THIOCHROMENONE DERIVATIVES AS ANTIDOTES, AND HERBICIDES CONTAINING THEM

    公开(公告)号:CA2087921A1

    公开(公告)日:1993-07-24

    申请号:CA2087921

    申请日:1993-01-22

    Abstract: O.Z. 0050/42969 Thiochromenone derivatives as antidotes, and herbicides containg them Herbicidal agents containing at least one thiochromenone of the formula I where n is 1, 2, 3 or 4, and the radicals R3 may have different meanings when n is > 1; R1 is hydrogen; cyano; halogen; substituted or unsubstituted alkyl, aryl or hetaryl; a group -XR4 or a group -COYR4, where X is oxygen, sulfur and NR5, Y is oxygen and NR5, R4 is one of the following groups: hydrogen; formyl; alkyl; cycloalkyl; alkylcarbonyl; cycloalkylcarbonyl; alkylsulfonyl; cycloalkylsulfonyl; substituted or unsubstituted aryl, hetaryl, arylcarbonyl, hetarylcarbonyl, arylsulfonyl or hetarylsulfonyl; and R5 is hydrogen or substituted or unsubstituted alkyl, aryl or hetaryl; O.Z. 0050/42969 R2 is hydrogen; cyano; nitroso; nitro; halogen; substituted or unsubstituted alkyl, alkoxy, alkylthio, aryl or hetaryl; a group -NR4R5 or a group -COYR4, where Y, R4 and R5 have the above meanings; R3 is hydrogen; cyano; halogen; substituted or unsubstituted alkyl, aryl or hetaryl; a group -YR4, a group -COYR4, a group -COR6 or a group -SO2R7, where Y and R4 have the above meanings; R6 is one of the following groups: hydrogen; alkyl; cycloalkyl; substituted or unsubstituted aryl or hetaryl; and R7 is hydrogen; alkyl; cycloalkyl; substituted or unsubsti tuted aryl or hetaryl; or a group -NR4R5, where R4 and R5 have the above meanings, and the plant-tolerated salts of those compounds I in which one or several of the substituents denote an acidic or basic group, and at least one herbicidal active ingredient.

    SELECTIVE HERBICIDE COMPOSITIONS CONTAINING 2,3-SUBSTITUTED 1,8-NAPHTIRIDINES AS ANTIDOTUMS AND CYCLOHEXANONE DERIVATIVES AS HERBICIDE ACTIVE COMPONENTS AND PROCESS FOR SELECTIVE WEED-KILLING

    公开(公告)号:HU206428B

    公开(公告)日:1992-11-30

    申请号:HU138690

    申请日:1990-03-09

    Applicant: BASF AG

    Abstract: 2,3-Substituted 1,8-naphthyridines of the general formula I in which the substituents have the following meaning: R denotes hydrogen or C1-C4-alkyl (n = 1 or 2> R denotes amino, substituted amino, XR , in which X is oxygen or sulphur and R represents hydrogen, C1-C12-alkyl, C1-C4-alkoxycarbonyl-(C1-C4)alkyl, C5-C8-cycloalkyl, substituted or unsubstituted phenyl, substituted or unsubstituted phenyl(C1-C3)-alkyl, halogen, isothiuronium halide, C1-C12-alkyl, C1-C4-alkoxycarbonyl- C1-C4-alkyl, substituted or unsubstituted phenyl or phenyl-(C1-C3)-alkyl, R denotes C1-C4-alkyl, cyano, carboxyl, a group or in which X denotes oxygen or sulphur B denotes C1-C6-alkyl, C1-C6-alkoxy or alkylthio, amino, mono- or dialkylamino having 1 to 4 C atoms per alkyl radical, morpholino, piperidyl, chlorine, bromine or substituted or unsubstituted phenyl, D denotes C1-C4-alkyl or NH2 and R denotes hydrogen, C1-C8-alkyl or alkylcarbonyl, or R and R together denote -NH-N=C(CH2)-, and non-phytotoxic salts thereof, with the proviso that, if R denotes methyl, hydroxyl or amino (NH2), R does not represent cyano, carboxyl, a carboxamido or carboxylic ester group, processes for their preparation and herbicides containing at least one naphthyridine I as antidote and at least one herbicidal active ingredient from the group comprising a) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid derivatives or b) cyclohexenone derivatives.

    HERBICIDES CONTAINING SUBSTITUTED 2-AMINOTHIOPHENES

    公开(公告)号:CA2098016A1

    公开(公告)日:1992-06-14

    申请号:CA2098016

    申请日:1991-12-03

    Applicant: BASF AG

    Abstract: 2098016 9210094 PCTABS00013 Herbicidal agents contain as antagonistic compound at least one substituted 2-aminothiophene having formula (I), in which R1, R2 stand for H, CN, alkyl, halogen alkyl, if necessary substituted phenyl, CO-R6 or R1 + R2 stand for a C3-C6 alkylene chain, upon which a benzene ring, if necessary substituted, may be annulated, a C2-C3 alkylene chain broken by -O- or -N(R7)-, which may also carry 1-4 alkenyl residues or a group CO-N(R7)-CO; R3 stands for CN, if necessary substituted -C(NH2)=N-C6H5, -C(NH3+Hal-)=N-C6H5, CX-R6; Hal stands for halogen; R4 stands for H, alkyl, alkenyl, if necessary substituted phenyl, if necessary substituted triazin, -PX(OR8)2, -CX-R9, -SO2R10, -SO2-NHR10, -CX-N(R7)-CY-R8, -CX-N(R7)-SO2-R11 or R3=R4 stand for CO-O-CO; R5 stands for H, alkyl, -CX-R9, -SO2-R10; X, Y stand for O, S; R7 stands for H, phenyl, alkyl; R8 stands for H, alkyl, if necessary substituted phenyl; R9 stands for alkyl, halogen alkyl, alkenyl, halogen alkenyl, if necessary substituted cycloalkyl or cycloalkenyl, NH2, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted phenyl or phenylamino; R10 stands for alkyl, if necessary substituted phenyl; R11 stands for NH2, alkylamino, dialkylamino, if necessary substituted pyrrolidinyl, piperidinyl, morpholinyl, piperazinyl; R4 + R5 stand for =CR12R13 or -CO-W-CO-; R12 stands for H, NH2, alkylamino, cycloalkylamino; R13 stands for NH2, alkylamino, dialkylamino, cycloalkylamino, if necessary substituted thienylamino, pyrrolidinyl, piperidinyl, morpholinyl, if necessary substituted phenyl or pyridyl; W stands for an ethylene or ethenylene bridge, if necessary substituted, or for an aromatic or heteroaromatic 5/6 membered cycloalkylene or cycloalkenylene bridge, if necessary substituted. Also disclosed are a basic salt of compound (I), in which R3 stands for hydroxycarbonyl, hydroxythiocarbonyl, or an acid salt of compound (I) which contains a basic hydrogen atom, and at least one herbicidal active substance from (A) the group of 4-aryloxy- and 4-heteroaryloxy-phenoxyacetic acid derivates or from (B) the group of cyclohexan-1,3-dione derivates.

    ANTIDOTUMS CONTAINING 2,3-SUBSTITUTED 1,8-NAPHTIRIDINES, ANTIDOTED HERBICIDE KOMPOSITIONS AND PROCESS FOR PRODUCING THE ACTIVE COMPONENTS

    公开(公告)号:HUT53774A

    公开(公告)日:1990-12-28

    申请号:HU138690

    申请日:1990-03-09

    Applicant: BASF AG

    Abstract: 2,3-Substituted 1,8-naphthyridines of the general formula I in which the substituents have the following meaning: R denotes hydrogen or C1-C4-alkyl (n = 1 or 2> R denotes amino, substituted amino, XR , in which X is oxygen or sulphur and R represents hydrogen, C1-C12-alkyl, C1-C4-alkoxycarbonyl-(C1-C4)alkyl, C5-C8-cycloalkyl, substituted or unsubstituted phenyl, substituted or unsubstituted phenyl(C1-C3)-alkyl, halogen, isothiuronium halide, C1-C12-alkyl, C1-C4-alkoxycarbonyl- C1-C4-alkyl, substituted or unsubstituted phenyl or phenyl-(C1-C3)-alkyl, R denotes C1-C4-alkyl, cyano, carboxyl, a group or in which X denotes oxygen or sulphur B denotes C1-C6-alkyl, C1-C6-alkoxy or alkylthio, amino, mono- or dialkylamino having 1 to 4 C atoms per alkyl radical, morpholino, piperidyl, chlorine, bromine or substituted or unsubstituted phenyl, D denotes C1-C4-alkyl or NH2 and R denotes hydrogen, C1-C8-alkyl or alkylcarbonyl, or R and R together denote -NH-N=C(CH2)-, and non-phytotoxic salts thereof, with the proviso that, if R denotes methyl, hydroxyl or amino (NH2), R does not represent cyano, carboxyl, a carboxamido or carboxylic ester group, processes for their preparation and herbicides containing at least one naphthyridine I as antidote and at least one herbicidal active ingredient from the group comprising a) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid derivatives or b) cyclohexenone derivatives.

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