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公开(公告)号:FI58577C
公开(公告)日:1981-03-10
申请号:FI770378
申请日:1977-02-03
Applicant: BASF AG
Inventor: ADOLPHI HEINRICH , SCHWARZMANN MATTHIAS , HEINZE PETER
Abstract: Wood preservatives for protecting wood or wood-base materials against animal pests, and which contain a perfluoroalkane sulfonate of the formula C nF2n+1-SO3 M where n is one of the integers from 1-14 and M denotes hydrogen or a cation, and a process for protecting wood or wood-base materials against animal pests with these compounds.
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22.
公开(公告)号:HU176199B
公开(公告)日:1981-01-28
申请号:HUBA003557
申请日:1977-07-08
Applicant: BASF AG
Inventor: ADOLPHI HEINRICH , BAUMANN ANNEGRIT , HUBER ROLF , KIEHS KARL , MERGER FRANZ
IPC: A01N47/18 , A01N47/24 , A01P7/04 , C07D231/34 , C07D231/54 , C07C125/06 , A01N9/22
Abstract: New carbamates, a process for their manufacture by reaction of salts of pyrazolinediones with a carbamyl halide, and pesticides containing these new carbamates as active ingredients. The new carbamates may be used as insecticides and acaricides. They have an excellent action on sucking insects, especially aphids.
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公开(公告)号:FI58577B
公开(公告)日:1980-11-28
申请号:FI770378
申请日:1977-02-03
Applicant: BASF AG
Inventor: ADOLPHI HEINRICH , SCHWARZMANN MATTHIAS , HEINZE PETER
Abstract: Wood preservatives for protecting wood or wood-base materials against animal pests, and which contain a perfluoroalkane sulfonate of the formula C nF2n+1-SO3 M where n is one of the integers from 1-14 and M denotes hydrogen or a cation, and a process for protecting wood or wood-base materials against animal pests with these compounds.
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公开(公告)号:AU5334579A
公开(公告)日:1980-06-05
申请号:AU5334579
申请日:1979-11-30
Applicant: BASF AG
Inventor: SCHWARZ GERD-ULRICH , KIEHS KARL , ADOLPHI HEINRICH
IPC: C07C69/65 , A01N37/10 , A01N43/08 , A01N53/00 , A01N53/04 , A01N53/06 , A01N53/08 , C07C29/40 , C07C41/30 , C07C43/295 , C07C67/00 , C07C69/73 , C07C69/747 , C07C253/00 , C07C255/57 , C07C313/00 , C07C319/20 , C07C323/19 , C07D307/45 , C07D307/58 , C07D307/64 , C07D307/42 , C07C61/04 , C07C63/52 , A01N9/12 , A01N9/20
Abstract: Novel carboxylic acid esters of the formula I where R1, R2 and R3 are identical or different and each is hydrogen, halogen or alkyl or alkenyl of up to 5 carbon atoms, Y is 3-(2,2-dihalogenovinyl)-2,2-dimethyl-cyclopropyl or a radical of the formula where R4 is unbranched or branched alkyl, alkenyl or alkynyl of up to 4 carbon atoms or is an alicyclic radical of 3 to 7 carbon atoms, R5 is halogen, alkyl or alkoxy of up to 5 carbon atoms, trihalomethyl, cyano or nitro and a is from 0 to 3 and Z is a radical of the formula +TR where X is oxygen, sulfur or -CH2-, R6, R7 and R8 are halogen or alkyl, alkoxy or haloalkyl of up to 5 carbon atoms and b, c and d are from 0 to 3, their preparation and their use in insect and arachnid control.
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公开(公告)号:CA1076585A
公开(公告)日:1980-04-29
申请号:CA263820
申请日:1976-10-20
Applicant: BASF AG
Inventor: THEOBALD HANS , KIEHS KARL , ADOLPHI HEINRICH
IPC: A01N57/08 , A01N57/16 , A01N57/24 , A01N57/32 , A01P7/02 , A01P7/04 , C07D261/08 , C07F9/653 , C07F9/65 , A01N9/36
Abstract: Phosphoric acid derivatives of the formula , where X denotes oxygen or sulfur, R1 and R4 denote identical or different, linear or branched alkyl groups of a maximum of 6 carbon atoms, R2 denotes hydrogen or alkyl of a maximum of 3 carbon atoms, and R3 denotes linear or branched alkylthio, alkenylthio or alkynylthio of a maximum of 6 carbon atoms, phenyl optionally substituted by nitro or chlorine, or linear or branched alkylamino or dialkylamino each of a maximum of 5 carbon atoms in the alkyl group, a process for their manufacture by reaction of isoxazole derivatives with salts of phosphoric acid derivatives and a process for controlling pests, or protecting objects against pest attack, by treatment with these phosphoric acid derivatives.
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公开(公告)号:DE2831235A1
公开(公告)日:1980-01-31
申请号:DE2831235
申请日:1978-07-15
Applicant: BASF AG
Inventor: RENTZEA COSTIN DIPL ING DR , AMMERMANN EBERHARD DIPL CHEM D , SAUTER HUBERT DIPL CHEM DR , ADOLPHI HEINRICH
IPC: A01N43/50 , A01N43/56 , A01N43/653 , C07D249/08 , C07D521/00 , A01N9/22 , C07D247/02
Abstract: Azolyl cpds. of formula R1-C(Az)H-C(COR2)(COR3)H (I) and their plant-tolerable salts and metal complexes are new. In (I) R1 is aryl or heteroacryl, opt. substd. by >=1, same or different, halo, 1-4C opt. branched alkyl or alkoxy(themselves opt. halo substd.), NO2, OH or CN; R2 and R3 are each 1-3C opt. branched alkyl, OR4 or NR5R6; Az is 1,2,4-triazol-1-yl, 1-imidazolyl or 1-pyrazolyl; R4 is opt. branched 1-6C alkyl (opt. substd. by alkoxy, alkylthio or halo), alkenyl or alkynyl, is not >6C cycloalkyl or phenyl opt. substd. by >=1 opt. branched 1-4C alkyl or alkoxy, halo, CR3 or NO2; R5 and R6 are each H, opt. branched is not >6C alkyl, alkenyl or alkynyl, is not >6C cycloalkyl or phenyl opt. substd. as for R4; or NR5R6 is morpholino, piperidino or pyrrolidino, opt. substd. by is not >4C opt. branched alkyl gps. (I) are prepd. by reacting AzH with R1-CH=C(COR2)COR3. (I) are nematocides, esp. useful against soil nematodes. They have low toxicity towards plants and warm-blooded animals and high selectivity.
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公开(公告)号:AU2191377A
公开(公告)日:1978-08-10
申请号:AU2191377
申请日:1977-02-03
Applicant: BASF AG
Inventor: KIEHS KARL , ADOLPHI HEINRICH , THEOBALD HANS
IPC: A01N57/08 , C07D309/38 , C07F9/58 , A01N9/36
Abstract: New pyridylphosphoric acid derivatives, a process for the manufacture thereof by reaction of pyridinecarboxylic acid esters with salts of phosphoric acid derivatives, and pesticides containing these new pyridylphosphoric acid derivatives as active ingredients. The compounds of the invention have the formula where X denotes hydrogen or halogen, Y denotes oxygen or sulfur, R1 denotes linear or branched alkyl, alkenyl or alkynyl of a maximum of 6 carbons atoms, or unsubstituted or halogen-substituted phenyl or benzyl, R2 denotes linear or branched alkyl, unsubstituted phenyl, substituted phenyl, alkyloxy or alkylthio of a maximum of 6 carbon atoms, alkenyloxy or alkenylthio of a maximum of 6 carbon atoms, alkynyloxy or alkynylthio of a maximum of 6 carbon atoms, amino or alkylamino with from 1 to 4 carbon atoms in the alkyl moiety, or dialkylamino with from 1 to 4 carbons atoms per alkyl moiety, and R3 denotes alkyl of from 1 to 4 carbon atoms.
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公开(公告)号:CA1018527A
公开(公告)日:1977-10-04
申请号:CA182524
申请日:1973-10-03
Applicant: BASF AG
Inventor: BEUTEL PETER , ADOLPHI HEINRICH , KIEHS KARL
IPC: A01N57/10 , A01N57/02 , A01N57/18 , C07F9/08 , C07F9/165 , C07F9/40 , C07F9/59 , C07F9/6533 , C07F9/655
Abstract: 1439058 Thiophosphoric and thiophosphoric esters BASF AG 11 Oct 1973 [12 Oct 1972] 47471/73 Headings C2P and C2C The invention comprises thiophosphorus esters of the formula wherein R 1 is methyl or ethyl, R 2 is methyl, ethyl, phenyl, methoxy or ethoxy, R 3 is C 1 -C 3 alkyl, R 4 is H or C 1 -C 3 alkyl or NR 3 R 4 is pyrrolidino, piperidino, morpholino, piperazino or N-alkyl piperazino, R 5 is C 1 -C 3 alkyl, R 6 is methyl, ethyl or phenyl and X is 0 or 5. They are obtained by reacting wherein B is a salt-forming cation and hal is Cl, Br or I. The products have pesticidal properties and may be used as active ingredients in conventional pesticidal formulations for use in plant protection and in the veterinary field. N,N - dimethyl - N 1 - dimethylamino - sulphonyl chloroacetamidine is obtained by reacting chlorosulphonyl isocyanate with N,N-dimethylchloroacetamide in CCl 4 at 40‹ C. and then reacting the product with a solution of dimethylamine in dioxane at 0‹ to 5‹ C.
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公开(公告)号:CA859172A
公开(公告)日:1970-12-22
申请号:CA859172D
Applicant: BASF AG
Inventor: ADOLPHI HEINRICH , SPAENIG HERMANN , STEIMMIG ANNA
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公开(公告)号:GB924657A
公开(公告)日:1963-05-01
申请号:GB4365461
申请日:1961-12-06
Applicant: BASF AG
Inventor: DICKHAEUSER HEINER , POHLEMANN HEINZ , STUMMEYER HERBERT , ADOLPHI HEINRICH , WINDERL SIEGFRIED
IPC: C07F9/165
Abstract: The invention comprises compounds of the formula: where R1 and R2 are alkyl radicals, X is oxygen or sulphur, Y is a radical NR3R4 wherein R3 and R4 are hydrogen or alkyl or R3 and R4 together with the nitrogen make up a heterocyclic ring, and Z is a radical NR3R4 as defined or an alkoxy radical. These compounds are prepared by reacting a salt of an O, O - dialkylthiolphosphoric acid or O, O-dialkyldithiophosphoric acid with a compound ZCO.CHHal.COY; or by reacting a compound ZCO.CH(SH).COY or a salt thereof with an O,O-dialkylthionophosphoric acid chloride or O,O-dialkylphosphoric acid chloride. The compounds of the invention are insecticides (see Group VI).ALSO:The invention comprises insecticidal compositions containing a compound of formula where R1 and R2 are alkyl radicals, X is oxygen or sulphur, Y is a radical NR3R4 wherein R3 and R4 are hydrogen or alkyl or R3 and R4 together with the nitrogen make up a heterocyclic ring, and Z is a radical NR3R4 as defined or an alkoxy radical (see Group IV (b)). These compounds may be made up as dusts by adding solid extenders, as sprays by adding dispersing, wetting and/or sticking agents to solid or liquid preparations, or as solutions or emulsions. Fungicides and/or other insecticides may be incorporated in the compositions. Examples use aqueous emulsions.
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