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公开(公告)号:DE50101660D1
公开(公告)日:2004-04-15
申请号:DE50101660
申请日:2001-03-23
Applicant: BASF AG
Inventor: ARNOLD HEIKO DR , FREIRE ERDBRUEGGER CRISTINA , HEIDEMANN THOMAS DR , MEYER GERALD , UNVERRICHT SIGNE , FRENZEL ANDREA DR , WULFF-DOERING JOACHIM , ANSMANN ANDREAS
IPC: B01J35/06 , B01J23/42 , B01J23/44 , B01J23/48 , B01J23/50 , B01J23/70 , B01J23/755 , B01J37/02 , C07B61/00 , C07C5/02 , C07C5/03 , C07C5/08 , C07C7/163 , C07C7/167 , C07C11/04 , C07C11/06 , C07C11/08
Abstract: In a coated catalyst having a core and at least one shell surrounding the core, the core is made up of an inert support material, the shell or shells is/are made up of a porous support substance, with the shell being attached physically to the core, and a catalytically active metal selected from the group consisting of the metals of the 10th and 11th groups of the Periodic Table of the Elements is present in finely divided form or a precursor of the catalytically active metal is present in uniformly distributed form in the shell or shells. The coated catalyst of the present invention is suitable for the reduction of unsaturated hydrocarbons. Here, better selectivities than in the case of previously known coated catalysts can be achieved. A process for producing the coated catalyst is also described.
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公开(公告)号:MY121869A
公开(公告)日:2006-02-28
申请号:MYPI9905645
申请日:1999-12-21
Applicant: BASF AG
Inventor: HEIDEMANN THOMAS DR , HIBST HARTMUT PROF DR , BAUER STEFAN , DIETRICH ULF
IPC: C01G31/00 , B01J23/68 , C07C51/265 , C10G1/00
Abstract: A MULTIMETAL OXIDE OF THE FORMULA I WHERE M IS A METAL SELECTED FROM THE GROUP CONSISTING OF LI, NA, K, RB, CS, TL, MG, CA, SR, BA, CU, ZN, CD, PB, CR, AU, AL, FE, CO, NI, AND/OR MO, AIS FROM 0.3 TO 1.9 AND B IS FROM 0 TO 0.5, WITH THE PROVISO THAT THE DIFFERENCE (A-B) > 0.1 AND C IS FROM 0 TO 20 AND X IS A NUMBER DETERMINED BY THE VALENCE AND AMOUNT OF ELEMENTS DIFFERENT FROM OXYGEN IN THE FORMULA I, HAS A CRYSTAL STRUCTURE GIVING AN X-RAY POWDER DIFFRACTION PATTERN WHICH DISPLAYS REFLECTIONS AT THE LATTICE SPACINGS D OF 15.23 ± 0.6, 12.16 ± 0.4, 10.68 ± 0.3, 3.41 ± 0.04, 3.09 ± 0.04, 3.02 ± 0.04, 2.36 ± 0.04 AND 1.80 ± 0.04 Å. PRECATALYSTS AND CATALYSTS PRODUCED THEREFROM FOR THE PARTIAL OXIDATION OF AROMATIC HYDROCARBONS ARE ALSO PROVIDED.
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公开(公告)号:DE19706526A1
公开(公告)日:1998-08-20
申请号:DE19706526
申请日:1997-02-19
Applicant: BASF AG
Inventor: GEHRER EUGEN DR , HEIDEMANN THOMAS DR , RUST HARALD , SCHAEFER HANS DIETER
IPC: C07C2/66 , C07C45/36 , C07C49/784 , B01J27/198 , C07C2/04 , C07C15/16 , C07C45/28 , C07C49/786
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公开(公告)号:MY136695A
公开(公告)日:2008-11-28
申请号:MYPI20045180
申请日:2004-12-16
Applicant: BASF AG
Inventor: STEINBRENNER ULRICH DR , HEIDEMANN THOMAS DR , ROEPER MICHAEL PROF DR , STEPHAN JUERGEN DR , NARBESHUBER THOMAS DR , TROPSCH JURGEN DR , BOTTKE NILS DR , BENFER REGINA DR
IPC: C07C2/66 , C07C303/06 , C07C309/31 , C11D1/22 , C11D11/04
Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
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公开(公告)号:AT261339T
公开(公告)日:2004-03-15
申请号:AT01933749
申请日:2001-03-23
Applicant: BASF AG
Inventor: ARNOLD HEIKO DR , FREIRE ERDBRUEGGER CRISTINA , HEIDEMANN THOMAS DR , MEYER GERALD , UNVERRICHT SIGNE , FRENZEL ANDREA DR , WULFF-DOERING JOACHIM , ANSMANN ANDREAS
IPC: B01J35/06 , B01J23/42 , B01J23/44 , B01J23/48 , B01J23/50 , B01J23/70 , B01J23/755 , B01J37/02 , C07B61/00 , C07C5/02 , C07C5/03 , C07C5/08 , C07C7/163 , C07C7/167 , C07C11/04 , C07C11/06 , C07C11/08
Abstract: In a coated catalyst having a core and at least one shell surrounding the core, the core is made up of an inert support material, the shell or shells is/are made up of a porous support substance, with the shell being attached physically to the core, and a catalytically active metal selected from the group consisting of the metals of the 10th and 11th groups of the Periodic Table of the Elements is present in finely divided form or a precursor of the catalytically active metal is present in uniformly distributed form in the shell or shells. The coated catalyst of the present invention is suitable for the reduction of unsaturated hydrocarbons. Here, better selectivities than in the case of previously known coated catalysts can be achieved. A process for producing the coated catalyst is also described.
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公开(公告)号:MY139380A
公开(公告)日:2009-09-30
申请号:MYPI20023670
申请日:2002-10-01
Applicant: BASF AG
Inventor: STEINBRENNER ULRICH DR , HEIDEMANN THOMAS DR , SCHINDLER GOETZ-PETER DR , STEPHAN JUERGEN DR , MAAS HEIKO DR
IPC: C07C15/00 , C07C309/31 , C11D1/22
Abstract: THE PREPARATION OF ALKYLARYL COMPOUNDS TAKES PLACE, INTER ALIA, BYA1) PREPARATION OF C4-OLEFIN MIXTURE FROM LPG, LNG OR MTO STREAMS,@B1) REACTION OF THE C4-OLEFIN MIXTURE OBTAINED IN THIS WAY OVER A METATHESIS CATALYST FOR THE PREPARATION OF AN OLEFIN MIXTURE COMPRISING 2-PENTENE AND/ OR 3-HEXENE AND OPTIONAL REMOVAL OF 2-PENTENE AND/ OR 3-HEXENE,CI) DIMERIZATION OF THE 2-PENTENE AND/OR 3-HEXENE OBTAINED IN STAGE B1) OVER A DIMERIZATION CATALYST TO GIVE A MIXTURE COMPRISNG C10-12 OLEFINS,D1) REACTION OF THE C10-12 OLEFIN MIXTURE OBTAINED IN STAGE B1) WITH AN AROMATIC HYDROCARBON IN THE PRESENCE OF AN ALKYLATION CATALYST TO FORM ALKYLAROMATIC COMPOUNDS, IT BEING POSSIBLE TO ADD ADDITIONAL LINEAR OLEFINS PRIOR TO THE REACTION.
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公开(公告)号:MY127995A
公开(公告)日:2007-01-31
申请号:MYPI20005464
申请日:2000-11-22
Applicant: BASF AG
Inventor: WALTER MARC DR , HEIDEMANN THOMAS DR
IPC: B01J27/02 , B01J23/755 , B01J27/053 , B01J27/043 , B01J37/02 , B01J37/20 , C07B61/00 , C07C2/08 , C07C2/10 , C07C11/107
Abstract: AN OLIGOMERIZATION CATALYST FOR OLEFINS HAVING FROM 2 TO 6 CARBON ATOMS IS PRODUCED BY TREATING ALUMINUM OXIDE WITH A NICKEL COMPOUND AND A SULFUR COMPOUND, EITHER SIMULTANEOUSLY OR FIRSTLY WITH THE NICKEL COMPOUND AND THEN WITH THE SULFUR COMPOUND, AND SUBSEQUENTLY DRYING AND CALCINING THE RESULTING CATALYST, WHEREIN A MOLAR RATIO OF SULFUR TO NICKEL IN THE FINISHED CATALYST OF FROM 0.25:1 TO 0.38: IS SET IN THIS WAY.THE CATALYST AND ITS USE ARE ALSO DESCRIBED.
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