公开(公告)号：DE3729226A1

公开(公告)日：1989-03-23

申请号：DE3729226

申请日：1987-09-02

Applicant: BASF AG

Inventor： GOETZ NORBERT DR ,  RECKER HANS-GERT DR ,  SMUDA HUBERT DR

IPC: C07C33/46 ,  C07C27/00 ,  C07C29/136 ,  C07C29/143 ,  C07C67/00 ,  C07D301/26 ,  C07D303/02 ,  C07D303/04 ,  C07D303/08 ,  C07D303/22 ,  C07D303/34

Abstract: Phenyl-substituted epoxides of the formula where R1 and R2 are each hydrogen, alkyl, alkenyl, phenyl, halogen, nitro, alkoxy, haloalkyl, phenoxy or phenylsulfonyl, are prepared by reducing a haloacetophenone to a halohydrin and reacting the halohydrin with an alkali metal hydroxide by a process in which the reduction with the alkali metal borohydride and the reaction are carried out in aqueous organic solution, or the cyclization of a halohydrin with an alkali metal hydroxide is carried out in an organic liquid.

公开(公告)号：DE3884478D1

公开(公告)日：1993-11-04

申请号：DE3884478

申请日：1988-07-01

Applicant: BASF AG

Inventor： GOETZ NORBERT DR ,  KARBACH STEFAN DR ,  RECKER HANS-GERT DR

IPC: C07C47/232 ,  C07C45/00 ,  C07C45/48 ,  C07C45/74 ,  C07C47/24 ,  C07C67/00 ,  C07C205/44 ,  C07D213/48 ,  C07D237/08 ,  C07D239/26 ,  C07D241/12 ,  C07D261/08 ,  C07D263/32 ,  C07D263/60 ,  C07D277/24 ,  C07D307/46 ,  C07D309/32 ,  C07D333/22 ,  C07D335/02 ,  C07D521/00

Abstract: alpha , beta -Substituted acroleins of the formula I in which the radical R represents an alkoxy, phenoxy, halogen, haloalkyl, haloalkoxy, haloalkyl thiyl or nitro group, n denotes an integer from 1 to 5, it being possible for the radicals R to be identical or different if n is greater than 1 and when substituted by nitro groups the aromatic ring carries no more than 3 nitro groups, and in which R represents an alkyl, cycloalkyl, a substituted or unsubstituted aryl or heteroaryl or a heterocyclic radical, are prepared by reacting a phenylacetaldehyde of the formula II with an aldehyde of the formula III [R -CHO] III in the presence of a base and a solvent. alpha , beta -Substituted acroleins are also described.

公开(公告)号：DE3737888A1

公开(公告)日：1989-05-18

申请号：DE3737888

申请日：1987-11-07

Applicant: BASF AG

Inventor： KURBACH STEFAN DR ,  JANSSEN BERND DR ,  RECKER HANS-GERT DR ,  SMUDA HUBERT DR ,  MEYER NORBERT DR ,  JUNG JOHANN PROF DR ,  RADEMACHER WILHELM DR

IPC: A01N43/50 ,  A01N43/653 ,  C07D405/06 ,  C07D521/00

Abstract: Method of influencing plant growth, characterised in that the soil, the seed and/or the plants are treated with an azolyl methyl oxirane of the formula in which the substituents A and B represent C1-C4-alkyl, phenyl, naphthyl, diphenyl or phenyl which is substituted by one to three radicals from amongst the group comprising halogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, nitro or phenoxy and Z represents the CH group or nitrogen, or their metal salts or acid addition salts, and compositions for influencing plant growth which contain at least one azolyl methyl oxirane.

公开(公告)号：DE3881649D1

公开(公告)日：1993-07-15

申请号：DE3881649

申请日：1988-11-18

Applicant: BASF AG

Inventor： SMUDA HUBERT DR ,  HOELDERICH WOLFGANG DR ,  GOETZ NORBERT DR ,  RECKER HANS-GERT DR ,  HUPFER LEOPOLD DR

IPC: B01J29/04 ,  B01J29/86 ,  C07B61/00 ,  C07C45/00 ,  C07C45/51 ,  C07C45/52 ,  C07C45/54 ,  C07C45/58 ,  C07C45/67 ,  C07C47/228 ,  C07C47/24 ,  C07C47/27 ,  C07C47/277 ,  C07C47/453 ,  C07C47/457 ,  C07C67/00 ,  C07C319/20 ,  C07C323/22

Abstract: Prodn. of phenylacetaldehydes of formula Ar-CH2-CHO (I) is effected by (a) contacting an epoxide or glycol deriv. of formula Ar-CHY-CH2Z (II) with a borosilicate zeolite catalyst in the gas phase at 70-200 deg.C under reduced pressure or (b) contacting a phenylglycidate ester of formula (III) with a zeolite, phosphate, supported H3PO4, supported H3BO3 and/or acidic metal oxide catalyst in the liq. or gas phase at 50-500 deg.C and 0.01-50 bar, Ar is phenyl with 0-5 substits. selected from halogen and opt. halogenated alkyl, alkenyl, alkylthio and cycloalkyl, Y and Z are OH, alkoxy, aryloxy or acyloxy or Y+Z is O, R6 is t-Bu or i-Pr.

公开(公告)号：DE3842306A1

公开(公告)日：1990-06-21

申请号：DE3842306

申请日：1988-12-16

Applicant: BASF AG

Inventor： WEBER THOMAS DR ,  HECKMANN WALTER DR ,  MERTES JUERGEN DR ,  TESCH HELMUT DR ,  ALTSTAEDT VOLKER DR ,  EBERLE WOLFGANG DR ,  FOLDA THOMAS DR ,  STUTZ HERBERT DR ,  RECKER HANS-GERT DR

IPC: C08G59/00 ,  C08G59/56 ,  C08L63/00

Abstract: The invention relates to curable, impact-modified epoxy resin mixtures comprising A. an aromatic epoxide compound, B. an amine curing agent, C. 10 to 40 % by weight of an aromatic, thermoplastic oligomer containing reactive groups, preferably a polyether sulfone, and D. 0.1 to 10 % by weight of a high-molecular-weight emulsifier, preferably a phenoxy resin, an epoxy resin or a thermoplastic copolymer, which is compatible both with the epoxide compound A and with the oligomer C. The epoxy resin mixtures are suitable for the production of high-performance composite materials.

公开(公告)号：DE3722886A1

公开(公告)日：1989-01-19

申请号：DE3722886

申请日：1987-07-10

Applicant: BASF AG

Inventor： GOETZ NORBERT DR ,  KARBACH STEFAN DR ,  RECKER HANS-GERT DR

IPC: C07C47/232 ,  C07C45/00 ,  C07C45/48 ,  C07C45/74 ,  C07C47/24 ,  C07C67/00 ,  C07C205/44 ,  C07D213/48 ,  C07D237/08 ,  C07D239/26 ,  C07D241/12 ,  C07D261/08 ,  C07D263/32 ,  C07D263/60 ,  C07D277/24 ,  C07D307/46 ,  C07D309/32 ,  C07D333/22 ,  C07D335/02 ,  C07D521/00

Abstract: alpha , beta -Substituted acroleins of the formula I in which the radical R represents an alkoxy, phenoxy, halogen, haloalkyl, haloalkoxy, haloalkyl thiyl or nitro group, n denotes an integer from 1 to 5, it being possible for the radicals R to be identical or different if n is greater than 1 and when substituted by nitro groups the aromatic ring carries no more than 3 nitro groups, and in which R represents an alkyl, cycloalkyl, a substituted or unsubstituted aryl or heteroaryl or a heterocyclic radical, are prepared by reacting a phenylacetaldehyde of the formula II with an aldehyde of the formula III [R -CHO] III in the presence of a base and a solvent. alpha , beta -Substituted acroleins are also described.

公开(公告)号：AT73787T

公开(公告)日：1992-04-15

申请号：AT88113906

申请日：1988-08-26

Applicant: BASF AG

Inventor： GOETZ NORBERT DR ,  RECKER HANS-GERT DR ,  SMUDA HUBERT DR

IPC: C07C33/46 ,  C07C27/00 ,  C07C29/136 ,  C07C29/143 ,  C07C67/00 ,  C07D301/26 ,  C07D303/02 ,  C07D303/04 ,  C07D303/08 ,  C07D303/22 ,  C07D303/34

公开(公告)号：DE3740270A1

公开(公告)日：1989-06-01

申请号：DE3740270

申请日：1987-11-27

Applicant: BASF AG

Inventor： SMUDA HUBERT DR ,  HOELDERICH WOLFGANG DR ,  GOETZ NORBERT DR ,  RECKER HANS-GERT DR

IPC: C07C45/51 ,  C07C45/52 ,  C07C45/54 ,  C07C45/58

Abstract: Phenylacetaldehydes of the general formula I (I) where R1 to R5 are each independently of the others hydrogen, alkyl, alkoxy, halogen, haloalkyl, haloalkoxy or haloalkylthio, by catalytic rearrangement in the presence of a zeolite, are prepared by reacting an epoxy of the formula II or a phenylglycol of the formula III (II) (III) where Y and Z can be identical to or different from each other and are each hydroxyl, alkoxy, aryloxy or acyloxy, in the gas phase over a borosilicate zeolite catalyst at from 70 DEG to 200 DEG C. under reduced pressure.

公开(公告)号：DE3708737A1

公开(公告)日：1988-10-06

申请号：DE3708737

申请日：1987-03-18

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  GOETZ NORBERT DR ,  RECKER HANS-GERT DR ,  SMUDA HUBERT DR

IPC: C07C45/52 ,  C07C45/58 ,  C07C47/228 ,  C07C47/24 ,  C07C47/277 ,  C07C149/34

公开(公告)号：DE3601927A1

公开(公告)日：1987-07-30

申请号：DE3601927

申请日：1986-01-23

Applicant: BASF AG

Inventor： JANSSEN BERND DR ,  KARBACH STEFAN DR ,  RECKER HANS-GERT DR ,  THYES MARCO DR

IPC: C07C47/238 ,  C07C45/00 ,  C07C45/51 ,  C07C47/21 ,  C07C47/22 ,  C07C47/228 ,  C07C47/232 ,  C07C47/24 ,  C07C47/277 ,  C07C67/00 ,  C07D301/12 ,  C07D303/14 ,  C07D303/16 ,  C07D303/32

Abstract: Alpha,beta-substituted acroleins of the general formula I (I) where A and B are identical or different and are each C1-C4-alkyl, naphthyl, biphenyl or phenyl which may be monosubstituted or polysubstituted by halogen, nitro, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, phenoxy or phenylsulfonyl, are prepared by a process in which a compound of the general formula III (III) where A has the above meanings and R1 and R2 are identical or different and are each C1-C4-alkyl or together possess the carbon atoms required to complete a ring, is reacted with a phosphorus compound of the general formula IV or V (IV) (V) where B the meanings stated above, R1 and R2 are as defined above and X(-) is a halide ion, in the presence of a base. The alpha,beta-substituted acroleins can be further processed to give hydroxymethyloxiranes.