22.
    发明专利
    未知

    公开(公告)号:DE3902005A1

    公开(公告)日:1990-07-26

    申请号:DE3902005

    申请日:1989-01-25

    Applicant: BASF AG

    Abstract: Thiophene azo dyes of the formula … … in which… X denotes cyano or C1-C4-alkoxycarbony,… Y denotes halogen, hydroxyl, mercapto, optionally substituted C1-C6-alkoxy, C5-C7-cycloalkoxy, optionally substituted phenoxy, optionally substituted C1-C6-alkylthio, C5-C7-cycloalkylthio, optionally substituted phenylthio, C1-C6-alkylsulphonyl or optionally substituted phenylsulphonyl,… Z denotes nitro, cyano, C1-C4-alkanoyl, benzoyl, C1-C4-alkylsulphonyl, phenylsulphonyl or a radical of the formula -CH=CB B or -CH=N-B , where B and B independently of one another stand for cyano, optionally substituted C1-C6-alkoxycarbonyl or C3-C6-alkenyloxycarbonyl or one radical B or B stands for cyano and the other for C1-C4-alkylsulphonyl, optionally substituted phenyl, benzoyl, phenylsulphonyl or carbamoyl and B stands for hydroxyl, C1-C4-alkoxy, phenoxy or phenylamino,… R denotes C1-C4-alkoxy,… R denotes hydrogen, optionally substituted C1-C10-alkyl or R ,… R denotes a radical of the formula CH2-CH(OR )-CH2R and… R denotes optionally substituted C1-C6-alkanoylamino or optionally substituted benzoylamino, where… R stands for hydrogen, C1-C10-alkanoyl, C1-C10-alkoxycarbonyl or C1-C10-mono- or dialkylcarbamoyl, where the alkyl groups of the substituents mentioned can be interrupted by oxygen atoms, and… R stands for chlorine, bromine or optionally substituted hydroxyl,… and their use for dyeing textile fibres.

    27.
    发明专利
    未知

    公开(公告)号:DE3738374A1

    公开(公告)日:1989-05-24

    申请号:DE3738374

    申请日:1987-11-12

    Applicant: BASF AG

    Abstract: Thien-3-ylazo dyes of the formula: where X is cyano, nitro, C1-C6-alkanoyl, substituted or unsubstituted benzoyl, substituted or unsubstituted phenyl or the radical COOR1 or CONR1R2 where R1 and R2 are identical or different and each is independently of each other substituted or unsubstituted C1-C8-alkyl, C5-C7-cycloalkyl, C3-C4-alkenyl, substituted or unsubstituted phenyl or together with the nitrogen atom linking them a 5- or 6-membered saturated heterocyclic radical, and R2 may additionally be hydrogen, Y is hydrogen, cyano, C1-C6-alkanoyl, substituted or unsubstituted benzoyl, C1-C4-alkylsulfonyl, substituted or unsubstituted phenylsulfonyl, substituted or unsubstituted phenyl or the radical COOR1 or CONR1R2 where R1 and R2 are each as defined above, Z is hydrogen, substituted or unsubstituted C1-C8-alkyl, substituted or unsubstituted phenyl, substituted or unsubstituted C1-C6-alkylthio, substituted or unsubstituted phenylthio, substituted or unsubstituted C1-C6-alkylsulfonyl or phenylsulfonyl or together with the radical Y a fused benzo ring which may be substituted, and K is the radical of a coupling component of the 2,6-diaminopyridine, 6-hydroxypyrid-2-one or 5-aminopyrazole series, are used for dyeing synthetic fiber materials, in particular synthetic polyesters, in yellow to red shades and are notable for good light fastness, fastness to dry heat setting and pleating and for good affinity.

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