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公开(公告)号:JP2000109323A
公开(公告)日:2000-04-18
申请号:JP29453498
申请日:1998-10-01
Applicant: TODA KOGYO CORP , AGENCY IND SCIENCE TECHN
Inventor: YAMAMOTO AKINORI , KATAMOTO TSUTOMU , SHIBAZAKI YASUO , ODA KIICHI
Abstract: PROBLEM TO BE SOLVED: To provide the production process of well-oriented platelike spinel-type ferrite powdery particles which are appropriately used as a radio wave absorptive material or electromagnetic-shielding material. SOLUTION: This production process for producing the objective platelike spinel-type ferrite powdery particles, consists of a first stage and a second stage. The first stage comprises: adding a water-soluble salt of Ni or its aqueous solution to an aqueous liquid suspension of platelike hematite powdery particles; thereafter, adjusting the pH of the resulting suspension to 9.0-14.0; aging this suspension at 0-30 deg.C to coat the surface of each of platelike hematite particles with hydroxide or oxide of Ni; and thereafter, calcining the coated hematite particles at 500-700 deg.C by heating them to obtain powdery particles of an Ni-containing platelike calcined material. The second stage comprises: adding a water-soluble salt of Ni or its aqueous solution to an aqueous liquid suspension of the Ni-containing platelike calcined material powdery particles obtained in the stage 1; thereafter, adjusting the pH of the resulting suspension to 9.0-14.0; aging this suspension at 0-30 deg.C to coat the surface of each of the Ni-containing platelike calcined material powdery particles with hydroxide or oxide of Ni; and thereafter, firing the coated powdery particles at 800-1,200 deg.C by heating them to obtain platelike spinel-type ferrite powdery particles.
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22.
公开(公告)号:JP2000007327A
公开(公告)日:2000-01-11
申请号:JP16987098
申请日:1998-06-17
Applicant: AGENCY IND SCIENCE TECHN
Inventor: ONO AKIRA , SHIBAZAKI YASUO , ODA KIICHI , SANO SABURO , TOMONO TAKUMI , OGURI KENTA , KAWAI HIDEJI , NOMURA YUJI
Abstract: PROBLEM TO BE SOLVED: To provide highly plastic alumina particles exhibiting an excellent plastic property as a raw material for ceramics by forming alumina hydrate coating films on the surfaces of alumina particles. SOLUTION: The alumina particles each preferably has a fine hexagonal plate-like shape, a particle size of
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公开(公告)号:JPH0891830A
公开(公告)日:1996-04-09
申请号:JP23125294
申请日:1994-09-27
Applicant: AGENCY IND SCIENCE TECHN , CERAMICS SUIKASO SEIKEI GIJUTS
Inventor: SHIBAZAKI YASUO , ODA KIICHI , SANO SABURO , MAEDA MASAKI , TAMURA MINORU , ICHIKAWA YUKARI , KOIZUMI KENICHI , FUKAKUSA HISAYUKI , TAKENAKA HIDEO
IPC: C01F7/02
Abstract: PURPOSE: To obtain high plasticity alumina particles useful as a material excellent in heat resistance, electric insulating property and mechanical strength and giving a high density compact by forming a specified compd. on the surfaces of α-alumina particles. CONSTITUTION: An aluminate compd. is formed on the surfaces of α-alumina particles, preferably hexagonal platy particles, especially preferably particles each having
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公开(公告)号:JPH07331110A
公开(公告)日:1995-12-19
申请号:JP15178394
申请日:1994-06-10
Applicant: AGENCY IND SCIENCE TECHN , YOSHIDA KOGYO KK
Inventor: SHIBAZAKI YASUO , ODA KIICHI , SANO SABURO , MAEDA MASAKI , MATSUO YOJI
Abstract: PURPOSE:To prepare a flaky alumina pigment which has good coatability and high-temp. stability and is useful as a pigment for coating materials and potteries by treating the surface of a flaky alumina pigment with a particular metal or metallic compd. CONSTITUTION:A flaky alumina pigment comprising a flaky alumina and a color compd. metal oxide reacted with and present on the surface of the flaky alumina. This flaky alumina pigment is prepd. by coating a flaky alumina with a metal or a metallic compd. capable of reacting with alumina to develop a color and calcining the coated flaky alumina at a high temp. Pref., the flaky glumina has a particle diameter of 0.1 to 20mum and an aspect ratio of 2 to 50. The color compd. metal oxide is a compd. comprising alumina and a metal oxide excluding alumina. The metal oxide is at least one member selected from oxides of Mg, Zn, Mn, Ni, Co, Ti, Fe, Cr, Cu, and V. The color metal oxide is pref. of a spinel crystalline structure.
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公开(公告)号:JPH06278034A
公开(公告)日:1994-10-04
申请号:JP7173893
申请日:1993-03-30
Applicant: AGENCY IND SCIENCE TECHN , YOSHIDA KOGYO KK
Inventor: SHIBAZAKI YASUO , ODA KIICHI , FUKUDA YUSHI , NAGAI YOSHITAKA
Abstract: PURPOSE:To evenly distribute plate-shape particles so as to improve the sharpness of a grinding wheel by rotating a mixture of binder resin and plate-shape alumina particles at high speed, and orienting the plate-shape alumina particles by means of centrifugal force, thus molding the grinding wheel. CONSTITUTION:Fine plate-shape alumina (alpha-Al2O3) particles are obtained through a hydrothermal treatment and are mixed with a binder resin (binding agent) and this mixture is heated to melt the binder resin and the molten mixture is fed from a feeding portion. While the mixture is being fed, a lower mold is rotated relative to a upper mold and a base body is disposed between the upper mold the lower mold. The molten mixture fed from the feeding portion of the die body held in place is fed into a gap formed between the base body and the upper mold and is forced to collide with each other by a centrifugal force caused by rotation of the lower mold and the alumina particles in the molten mixture are oriented in the vertical direction by this collision. Cooling water is fed into the cooling portion of the lower mold and the oriented alumina particles are sequentially hardened by the binder resin to form an alumina grinding wheel.
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公开(公告)号:JPH0578118A
公开(公告)日:1993-03-30
申请号:JP13077891
申请日:1991-03-22
Applicant: AGENCY IND SCIENCE TECHN , FUJI CHEM IND CO LTD
Inventor: SHIBAZAKI YASUO , ODA KIICHI , WATAMURA SHINJI , MACHIMURA HITOSHI , MURAKAMI TATSUO
Abstract: PURPOSE:To provide an inorganic powder substance carrying metal hydroxide ion and resistant to the dissolution of metal ion. CONSTITUTION:Amorphous magnesium silicate aluminate is added to and suspended in a weakly acidic aqueous solution of a water-soluble salt of a metal selected from Cu, Mn, Ni, Zn, Ag and Co. In the above process, the magnesium in the magnesium silicate aluminate is subjected to ion-exchange reaction with the above metal and the suspension of the obtained product is aged, filtered, washed with water and dried to obtain the objective inorganic powder substance. The obtained inorganic powder substance is new substance.
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公开(公告)号:JP2000119060A
公开(公告)日:2000-04-25
申请号:JP29068998
申请日:1998-10-13
Applicant: AGENCY IND SCIENCE TECHN , NIKKO KK , YKK CORP
Inventor: ONO AKIRA , SHIBAZAKI YASUO , ODA KIICHI , SANO SABURO , TOMONO TAKUMI , OGURI KENTA , KAWAI HIDEJI , NOMURA YUJI
IPC: C04B35/628 , C01F7/02 , C04B35/10 , C04B35/632
Abstract: PROBLEM TO BE SOLVED: To obtain a highly plastic alumina paste useful as a ceramic stock by incorporating alumina particles with agar-agar. SOLUTION: This highly plastic alumina paste is obtained by melting agar powder under boiling followed by cooling to form agar gel which is then kneaded with alumina particles; alternatively, by adding alumina particles to an aqueous solution of agar powder which is melted under boiling in advance, followed by cooling the system to effect coating the alumina surface with agar-agar followed by dehydration; wherein it is preferable that the agar-agar to be used as a starting material is >=5 g/cm2 in jelly strength, and the agar content of the final alumina paste is 0.5-10 wt.%. This alumina paste obtained by mixing (kneading) process is capable of controlling its pore size depending on its gel size, therefore being advantageous for making porous forms; whereas another version of this alumina paste obtained by coating process is hard to produce pores because the agar-agar as binder uniformly and extremely thinly adheres to the alumina, therefore affording a dense sintered compact, dense/high- density molded form or molded form with controlled pore size. The above method for producing this alumina paste is effective in cost reduction and operability improvement.
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公开(公告)号:JPH11228210A
公开(公告)日:1999-08-24
申请号:JP4878098
申请日:1998-02-13
Applicant: AGENCY IND SCIENCE TECHN
Inventor: SHIBAZAKI YASUO , ODA KIICHI , SANO SABURO , TOMONO TAKUMI , OGURI KENTA , KAWAI HIDEJI , NOMURA YUJI , ONO AKIRA
IPC: C04B33/04
Abstract: PROBLEM TO BE SOLVED: To provide a method for improving the plasticity of natural kaolinite and artificial kaolinite. SOLUTION: A kaolinite is brought into contact with an aqueous solution containing NH4 to adsorb NH4 on the surface of the kaolinite. The kaolinite is brought into contact with an aqueous solution containing a divalent cation and the NH4 adsorbed on the surface of the kaolinite is substituted with the divalent cation. The aqueous solution containing NH4 is an aqueous solution of CH3 COONH4 or an aqueous solution of NH4 Cl and Mg or Ca is used as the divalent cation.
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公开(公告)号:JPH1192233A
公开(公告)日:1999-04-06
申请号:JP26817897
申请日:1997-09-12
Applicant: AGENCY IND SCIENCE TECHN , CERAMICS SUIKA SOSEIKEI GIJUTS
Inventor: SHIBAZAKI YASUO , ODA KIICHI , SANO SABURO , TOMONO TAKUMI , OGURI KENTA , KAWAI HIDEJI , NOMURA YUJI , ONO AKIRA
IPC: C04B35/628 , B28B3/20 , B28C7/00
Abstract: PROBLEM TO BE SOLVED: To provide a method of controlling the plasticity of clay paste for imparting good plasticity enough to permit its smooth extrusion molding to the clay paste composed of non-plastic particles as alumina or the like. SOLUTION: The particle-filling structure of clay paste is made of the aggregation of secondary particles formed by coagulation of the primary particles, the water-containing gaps larger than the space between the primary particles are formed 20-30 vol.% based on the clay paste and the gaps between the primary particles in the secondary particles becomes
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公开(公告)号:JPH08259331A
公开(公告)日:1996-10-08
申请号:JP8870295
申请日:1995-03-22
Applicant: AGENCY IND SCIENCE TECHN
Inventor: MAEDA MASAKI , ODA KIICHI , SHIBAZAKI YASUO
IPC: C04B35/584 , C04B35/632
Abstract: PURPOSE: To obtain a composition for a plastic molding enabling the simplification of a fat removing process after an injection molding by adding polysaccharide high molecular materials to a highly dispersed aqueous slurry of boron nitride-based ceramic powder of a high concentration showing almost no plasticity, blending, kneading and maturing. CONSTITUTION: This composition for a plastic molding is obtained by adding a dispersing agent to a silicon nitride-based ceramic powder and a sintering assistant, adding polysaccharide high molecular materials to a highly dispersed aqueous slurry of a high concentration prepared by using water as a solvent, blending, kneading and maturing. By using this composition for plastic molding, since water as the solvent evaporates during a drying process and fine pores are produced in the molding material, troubles such as swelling or cracking in the molded product due to the thermal decomposition of organic matters do not occur.
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