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公开(公告)号:DE59405873D1
公开(公告)日:1998-06-10
申请号:DE59405873
申请日:1994-02-10
Applicant: BASF AG
Inventor: WEISEN JUERGEN DR , REUTHER WOLFGANG DR , HAHN ERWIN DR
IPC: C08G14/10 , C08J11/16 , C09D161/34 , C14C3/20
Abstract: A process for the recycling of cured amino resins in which cured amino resins, optionally containing fillers, are treated with an aqueous sulphite, hydrogen sulphite or disulphite solution and the resultant low-molecular-weight degradation products are employed in chemical processes. The invention also relates to the low-molecular-weight degradation products of cured amino resins which are obtainable by this process, and to their use for the coating of mouldings, for the tanning of leather and hides, and for the production of mouldings containing or comprising cured amino resins.
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公开(公告)号:DE59306076D1
公开(公告)日:1997-05-15
申请号:DE59306076
申请日:1993-01-14
Applicant: BASF AG
Inventor: HAHN ERWIN DR , HENGELSBERG HEIDI DR , MAYER UDO DR
Abstract: Basic azo dyes useful for dyeing or printing polymeric material have the formula (* CHEMICAL STRUCTURE *) where R1 is hydrogen, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-alkanoylamino, R2 is hydrogen, C1-C4-alkyl, C1-C4-alkoxy or a radical of the formula CO-X, and X is hydroxyl, C1-C4-alkoxy, amino, mono- or di(C1-C6-alkyl)amino or a radical of the formula (* CHEMICAL STRUCTURE *) (* CHEMICAL STRUCTURE *) (* CHEMICAL STRUCTURE *) where n is 0 or 1, R3, R4 and R5 are hydrogen or substituted or unsubstituted C1-C4-alkyl, R6 is hydrogen or C1-C4-alkyl, L is C2-C6-alkylene, and An(negative earth) is one equivalent of an anion, with the proviso that at least one basic or quaternary radical is present in the molecule.
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公开(公告)号:DE59206937D1
公开(公告)日:1996-09-26
申请号:DE59206937
申请日:1992-05-29
Applicant: BASF AG
IPC: C09B29/042 , C09B29/00 , C09B29/08 , C09B29/09
Abstract: Thiazole azo dyestuffs of the formula … … in which …… R denotes hydrogen, optionally substituted C1-C6-alkyl, halogen, optionally substituted C1-C6-alkoxy, optionally substituted C1-C6-alkylthio, optionally substituted phenylthio, C1-C6-alkylsulphonyl, optionally substituted phenylsulphonyl or C1-C4-alkoxycarbonyl, … R denotes cyano, C1-C4-alkanoyl, benzoyl, C1-C6-alkylsulphonyl, optionally substituted phenylsulphonyl or a radical of the formula -CH = T, in which T represents the radical of a CH-acidic compound, … R denotes hydrogen, optionally substituted C1-C6-alkoxy, C1-C4-alkoxycarbonyl, carbamoyl or C1-C4-mono- or dialkyl carbamoyl, … R denotes C1-C6-alkyl, optionally substituted C1-C6-alkoxy, optionally substituted C1-C4-alkoxycarbonyloxy, optionally substituted phenoxycarbonyloxy, substituted aminocarbonyloxy, optionally substituted C1-C4-alkanoyloxy, optionally substituted C1-C4-alkanoylamino, or optionally substituted phenyl, … R denotes hydrogen, optionally substituted C1-C10-alkyl or optionally substituted C3-C5-alkenyl and … R and R denote hydrogen, halogen, cyano, optionally substituted C1-C10-alkyl, optionally substituted C1-C4-alkoxy, amino or C1-C4-mono- or dialkylamino, … and their use for the dyeing or printing of textile fibres.
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公开(公告)号:DE3788325D1
公开(公告)日:1994-01-13
申请号:DE3788325
申请日:1987-09-15
Applicant: BASF AG
Inventor: HENNING GEORG DR , HAHN ERWIN DR , HAUSER PETER DR , PATSCH MANFRED DR
IPC: C08K5/34 , C08K5/3412 , C08K5/3437 , C09B5/62 , C09B67/48 , C09D7/00 , C09D7/12 , C09D11/02
Abstract: A tetrachloroperylene-3,4,9,10-tetracarboxylic acid diimide pigment which contains not less than 85% by weight of the tetrachloro compound of the formula which is present to the extent of not less than 95% by weight in the beta -modification and which, in an X-ray spectrum, exhibits 2(-) CuK alpha main lines at 9.0 DEG , 13.3 DEG , 15.0 DEG , 16.8 DEG , 19.1 DEG , 21.5 DEG , 24.2 DEG , 25.4 DEG , 26.5 DEG , 27.0 DEG and 27.5 DEG . In finishes, the pigment gives very brilliant colorations which are very highly lightfast and fast to weathering and which, upon weathering, neither bleach nor darken up.
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公开(公告)号:DE59003404D1
公开(公告)日:1993-12-16
申请号:DE59003404
申请日:1990-05-19
Applicant: BASF AG
Inventor: HAHN ERWIN DR , BREITSCHAFT WALTER DR , MAYER UDO DR , SCHROEDER GUNTER-RUDOLF DR
IPC: C07D295/18 , C07D295/185 , C09B11/00 , C09B11/10 , C09B11/12 , C09B11/16 , C09B11/18 , D06P1/42 , D21H21/28
Abstract: Triphenylmethane dyes of the formula +TR where each R1 is independently of the others hydrogen or substituted or unsubstituted C1-C6-alkyl, or two R1 radicals together with the nitrogen atom joining them form a heterocyclic radical, R2 and R5 is independently of the others hydrogen or C1-C4-alkyl, R3 and R4 is independently of the others hydrogen, C1-C4-alkyl, C1-C4-alkoxy or halogen, An(-) is one equivalent of an anion, and n is 1 or 2, preparable from piperazine derivatives as intermediates, are useful for coloring paper.
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公开(公告)号:DE4215391A1
公开(公告)日:1993-11-18
申请号:DE4215391
申请日:1992-05-11
Applicant: BASF AG
Inventor: HAHN ERWIN DR , KRAEH CLAUDIA DR , MAYER UDO DR
Abstract: New rhodamine dyestuffs are 2,2,4,8,10,10-hexamethyl-6-(2-carboxy phenyl)-1,2,3,4,8,9,10,11-octahydro- dipyrido(3,2-a:3,2-g) xanthylium salts of formula (I). R1, R2 are H or (substd.) 1-4C alkyl; and An(-) is the equiv. of an anion. (I) may be prepd. by the prior art in e.g. J. Org. Chem., vol. 30, pp. 1832-1837, 1965; SU A-548603; and US Application 566924 (29.12.83); examples are given (below). Specifically, R1 is 1-4C alkyl or esp. H; and R2 is H or esp. 1-4C alkyl. (I) may be prepd. by reacting an opt. N-substd. 3-ethoxy aniline with acetone, giving a 7-ethoxy-2,2,4- trimethyl- dihydroquinoline, hydrogenation and treatment with HBr in glacial acetic acid and reaction of the resultant 2,2,4-trimethyl-7-hydroxy- tetrahydroquinoline with e.g. phthalic anhydride. USE/ADVANTAGE - (I) are used for dyeing polyacrylonitrile fibres, for pigmenting polymers or in ink prodn. (claimed). They may also be used as laser dyestuffs or in electrophotographic toner mfr. and have improved properties, esp. high light fastness.
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公开(公告)号:DE4021960A1
公开(公告)日:1992-01-16
申请号:DE4021960
申请日:1990-07-10
Applicant: BASF AG
Inventor: HAHN ERWIN DR , HANSEN GUENTER DR , ETZBACH KARL-HEINZ DR , REICHELT HELMUT DR , SCHEFCZIK ERNST DR , GRUETTNER SABINE DR , DEGEN HELMUT
Abstract: Thiophene azo dyes I … … where the substituents have the following meanings:… R = cyano or C1-C4-alkoxycarbonyl; R = halogen; C1-C6 alkyl whose carbon chain may be interrupted by one or two oxygen atoms in ether function; C1-C6-alkoxy or C1-C6-alkylthio which may each carry phenyl as substituent; phenylthio or phenylsulphonyl which may each carry halogen, C1-C4-alkyl or C1-C4-alkoxy as substituents; R = cyano; C1-C4-alkanoyl, benzoyl, C1-C4-alkylsulphonyl or phenylsulphonyl; R = hydrogen; cyano; C1-C4-alkoxy which may carry hydroxyl or C1-C4-alkoxy as substituents; C1-C4-alkoxycarbonyl, aminocarbonyl, mono- or di- C1-C4-alkylaminocarbonyl; R = hydrogen; C1-C4-alkyl or C1-C4-alkoxy which may each carry hydroxyl, C1-C4-alkoxy or C1-C4-alkanoyloxy as substituents; C1-C4-alkanoyloxy which may carry hydroxyl, chlorine, cyano, C1-C4-alkoxy or phenoxy as substituents; C1-C6-alkanoylamino which may carry hydroxyl, chlorine, cyano, C1-C4-alkoxy, phenoxy or C1-C4-alkanoyloxy as substituents; benzoylamino which may carry chlorine, cyano, nitro, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkoxycarbonyl or C1-C4-alkylsulphonyl as substituents; C1-C4-alkoxycarbonylamino or di-C1-C4-alkylaminocarbonyloxy whose alkyl groups may be bonded together to form a 6- or 7-membered ring containing the nitrogen atom of the amino group; R = hydrogen; C1-C10-alkyl whose carbon chain may be interrupted by one to three oxygen atoms in ether function and which may carry hydroxyl, halogen, cyano, C1-C4-alkanoyloxy or C1-C4-alkoxycarbonyl as substituents; C3-C5-alkenyl which may carry hydroxyl, halogen, C1-C4-alkoxy or C1-C4-alkanoyloxy as substituents; R = hydrogen; halogen; cyano; one of the alkyl groups R of the type defined; C1-C4-alkoxy; amino or mono- or di-C1-C4-alkylamino; R = one of the radicals R . … The thiophene azo dyes I are chiefly used as disperse dyes for dyeing textile material, in particular polyesters.
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公开(公告)号:DE4001237A1
公开(公告)日:1991-07-25
申请号:DE4001237
申请日:1990-01-18
Applicant: BASF AG
Inventor: KSOLL PETER DR , HAHN ERWIN DR , WITTMER PETER , HOHMANN ANDREAS DR , DE CLERCQ ARNOLD DR , RIEBELING ULRICH
IPC: C09K23/00 , B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:DE3917601A1
公开(公告)日:1990-12-06
申请号:DE3917601
申请日:1989-05-31
Applicant: BASF AG
Inventor: HAHN ERWIN DR , BREITSCHAFT WALTER DR , MAYER UDO DR , SCHROEDER GUNTER-RUDOLF DR
IPC: C07D295/18 , C07D295/185 , C09B11/00 , C09B11/10 , C09B11/12 , C09B11/16 , C09B11/18 , D06P1/42 , D21H21/28
Abstract: Triphenylmethane dyes of the formula +TR where each R1 is independently of the others hydrogen or substituted or unsubstituted C1-C6-alkyl, or two R1 radicals together with the nitrogen atom joining them form a heterocyclic radical, R2 and R5 is independently of the others hydrogen or C1-C4-alkyl, R3 and R4 is independently of the others hydrogen, C1-C4-alkyl, C1-C4-alkoxy or halogen, An(-) is one equivalent of an anion, and n is 1 or 2, preparable from piperazine derivatives as intermediates, are useful for coloring paper.
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公开(公告)号:DE3911949A1
公开(公告)日:1990-10-18
申请号:DE3911949
申请日:1989-04-12
Applicant: BASF AG
Inventor: HAHN ERWIN DR , HANSEN GUENTER DR , ETZBACH KARL-HEINZ DR , REICHELT HELMUT DR , SCHEFCZIK ERNST DR , DEGEN HELMUT , KRALLMANN REINHOLD , WAGENBLAST GERHARD DR
IPC: C09B29/033 , C09B67/22
Abstract: Navy blue and black dyestuff mixtures, containing one or more thiopheneazo dyestuffs whose diazo component is derived from the 2-aminothiophene series and whose coupling component is derived from the aniline series, and one or more dyestuffs F whose absorption maximum is at a wavelength of 390 to 520 nm, where the amount of the thiopheneazo dyestuffs is 60 to 99% by weight, relative to the total weight of the thiopheneazo dyestuffs and the dyestuffs F in the mixture.
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