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公开(公告)号:DE2000511A1
公开(公告)日:1971-07-22
申请号:DE2000511
申请日:1970-01-07
Applicant: BASF AG
Inventor: MERGER FRANZ DR , FUCHS WERNER DR , DOCKNER TONI DR
Abstract: 1326717 2,2 - dialkyl - 3 - acyloxypropanols BADISCHE ANILIN- & SODAFABRIK AG 6 Jan 1971 [7 Jan 1970] 576/71 Heading C2C 2,2 - dialkyl - 3 - acyloxypropanols of general formula where R 1 denotes hydrogen or an aliphatic, cycloaliphatic, araliphatic or aromatic radical and R 2 and R 3 separately denote identical or different aliphatic radicals or jointly with the adjacent carbon atom from a cycloaliphatic ring, are prepared by reacting a carboxylic acid R 1 COOH with formaldehyde and a secondary aldehyde in the presence of a strong acid while removing water formed and present at the beginning of the reaction. The formaldehyde may be added as paraformaldehyde, trioxan or in the form of an aqueous formaldehyde solution and a solvent forming an azeotrope with water may be used. Many starting materials are listed and the acid catalysts may be trichloracetic, phosphoric, cyanoacetic, o-bromobenzoic, p-chlorobenzoic, benzene and p-toluenesulphonic, sulphuric and phosphoric acids. Examples describe the preparation of acetoxypivaldehyde, tri-, di- and mono-chloroacetoxypivaldehyde, αα-dichloropropionyloxy-pivaldehyde, isobutyryloxypivaldehyde, 2 - methyl- 2 - n - propyl - 3 - acetoxypropanol, 2 - ethyl- 2 - n - butyl - 3 - acetoxypropanal, 1- acetoxymethyl hexahydrobenzaldehyde, benzoyloxypivaldehyde, and 3-4- and 2-4-dichlorobenzoyloxypivaldehyde.
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公开(公告)号:DE1957301A1
公开(公告)日:1971-05-19
申请号:DE1957301
申请日:1969-11-14
Applicant: BASF AG
Inventor: MERGER FRANZ DR , PLATZ ROLF DR , FUCHS WERNER DR
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公开(公告)号:DE3160005D1
公开(公告)日:1982-12-09
申请号:DE3160005
申请日:1981-01-08
Applicant: BASF AG
Inventor: RIEBER NORBERT DR , BOEHM HEINRICH DR , PLATZ ROLF DR , FUCHS WERNER DR
IPC: C07D229/00 , C07D249/00 , C07D487/08
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公开(公告)号:DE2151205A1
公开(公告)日:1973-04-19
申请号:DE2151205
申请日:1971-10-14
Applicant: BASF AG
Inventor: KUERTEN HERIBERT DR , PLATZ ROLF DR , HUGO DR POPP KARL , NAGEL OTTO DR , FUCHS WERNER DR
IPC: B01D3/16 , B01F3/04 , B01F3/08 , B01F5/02 , B01F5/10 , C02F3/12 , C02F3/22 , C12M1/08 , B01F5/04
Abstract: 1405264 Aerating liquids BADISCHE ANILIN- & SODA-FABRIK AG 13 Oct 1972 [14 Oct 1971] 47273/72 Divided out of 1303163 Heading B1C In a process for oxygenating a body of liquid e.g. waste liquid containing activated sludge, air is introduced into the body of liquid together with a submerged jet of the liquid partly by the inductive action of the jet and partly by a pump. The jet of liquid having a speed of from 5 to 100 metres per second and being directed into an open-ended confined mixing zone 3 of hydraulic diameter 2 to 20 times the diameter of the liquid nozzle 1 and of length 2 to 30 times its hydraulic diameter. Liquid from the vessel 4 is circulated by a pump 7 and fresh waste liquor may be introduced continuously by a line 8, treated liquor overflowing at 5 to settling tanks. The combined air/liquid jet nozzle 1 may be located horizontally, vertically or at any intermediate position.
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公开(公告)号:DE2144148A1
公开(公告)日:1973-03-08
申请号:DE2144148
申请日:1971-09-03
Applicant: BASF AG
Inventor: BRESSEL ULRICH DR , FUCHS WERNER DR , PLATZ ROLF DR
IPC: C07C5/48 , C07B31/00 , C07B35/04 , C07C1/00 , C07C5/44 , C07C5/56 , C07C11/00 , C07C15/44 , C07C67/00 , C07C69/54 , C07B3/00
Abstract: Dehydrogenation of isobutyronitrile, ethylbenzene or methyl isobutyrate with iodine and oxygen into methacrylonitrile, styrene or methyl methacrylate at 400 DEG to 800 DEG C is carried out in a reaction chamber in which there are arranged, in the direction of flow of the bulk of the reactants introduced through a nozzle, coaxially from inside to outside first a mixing zone and then a circulation tube.
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公开(公告)号:CH518895A
公开(公告)日:1972-02-15
申请号:CH1327069
申请日:1969-09-02
Applicant: BASF AG
Inventor: MERGER FRANZ DR , PLATZ ROLF DR , FUCHS WERNER DR
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公开(公告)号:DE1962284A1
公开(公告)日:1971-06-24
申请号:DE1962284
申请日:1969-12-12
Applicant: BASF AG
Inventor: MERGER FRANZ DR , FUCHS WERNER DR
Abstract: The molecular cpd. of 1 mol. of 2,6-dimethyl-3,5-dichloro-benzoquinone and 2 mol of 2,6-dimethyl-3,4,5-trichlorophenol is produced in good yield and purity by reacting 2,6-dimethyl-4-t-butyl-phenol with SO2Cl2 at >50 degrees C. The product has fungicidal and insecticidal activity and can be used as a bactericide fungicide and wood-preservative.
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公开(公告)号:DE1958463A1
公开(公告)日:1971-06-03
申请号:DE1958463
申请日:1969-11-21
Applicant: BASF AG
Inventor: MERGER FRANZ DR , FUCHS WERNER DR , OBERHANSBERG JOACHIM DR , DUEMBGEN GERD DR
IPC: C07C69/675 , C07C69/66
Abstract: acid monoester, useful as raw material in the manufacture of synthetic resins and plasticisers, is produced from 2:2-dimethyl-3-hydroxypropanol obtained by reacting HCHO with isobutyraldehyde at elevated temps. in the presence of tert. amines. This reaction mixture, after removal of free amine, is then reacted at 120 - 175 degrees C in the presence of an organic salt of a tert. amine of mol. wt. below 250.
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公开(公告)号:DE1957591A1
公开(公告)日:1971-05-27
申请号:DE1957591
申请日:1969-11-15
Applicant: BASF AG
Inventor: MERGER FRANZ DR , FUCHS WERNER DR , WINDERL SIEGFRIED DR , HAARER ERICH DR
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30.
公开(公告)号:CH496812A
公开(公告)日:1970-09-30
申请号:CH856467
申请日:1967-06-16
Applicant: BASF AG
Inventor: DISTLER HARRY DR , FUCHS WERNER DR
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