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公开(公告)号:DE1110408B
公开(公告)日:1961-07-06
申请号:DEB0055873
申请日:1959-12-11
Applicant: BASF AG
Inventor: KELLER DR LOTHAR , REINHARD DR HANS , PETRI ROLF
IPC: C08J9/14
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公开(公告)号:DE1102390B
公开(公告)日:1961-03-16
申请号:DEB0055872
申请日:1959-12-11
Applicant: BASF AG
Inventor: KELLER DR LOTHAR , REINHARD DR HANS , PETRI ROLF
IPC: C08J9/10
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公开(公告)号:NO306610B1
公开(公告)日:1999-11-29
申请号:NO915072
申请日:1991-12-20
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD , WISTUBA ECKEHARDT , SCHWARTZ MANFRED , PETRI ROLF , BECHERT BERTOLD , DENU HANS-JUERGEN
IPC: C04B41/48 , C04B41/62 , C04B41/63 , C09D133/06
Abstract: A concrete tile (I) is claimed, which is coated with a copolymer (A) with Tg -25 to +30 deg.C, derived from (a) 0.1-10 wt.% monomer of formula R1CH=CR2-CO-X-R3-Z-CHR4R5 (III), (b) 85-99.9 wt.% at least 2 monomers of the type (1-24C alkyl) (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, 3-6C unsatd. nitriles, vinyl halides and/or 2-8C non-aromatic hydrocarbons with olefinic double bond(s), and (c) 0-10 wt.% other Sn-free comonomers; R1, R2 = H or 1-4C alkyl; R3 = 1-20C bridging gp.; R4 = -COR6, -COOR6 or CN; R5 = H, -COR9, -COOR9 or CN; X = O or NR7; Z = single bond, CH2, O, NR8 or -OCO-; (with R6-R9 = H, or 1-12C alkyl, aryl, alkaryl or aralkyl). Also claimed is a process for the prodn. of (I), by application of an aq. prepn. contg. (A) to at least one surface of the green concrete, and drying the prepn. by hardening the concrete. More specifically, monomer (a) is acetylacetoxyethyl (meth)acrylate, acetylacetoxybutyl (meth)acrylate, cyanoacetoxyethyl (meth)acrylate, 1,1-dibenzoyl-2-(meth)acrylamidoethane, 1-benzoyl-1-acetyl-2- (meth)acrylamidoethane, or ethyl alpha-benzoyl-beta-(meth) acrylamidopropionate, and (b) are vinylaromatics or (1-8C alkyl) (meth)acrylates; (I) is coated with a prepn. contg. copolymer (A) and up to 450 wt.% mineral additives (B) and/or colour pigments (C) (w.r.t. amt. of A); another layer of the aq. prepn. is applied to the hardened tile and dried; the amt. of prepn. used is such that the total amt. of dry coating is 50-500 g/m2.
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公开(公告)号:NO303627B1
公开(公告)日:1998-08-10
申请号:NO912625
申请日:1991-07-04
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD , WISTUBA ECKEHARDT , SCHWARTZ MANFRED , PETRI ROLF , BECHERT BERTOLD
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公开(公告)号:ES2064813T3
公开(公告)日:1995-02-01
申请号:ES91110520
申请日:1991-06-26
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD DR , WISTUBA ECKEHARDT DR , SCHWARTZ MANFRED DR , PETRI ROLF , BECHERT BERTOLD
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公开(公告)号:NO915072L
公开(公告)日:1992-06-23
申请号:NO915072
申请日:1991-12-20
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD , WISTUBA ECKEHARDT , SCHWARTZ MANFRED , PETRI ROLF , BECHERT BERTOLD , DENU HANS-JUERGEN
IPC: C04B41/48 , C04B41/62 , C04B41/63 , C09D133/06 , C09D133/00
Abstract: A concrete tile (I) is claimed, which is coated with a copolymer (A) with Tg -25 to +30 deg.C, derived from (a) 0.1-10 wt.% monomer of formula R1CH=CR2-CO-X-R3-Z-CHR4R5 (III), (b) 85-99.9 wt.% at least 2 monomers of the type (1-24C alkyl) (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, 3-6C unsatd. nitriles, vinyl halides and/or 2-8C non-aromatic hydrocarbons with olefinic double bond(s), and (c) 0-10 wt.% other Sn-free comonomers; R1, R2 = H or 1-4C alkyl; R3 = 1-20C bridging gp.; R4 = -COR6, -COOR6 or CN; R5 = H, -COR9, -COOR9 or CN; X = O or NR7; Z = single bond, CH2, O, NR8 or -OCO-; (with R6-R9 = H, or 1-12C alkyl, aryl, alkaryl or aralkyl). Also claimed is a process for the prodn. of (I), by application of an aq. prepn. contg. (A) to at least one surface of the green concrete, and drying the prepn. by hardening the concrete. More specifically, monomer (a) is acetylacetoxyethyl (meth)acrylate, acetylacetoxybutyl (meth)acrylate, cyanoacetoxyethyl (meth)acrylate, 1,1-dibenzoyl-2-(meth)acrylamidoethane, 1-benzoyl-1-acetyl-2- (meth)acrylamidoethane, or ethyl alpha-benzoyl-beta-(meth) acrylamidopropionate, and (b) are vinylaromatics or (1-8C alkyl) (meth)acrylates; (I) is coated with a prepn. contg. copolymer (A) and up to 450 wt.% mineral additives (B) and/or colour pigments (C) (w.r.t. amt. of A); another layer of the aq. prepn. is applied to the hardened tile and dried; the amt. of prepn. used is such that the total amt. of dry coating is 50-500 g/m2.
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公开(公告)号:DE4021502A1
公开(公告)日:1992-01-16
申请号:DE4021502
申请日:1990-07-05
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD DR , WISTUBA ECKEHARDT DR , SCHWARTZ MANFRED DR , PETRI ROLF , BECHERT BERTOLD
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公开(公告)号:FI910567A0
公开(公告)日:1991-02-06
申请号:FI910567
申请日:1991-02-06
Applicant: BASF AG
Inventor: DOTZAUER BERNHARD , WISTUBA ECKEHARDT , SCHWARTZ MANFRED , PETRI ROLF , BECHERT BERTOLD
IPC: C04B41/48 , C04B41/63 , C09D133/08 , C04B
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公开(公告)号:CH595404A5
公开(公告)日:1978-02-15
申请号:CH629175
申请日:1975-05-15
Applicant: BASF AG
Inventor: HAMPEL UWE , PETRI ROLF , PETERSEN HARRO DR , LENZ JOHANN , MATTHIAS GUENTHER DR , REUTHER WOLFGANG DR
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公开(公告)号:DE2343457A1
公开(公告)日:1975-04-17
申请号:DE2343457
申请日:1973-08-29
Applicant: BASF AG
Inventor: PETRI ROLF , DISTLER HARRY DR , BECHERT BERTOLD , BERGOLD WOLFRAM DIPL-CHEM DR
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