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    Oligomeric diarylbutadienes
    23.
    发明专利
    Oligomeric diarylbutadienes 未知

    公开(公告)号：SI1008586T1

    公开(公告)日：2004-02-29

    申请号：SI9930430

    申请日：1999-11-18

    Applicant: BASF AG

    Inventor： HABECK THORSTEN DR ,  WUENSCH THOMAS DR ,  WESTENFELDER HORST

    IPC: A61K8/00 ,  A61K8/40 ,  A61Q17/00 ,  A61Q17/04 ,  C07C67/343 ,  C07C69/618 ,  C07C253/30 ,  C07C255/41 ,  C09K3/00 ,  A61K7/42

    Abstract: New oligomeric 4,4-diarylbutadiene carboxylic acid ester or amide sunscreen compounds. Oligomeric 4,4-diarylbutadiene carboxylic acid esters or amides of formula (I) are new. R1, R2 = H; aliphatic-, cycloaliphatic-, aromatic- or araliphatic- group; or carboxylate, sulfonate or ammonium; R3 = aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic group; carbonyl, sulfonyl, phosphonyl, carboxylic acid ester or CN; Y = O or N(R4); R4 = H or aliphatic-, cycloaliphatic-, aromatic-,araliphatic or heterocyclic group; m = 2-10; n = 1-3 X = the residue of a polyol with 2-10 OH groups (corresponding to m). Am Independent claim is included for preparation of (I).

    24.
    发明专利
    未知

    公开(公告)号：AT246672T

    公开(公告)日：2003-08-15

    申请号：AT99122878

    申请日：1999-11-18

    Applicant: BASF AG

    Inventor： HABECK THORSTEN DR ,  WUENSCH THOMAS DR ,  WESTENFELDER HORST

    IPC: A61K8/00 ,  A61K8/40 ,  A61Q17/00 ,  A61Q17/04 ,  C07C67/343 ,  C07C69/618 ,  C07C253/30 ,  C07C255/41 ,  C09K3/00 ,  A61K7/42

    Abstract: New oligomeric 4,4-diarylbutadiene carboxylic acid ester or amide sunscreen compounds. Oligomeric 4,4-diarylbutadiene carboxylic acid esters or amides of formula (I) are new. R1, R2 = H; aliphatic-, cycloaliphatic-, aromatic- or araliphatic- group; or carboxylate, sulfonate or ammonium; R3 = aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic group; carbonyl, sulfonyl, phosphonyl, carboxylic acid ester or CN; Y = O or N(R4); R4 = H or aliphatic-, cycloaliphatic-, aromatic-,araliphatic or heterocyclic group; m = 2-10; n = 1-3 X = the residue of a polyol with 2-10 OH groups (corresponding to m). Am Independent claim is included for preparation of (I).

    25.
    发明专利
    未知

    公开(公告)号：AT241954T

    公开(公告)日：2003-06-15

    申请号：AT99122884

    申请日：1999-11-18

    Applicant: BASF AG

    Inventor： HABECK THORSTEN DR ,  PRECHTL FRANK DR ,  WUENSCH THOMAS DR ,  WESTENFELDER HORST

    IPC: A61K8/00 ,  A61K8/30 ,  A61K8/40 ,  A61K8/49 ,  A61K31/275 ,  A61K31/277 ,  A61Q1/00 ,  A61Q1/04 ,  A61Q17/04 ,  A61Q19/00 ,  C07C255/37 ,  A61K7/42

    Abstract: alpha -Alkyl-styryl derivatives (I) are used as photostable UV-filter in cosmetic or pharmaceutical compositions for protecting the human skin or hair against the sun light, optionally combined with other components absorbing in the UV range. alpha -Alkyl-styryl derivatives of formula (I) are used as photostable UV-filter in cosmetic or pharmaceutical compositions for protecting the human skin or hair against the sun light, optionally combined with other components absorbing in the UV range. R , R = H, OH, NH2, 1-12C alkyl, 1-12C alkoxy, 1-12C alkylamino, 1-12C dialkylamino, water soluble substituents such as carboxylate, sulfonate or ammonium residues; R , R = COOR , COR , CONR R or CN; R = 1-12C alkyl; R , R = H, 1-12C alkyl, 2-10C alkenyl, 3-10C cycloalkyl, 3-10C cycloalkenyl, aryl or heteroaryl (all optionally substituted); A = O, S or NR B' = 1-12C alkylene, 4-12C cycloalkylene, 8-22C aralkylene, 9-21C monooxoaralkylene or -(X)n-Y'-; R = H or 1-12C alkyl; X = -(CH2)2-Z-, -(CH2)3-Z-, -CH(CH3)2-CH2-Z-, -(CH2)4-Z- or -CH2-CH(CH2-CH3)-Z-; Y' = -(CH2)2-, -(CH2)3-, -CH(CH3)-CH2-, -(CH2)4- or -CH2-CH(CH2-CH3)-; Z = O or S; n = 1-150; two of R , R and R = form 5- to 6-membered ring fused to the benzene ring. An Independent claim is also included for a sunscreen comprising the cosmetic and pharmaceutical composition for protecting the human epidermis and hair against UV light (280-400 nm) containing (I).

    PROCESS FOR PREPARING ALKYL ESTERS OF (METH) ACRYLIC ACID
    29.
    发明专利
    PROCESS FOR PREPARING ALKYL ESTERS OF (METH) ACRYLIC ACID 未知

    公开(公告)号：MY157865A

    公开(公告)日：2016-07-29

    申请号：MYPI20060849

    申请日：2006-02-28

    Applicant: BASF AG

    Inventor： HABECK THORSTEN DR ,  RAUH ULRICH ,  FRIESE THORSTEN DR ,  MARTAN HANS DR

    IPC: C07C67/54

    Abstract: A PROCESS IS DESCRIBED FOR CONTINUOUSLY PREPARING ALKYL ESTERS OF (METH)ACRYLIC ACID BY REACTING (METH)ACRYLIC ACID AND ALKANOLS HAVING FROM 1 TO 5 CARBON ATOMS IN HOMOGENEOUS, LIQUID, SOLVENT-FREE PHASE AT ELEVATED TEMPERATURE AND IN THE PRESENCE OF AN ACIDIC ESTERIFICATION CATALYST, IN WHICH - THE (METH) ACRYLIC ACID, THE ALKANOL AND THE ACIDIC ESTERIFICATION CATALYST ARE FED TO A REACTION ZONE (5, 6), - A REACTION MIXTURE (21) IS DISCHARGED FROM THE REACTION ZONE (5: 6). AND IS INTRODUCED INTO A RECTIFICATION UNIT I AND SEPARATED BY ADDITION OF WATER INTO A TOP STREAM (23), COMPRISING THE ALKYL ESTER OF (METH)ACRYLIC ACID, AND A BOTTOM STREAM (22), AND - A SUBSTREAM OF THE BOTTOM STREAM (22) FROM THE RECTIFICATION UNIT I IS FED TO A RESIDUE DISSOCIATION UNIT IV, WHICH COMPRISES A DISSOCIATING BOILER (61). AND IS SEPARATED THEREIN INTO A TOP STREAM (29), WHICH IS RECYCLED INTO THE RECTIFICATION UNIT I AND A BOTTOM STREAM (40). WHICH IS REMOVED FROM THE SYSTEM, WHEREIN THE RESIDUE DISSOCIATION UNIT IV, AS WELL AS THE DISSOCIATING BOILER (61), FURTHER COMPRISES A RECTIFICATION COLUMN (62), THE WATER CONTENT OF THE LIQUID OBTAINED AT THE BOTTOMMOST STAGE THEREOF BEING LESS THAN 0.1% BY WEIGHT.

    30.
    发明专利
    未知

    公开(公告)号：DE50013446D1

    公开(公告)日：2006-10-26

    申请号：DE50013446

    申请日：2000-05-22

    Applicant: BASF AG

    Inventor： HABECK THORSTEN DR ,  PRECHTL FRANK DR ,  WUENSCH THOMAS DR ,  WESTENFELDER HORST

    IPC: A61K8/49 ,  C07D233/64 ,  A61K8/00 ,  A61K8/02 ,  A61K8/06 ,  A61K47/22 ,  A61Q1/00 ,  A61Q1/04 ,  A61Q17/04 ,  C07D235/16 ,  C07D239/70 ,  C07D263/56 ,  C07D277/64 ,  C08K5/3447 ,  C08K5/35 ,  C08K5/47

    Abstract: Use of new and known bicyclic and tricyclic enamines as UV filters in cosmetic and pharmaceutical preparations is new. Also new is their use for the protection of plastics. Use of bicyclic and tricyclic enamines as UV filters in cosmetic and pharmaceutical preparations is new. R and R = CN; alkylcarbonyl; alkoxycarbonyl; aryloxycarbonyl; or optionally substituted aminocarbonyl; R = H; 1-20C alkyl; 3-20C cycloalkyl; or -CH2-CH2-SO3 M ; M = cation; X = -O-; -S-; or -N(R )-; Z' = group of formula (ii) or (iii): R = H; alkyl, cycloalkyl, alkoxy, cycloalkoxy, alkoxycarbonyl, alkyl-NH-CO-, (alkyl)2-NH-CO-, alkyl-NH- or (alkyl)2N- (each with up to 20C); CN; NH2; or SO3 M and more than 1 R can be present. Independent claims are also included for: (1) the use of compounds (I) as light screening agents for the protection of plastics; (2) (I; Z' = (iii); and (3) (I; Z' = (ii); R4 = R40; R1, R2 = R10, R20 respectively) R and R = CN or 2-10C alkoxycarbonyl optionally substituted with -(CH2)n-SO3 M ; R = H; CH3; or -(CH2)n-SO3 M ; R = H; 1-8C alkyl; 1-8C alkoxy; or -SO3 M ; n = 2 or 3; M = H or HN(R )(R )(R ) ; R -R = H lower alkyl optionally substituted with OH; or a metal cation; but at least one -(CH2)n-SO3 M or -SO3 M must be present.

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