPOLYMER 有权
    包含接枝的异丁烯共聚物的粘合剂

    公开(公告)号：US20150166854A1

    公开(公告)日：2015-06-18

    申请号：US14415777

    申请日：2013-08-12

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： Hae-Seung Lee ,  Jonathan E. Janoski ,  Joon Chatterjee ,  Kevin M. Lewandowski ,  Babu N. Gaddam

    IPC: C09J151/06 ,  B05D5/00 ,  C08F299/00

    CPC classification number: C09J151/06 ,  B05D5/00 ,  C08F299/00 ,  C08L51/06 ,  C09J123/22 ,  C09J123/283 ,  Y10T428/2878

    Abstract: An adhesive composition is described comprising a tackifier and at least one grafted isobutylene copolymer. The grafted isobutylene copolymer has the formula: R1—(R2—Z) wherein R1 represents an isobutylene copolymer, R2 is a covalent bond or multivalent alkylene or arylene, and Z is a grafted polymer. Z is typically a homopolymer of copolymer comprising alkene repeat units, aralkylene repeat units, or a combination thereof. Also described are adhesive coated articles, methods of making adhesive coated articles, and grafted isobutylene polymers.

    Abstract translation: 描述了一种包含增粘剂和至少一种接枝异丁烯共聚物的粘合剂组合物。 接枝异丁烯共聚物具有下式：R1-（R2-Z）其中R1表示异丁烯共聚物，R2是共价键或多价亚烷基或亚芳基，Z是接枝聚合物。 Z通常是包含烯烃重复单元，亚芳基重复单元或其组合的共聚物的均聚物。 还描述了粘合剂涂覆制品，制造粘合剂涂覆制品的方法和接枝异丁烯聚合物。

    ADHESIVES COMPRISING REACTION PRODUCT OF HALOGENATED POLY(ISOBUTYLENE) COPOLYMERS AND POLYAMINES
    29.
    发明申请
    ADHESIVES COMPRISING REACTION PRODUCT OF HALOGENATED POLY(ISOBUTYLENE) COPOLYMERS AND POLYAMINES 有权
    包含反应性聚（异丁烯）共聚物和聚氨酯的反应产物的粘合剂

    公开(公告)号：US20150072143A1

    公开(公告)日：2015-03-12

    申请号：US14394342

    申请日：2013-02-06

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： Hae-Seung Lee ,  Pierre R. Bieber ,  Joon Chatterjee ,  Siegfried R. Goeb ,  Babu N. Gaddam

    IPC: C09J123/36 ,  C09J123/20 ,  C09J7/02

    CPC classification number: C09J123/36 ,  C08L23/22 ,  C09J7/20 ,  C09J123/20 ,  C09J123/22 ,  C09J2423/00 ,  Y10T428/2852

    Abstract: Adhesive composition are described comprising the reaction product of at least one halogenated copolymer of isobutylene wherein halogen atoms of the copolymer are replaced by a polyamine having a melting point greater than 25° C., thereby crosslinking the copolymer. The isobutylene copolymer comprises halogenated repeat units derived from isoprene, butadiene, para-alkyl styrene, or a combination thereof. The adhesive composition comprises a copolymer of isobutylene repeat units and second repeat units selected from alkene repeat units, para-methyl styrene repeat units, or a combination thereof wherein at least a portion of the second repeat units are directly bonded to one another with a polyamine crosslinker having a melting point greater than 25° C. Also described are adhesive articles, such as tapes, comprising such adhesives.

    Abstract translation: 描述了粘合剂组合物，其包含至少一种异丁烯的卤化共聚物的反应产物，其中共聚物的卤素原子被熔点大于25℃的多胺代替，从而使共聚物交联。 异丁烯共聚物包含衍生自异戊二烯，丁二烯，对 - 烷基苯乙烯或其组合的卤代重复单元。 粘合剂组合物包含异丁烯重复单元和选自烯烃重复单元，对甲基苯乙烯重复单元或其组合的第二重复单元的共聚物，其中至少一部分第二重复单元通过多胺直接键合 具有熔点大于25℃的交联剂。还描述了包含这种粘合剂的粘合剂制品，例如胶带。

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