公开(公告)号：DE3813147A1

公开(公告)日：1989-11-02

申请号：DE3813147

申请日：1988-04-20

Applicant: BASF AG

Inventor： MERGER FRANZ DR ,  HORLER HANS DR ,  HOELDERICH WOLFGANG DR ,  WITZEL TOM DR

IPC: B01J29/04 ,  B01J29/40 ,  B01J29/83 ,  B01J29/85 ,  B01J29/86 ,  B01J29/88 ,  C07B61/00 ,  C07C67/32 ,  C07C69/533

公开(公告)号：DE3808512A1

公开(公告)日：1989-09-28

申请号：DE3808512

申请日：1988-03-15

Applicant: BASF AG

Inventor： GOETZ NORBERT DR ,  HOELDERICH WOLFGANG DR ,  HUPFER LEOPOLD DR

IPC: C07C67/313 ,  C07C69/738

公开(公告)号：DE3741159A1

公开(公告)日：1989-06-15

申请号：DE3741159

申请日：1987-12-04

Applicant: BASF AG

Inventor： GOETZ NORBERT DR ,  HOELDERICH WOLFGANG DR

IPC: C07D213/12 ,  C07D213/57 ,  C07D213/84 ,  C07D213/85

Abstract: Cyanopyridines of the formula are prepared by reacting acrolein and an alkanal or its acetal or ketone of the formula where R1, R2 and R3 may be identical or different and are each hydrogen, alkyl of 1 to 6 carbon atoms or aryl and R4 is alkyl and n is 0-11, with ammonia in the presence of a zeolite as a catalyst. The reaction is preferably carried out in the gas phase.

公开(公告)号：DE3740270A1

公开(公告)日：1989-06-01

申请号：DE3740270

申请日：1987-11-27

Applicant: BASF AG

Inventor： SMUDA HUBERT DR ,  HOELDERICH WOLFGANG DR ,  GOETZ NORBERT DR ,  RECKER HANS-GERT DR

IPC: C07C45/51 ,  C07C45/52 ,  C07C45/54 ,  C07C45/58

Abstract: Phenylacetaldehydes of the general formula I (I) where R1 to R5 are each independently of the others hydrogen, alkyl, alkoxy, halogen, haloalkyl, haloalkoxy or haloalkylthio, by catalytic rearrangement in the presence of a zeolite, are prepared by reacting an epoxy of the formula II or a phenylglycol of the formula III (II) (III) where Y and Z can be identical to or different from each other and are each hydroxyl, alkoxy, aryloxy or acyloxy, in the gas phase over a borosilicate zeolite catalyst at from 70 DEG to 200 DEG C. under reduced pressure.

公开(公告)号：DE3732950A1

公开(公告)日：1989-04-20

申请号：DE3732950

申请日：1987-09-30

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  SCHWARZMANN MATTHIAS DR

IPC: C07D307/06

Abstract: Tetrahydrofurans are prepared in the gas phase from butane-1,4-diols which may be substituted by alkyl, alkenyl and/or aryl radicals in the carbon skeleton. The reaction is carried out in the presence of a borosilicate and/or iron silicate zeolite, preferably of the pentasil type, as catalyst. Other catalysts which may be used are zeolites doped with alkali metals and/or alkaline earth metals and/or transition metals and/or rare earth metals and/or noble metals.

公开(公告)号：DE3724238A1

公开(公告)日：1989-02-02

申请号：DE3724238

申请日：1987-07-22

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  HESSE MICHAEL DR ,  SCHWARZMANN MATTHIAS DR

IPC: C07F9/50

公开(公告)号：DE3720676A1

公开(公告)日：1989-01-05

申请号：DE3720676

申请日：1987-06-23

Applicant: BASF AG

Inventor： HESSE MICHAEL DR ,  HOELDERICH WOLFGANG DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J29/04 ,  B01J29/08 ,  C07C209/60 ,  C07C211/09 ,  C07C87/14 ,  C07C87/16 ,  C07C85/18

Abstract: Diamines of the formula (I) where R1, R2 and R3 are each hydrogen, alkyl, aryl, alkoxy, aralkyl or cycloalkyl and X is a group of the formula (CR4R5)m (II) where R4 and R5 have the meanings given above for R1 and m is from 1 to 12, are prepared by a process in which a diamine of the formula (III) where R1, R2 and X are the groups described above, is reacted with an olefin of the formula (IV) where R6 and R9 are each hydrogen or alkyl which is straight-chain in the alpha -position, in the presence of a zeolite as a catalyst.

公开(公告)号：DE3708737A1

公开(公告)日：1988-10-06

申请号：DE3708737

申请日：1987-03-18

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  GOETZ NORBERT DR ,  RECKER HANS-GERT DR ,  SMUDA HUBERT DR

IPC: C07C45/52 ,  C07C45/58 ,  C07C47/228 ,  C07C47/24 ,  C07C47/277 ,  C07C149/34

公开(公告)号：DE3701570A1

公开(公告)日：1988-08-04

申请号：DE3701570

申请日：1987-01-21

Applicant: BASF AG

Inventor： THOMAS JUERGEN DR ,  HIMMEL WALTER DR ,  HOELDERICH WOLFGANG DR ,  SCHWARZMANN MATTHIAS DR

IPC: C10G47/18 ,  B01J29/86 ,  C10G47/20 ,  C10G49/02

公开(公告)号：DE3632529A1

公开(公告)日：1988-04-07

申请号：DE3632529

申请日：1986-09-25

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  GOETZ NORBERT DR ,  HUPFER LEOPOLD DR ,  LERMER HELMUT DR

IPC: B01J27/16 ,  B01J27/18 ,  B01J27/182 ,  B01J27/185 ,  B01J29/04 ,  C07C45/58 ,  C07C47/228 ,  C07C49/04 ,  C07C45/51 ,  C07C11/18 ,  C07C49/213 ,  C07C47/23 ,  C07C47/02 ,  B01J29/06

Abstract: Aldehydes and ketones are prepared from epoxides of the formula where R1 and R2 are each alkyl, alkenyl, aryl, alkoxy or aralkyl and R3 has the same meanings or is hydrogen, by a catalytic rearrangement reaction in the presence of various catalysts, in particular zeolites of the pentasil type.