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    21.
    发明专利
    未知

    公开(公告)号：DE19623413A1

    公开(公告)日：1997-12-18

    申请号：DE19623413

    申请日：1996-06-12

    Applicant: BASF AG

    Inventor： HIBST HARTMUT PROF DR

    IPC: B01J23/00 ,  B01J37/02

    Abstract: A process for producing a cup catalyst in which the active compound or a precursor compound thereof is placed together with the substrates in a cylindrical jar which is moved in such a way that its overall movement consists of a superimposition of a rotary movement of the cylindrical jar and a circular movement of its longitudinal axis.

    22.
    发明专利
    未知

    公开(公告)号：DE19542755A1

    公开(公告)日：1997-05-22

    申请号：DE19542755

    申请日：1995-11-16

    Applicant: BASF AG

    Inventor： HIBST HARTMUT PROF DR ,  TENTEN ANDREAS DR ,  MAROSI LASZLO DR

    IPC: C01G1/00 ,  B01J23/00 ,  B01J23/20 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  C01G31/00 ,  C01G39/00 ,  C01G41/00 ,  C07B61/00 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/38 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C07B33/00 ,  C07B35/04 ,  B01J23/24 ,  B01J23/85

    Abstract: A multimetal oxide of formula (I) Mo12-a-b-cVaM bM cOx is new, where: M = tungsten (W) and/or niobium (Nb); M = titanium (Ti), zirconium (Zr), hafnium (Hf), tantalum (Ta), chromium (Cr), silicon (Si) and/or germanium (Ge); a = 0.1-6; b = 0-6; c = 0-6; a+b+c = 0.1-6; and x = number determined by the valency and frequency of the element in (I) except oxygen. Its atomic space arrangement is determined by powder X-ray diffraction (the intensity A of the diffracted X-ray beam as a function of two-fold diffraction angle (2&thetas; )) using Cu-K alpha -radiation ( lambda = 1.54178 Angstrom ), so that in the 2&thetas; region of 5-50 degrees the following diffraction lines are produced: Al(X-ray diffraction line) = 8.3 plus or minus 0.7 (2&thetas; degrees ); A2=14.4 plus or minus 0.7; A3=22.3 plus or minus 0.2; A4=23.5 plus or minus 0.7; A5=27.2 plus or minus 0.4; A6=32.0 plus or minus 0.8; A7=34.8 plus or minus 0.6; A8=38.7 plus or minus 0.5; A9=45.4 plus or minus 0.4; and A10=48.8 plus or minus 0.4. Also claimed are: (i) a process for catalytic gas phase oxidation of organic compounds using the above multimetal oxide; and (ii) a finely divided mixture containing the above multimetal oxide (I) and a multimetal oxide (II) of formula: M 12CudHeOy, where: M = molybdenum (Mo), W, vanadium (V), Nb and/or Ta; d = 4-30; e = 0-20; and y = a number determined by the valency and frequency of the elements in (II) except oxygen.

    METHOD FOR PRODUCING 4-VINYLCYCLOHEXENE, ETHYL BENZOLE AND STYRENE
    25.
    发明专利
    METHOD FOR PRODUCING 4-VINYLCYCLOHEXENE, ETHYL BENZOLE AND STYRENE 未知

    公开(公告)号：MY134442A

    公开(公告)日：2007-12-31

    申请号：MYPI20030539

    申请日：2003-02-17

    Applicant: BASF AG

    Inventor： WALSDORFF CHRISTIAN DR ,  SCHINDLER GOETZ-PETER DR ,  HARTH KLAUS DR ,  HIBST HARTMUT PROF DR

    IPC: C07C2/46 ,  C07C5/32 ,  C07B61/00 ,  C07C2/52 ,  C07C5/367 ,  C07C13/20 ,  C07C15/073 ,  C07C15/46

    Abstract: THE INVENTION RELATES TO A PROCESS FOR PREPARING 4-VINYLCYCLOHEXENE, WHICH COMPRISES THE STEPS (A) PROVIDING AN N-BUTANE-CONTAINING FEED GAS STREAM [4],(B) FEEDING THE N-BUTANE-CONTAINING FEED GAS STREAM INTO AT LEAST ONE DEHYDROGENATION ZONE [11] AND DEHYDROGENATING N-BUTANE TO BUTADIENE TO GIVE A PRODUCT STREAM [12] COMPRISING BUTADIENE, N-BUTANE, POSSIBLY 1-BUTENE AND 2- BUTENE AND POSSIBLY WATER VAPOR AND OTHER SECONDARY CONSTITUENTS,(C) FEEDING THE PRODUCT STREAM FROM DEHYDROGENATION, IF APPROPRIATE AFTER SEPARATING OFF WATER VAPOR AND SECONDARY CONSTITUENTS, INTO A DIMERIZATION ZONE [19] AND CATALYTICALLY DIMERIZING BUTADIENE TO GIVE A PRODUCT STREAM [20] COMPRISING 4- VINYLCYCLOHEXENE, N-BUTANE AND POSSIBLY 1-BUTENE, 2- BUTENE AND UNREACTED BUTADIENE, AND (D) SEPARATING OFF 4-VINYLCYCLOHEXENE FROM THE PRODUCT STREAM [20] FROM THE DIMERIZATION AND RECIRCULATING N-BUTANE AND POSSIBLY 1-BUTENE, 2-BUTENE AND UNREACTED BUTADIENE TO THE DEHYDROGENATION ZONE

    POLYMETAL OXIDE CONTAINING SILVER OXIDE AND VANADIUM OXIDE AND THE USE THEREOF
    26.
    发明专利
    POLYMETAL OXIDE CONTAINING SILVER OXIDE AND VANADIUM OXIDE AND THE USE THEREOF 未知

    公开(公告)号：MY121869A

    公开(公告)日：2006-02-28

    申请号：MYPI9905645

    申请日：1999-12-21

    Applicant: BASF AG

    Inventor： HEIDEMANN THOMAS DR ,  HIBST HARTMUT PROF DR ,  BAUER STEFAN ,  DIETRICH ULF

    IPC: C01G31/00 ,  B01J23/68 ,  C07C51/265 ,  C10G1/00

    Abstract: A MULTIMETAL OXIDE OF THE FORMULA I WHERE M IS A METAL SELECTED FROM THE GROUP CONSISTING OF LI, NA, K, RB, CS, TL, MG, CA, SR, BA, CU, ZN, CD, PB, CR, AU, AL, FE, CO, NI, AND/OR MO, AIS FROM 0.3 TO 1.9 AND B IS FROM 0 TO 0.5, WITH THE PROVISO THAT THE DIFFERENCE (A-B) > 0.1 AND C IS FROM 0 TO 20 AND X IS A NUMBER DETERMINED BY THE VALENCE AND AMOUNT OF ELEMENTS DIFFERENT FROM OXYGEN IN THE FORMULA I, HAS A CRYSTAL STRUCTURE GIVING AN X-RAY POWDER DIFFRACTION PATTERN WHICH DISPLAYS REFLECTIONS AT THE LATTICE SPACINGS D OF 15.23 ± 0.6, 12.16 ± 0.4, 10.68 ± 0.3, 3.41 ± 0.04, 3.09 ± 0.04, 3.02 ± 0.04, 2.36 ± 0.04 AND 1.80 ± 0.04 Å. PRECATALYSTS AND CATALYSTS PRODUCED THEREFROM FOR THE PARTIAL OXIDATION OF AROMATIC HYDROCARBONS ARE ALSO PROVIDED.

    28.
    发明专利
    未知

    公开(公告)号：ES2143702T3

    公开(公告)日：2000-05-16

    申请号：ES96117834

    申请日：1996-11-07

    Applicant: BASF AG

    Inventor： HIBST HARTMUT PROF DR ,  TENTEN ANDREAS DR ,  MAROSI LASZLO DR

    IPC: C01G1/00 ,  B01J23/00 ,  B01J23/20 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  C01G31/00 ,  C01G39/00 ,  C01G41/00 ,  C07B61/00 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/38 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055

    Abstract: A multimetal oxide of formula (I) Mo12-a-b-cVaM bM cOx is new, where: M = tungsten (W) and/or niobium (Nb); M = titanium (Ti), zirconium (Zr), hafnium (Hf), tantalum (Ta), chromium (Cr), silicon (Si) and/or germanium (Ge); a = 0.1-6; b = 0-6; c = 0-6; a+b+c = 0.1-6; and x = number determined by the valency and frequency of the element in (I) except oxygen. Its atomic space arrangement is determined by powder X-ray diffraction (the intensity A of the diffracted X-ray beam as a function of two-fold diffraction angle (2&thetas; )) using Cu-K alpha -radiation ( lambda = 1.54178 Angstrom ), so that in the 2&thetas; region of 5-50 degrees the following diffraction lines are produced: Al(X-ray diffraction line) = 8.3 plus or minus 0.7 (2&thetas; degrees ); A2=14.4 plus or minus 0.7; A3=22.3 plus or minus 0.2; A4=23.5 plus or minus 0.7; A5=27.2 plus or minus 0.4; A6=32.0 plus or minus 0.8; A7=34.8 plus or minus 0.6; A8=38.7 plus or minus 0.5; A9=45.4 plus or minus 0.4; and A10=48.8 plus or minus 0.4. Also claimed are: (i) a process for catalytic gas phase oxidation of organic compounds using the above multimetal oxide; and (ii) a finely divided mixture containing the above multimetal oxide (I) and a multimetal oxide (II) of formula: M 12CudHeOy, where: M = molybdenum (Mo), W, vanadium (V), Nb and/or Ta; d = 4-30; e = 0-20; and y = a number determined by the valency and frequency of the elements in (II) except oxygen.

    Production of multimetal oxide for gas phase catalytic oxidation of acrolein to acrylic acid
    29.
    发明专利
    Production of multimetal oxide for gas phase catalytic oxidation of acrolein to acrylic acid 未知

    公开(公告)号：DE19740493A1

    公开(公告)日：1999-03-18

    申请号：DE19740493

    申请日：1997-09-15

    Applicant: BASF AG

    Inventor： HIBST HARTMUT PROF DR ,  UNVERRICHT SIGNE DR ,  TENTEN ANDREAS DR

    IPC: B01J23/885 ,  B01J23/888 ,  B01J35/00 ,  C07C57/055 ,  C01G41/00 ,  C01G39/00

    Abstract: In the production of multimetal oxide compositions (I) containing copper (Cu) and molybdenum (Mo), tungsten (W), vanadium (V), niobium (Nb) and/or tantalum (Ta). the temperature at which a finely-divided precursor multimetal oxide (B) containing these metals is worked into an aqueous solution containing sources of Mo, V and optionally other elements is bX cD dX eF fX gOx; B = X 12CuhHiOy; X = W, Nb, Ta, chromium (Cr) and/or cerium (Ce); X = Cu nickel (Ni), cobalt (Co), iron (Fe), manganese (Mn) and/or zinc (Zn); X = antimony (Sb) and/or bismuth (Bi); X = lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs) and/or hydrogen (H); X = magnesium (Mg), calcium (Ca), strontium (Sr) and/or barium (Ba); X = silicon (Si), aluminium (Al), titanium (Ti) and/or zirconium (Zr); X = Mo, W, V, Nb and/or Ta; a = 1-8; b = 0.2-5; c = 0-23; d = 0-50; e = 0-2; f = 0-5; g = 0-50; h = 4-30; i = 0-20; x, y = values depending on the valency and content of the elements other than oxygen (O); p, q not = 0; p/q = 160:1 to 1:1 . The process comprises (a) preparing (B); (b) working the required amount of (B) into an aqueous solution containing sources of Mo, V and optionally other elements in the stoichiometric ratios for an oxide (A); (c) drying the aqueous mixture; and (d) molding as required and calcination at 250-600 deg C. Independent claims are also included for (a) multimetal oxide compositions (I) prepared in this way; (b) an aqueous solution containing dissolved elements corresponding to the stoichiometry of (A), which is obtained by dissolving sources of the elements in water at a temperature TL \- 60 deg C and then cooling the solution to a temperature TE less than TL; and (c) a solid obtained by drying the solution.

    30.
    发明专利
    未知

    公开(公告)号：DE19739716A1

    公开(公告)日：1999-03-11

    申请号：DE19739716

    申请日：1997-09-10

    Applicant: BASF AG

    Inventor： TELES JOAQUIM HENRIQUE DR ,  RIEBER NORBERT DR ,  BREUER KLAUS DR ,  DEMUTH DIRK DR ,  HIBST HARTMUT PROF DR ,  KAESHAMMER STEFAN DR ,  ETZRODT HEINZ DR ,  KAISER WULF DR

    IPC: B01J23/06 ,  C07B61/00 ,  C07C41/08 ,  C07C41/28 ,  C07C45/51 ,  C07C49/203 ,  C07C45/00 ,  C07B41/06 ,  B01J21/16

    Abstract: Unsaturated ketones, comprising optionally substituted but-3-enyl and/or buta-2.3-dienyl methyl ketones, are prepared by: (a) reacting allyl alcohols and/or propargyl alcohols with isopropenyl ethers, with formation of ketals as by-product; (b) preparing isopropenyl ethers by catalytic gas phase reaction of ketals with propyne and/or allene; and (c) feeding the ketal from stage (a) into stage (b). The but-3-enyl methyl ketones of formula (Ia) and but-2,3-dienyl methyl ketones of formula (Ib) formed, allyl alcohols of formula (IIa) and/or propargyl alcohols of formula (IIb) and isopropenyl ethers (III) used as starting materials are ketals (IV). R1, R2, R3, R4, R5 = H or (cyclo)alkyl, (cyclo)alkenyl or ar(alk)yl (optionally containing O); or R1R2 = 5-6-membered ring; and R6 = 1-4C alkyl. (III) are prepared by the gas phase reaction of (IV) and propyne or allene at elevated temperature in the presence of a heterogeneous catalyst containing Zn or Cd plus Si and O.

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