公开(公告)号：EP1036055A2

公开(公告)日：2000-09-20

申请号：EP98963492.8

申请日：1998-11-21

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： WEYER, Hans-Jürgen ,  STAMM, Armin ,  WEBER, Theodor ,  HENKELMANN, Jochem

IPC: C07C51/00

CPC classification number: C07C51/58 ,  C07C53/50

Abstract: The invention relates to a method for producing chlorocarboxylic acid chlorides of formula (I) R1-CHCl-Y-COCl, wherein R1 represents hydrogen or C¿1? to C20 alkyl for example and Y represents a saturated or a mono- or poly-olefinically unsaturated C2-C8 alkene chain for example, by reacting lactones with a chlorination agent in the presence of a urea compound.

公开(公告)号：EP0973708A1

公开(公告)日：2000-01-26

申请号：EP98910701.6

申请日：1998-02-18

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： HENNINGSEN, Michael ,  STAMM, Armin ,  FISCHER, Martin ,  SIEGEL, Wolfgang

IPC: C07C17/18 ,  C07C22/00 ,  C07C1/30 ,  C07C13/04 ,  C07F9/535

CPC classification number: C07F9/535 ,  C07C1/30 ,  C07C17/00 ,  C07C17/18 ,  C07C2601/02 ,  C07C13/04 ,  C07C22/00

Abstract: The invention concerns a process for halogenating cyclopropylmethyl ketone with at least one dihalogen triorganophosphorane of the general formula (I): R3PHal2, in which the R groups can be the same or different and designate a saturated or unsaturated aliphatic C1-C20 hydrocarbon group, a phenyl or C1-C4 alkylphenyl group which can optionally be further substituted by one to two fluorine, chlorine and/or nitro groups, P means phosphorus and Hal means chlorine, bromine or iodine, at 80 to 130 °C, the dihalogen triorganophosphorane of the general formula (I) being prepared in situ from triorganophosphane oxide or triorganophosphane sulphide of the general formula (II), R3PA, in which R has the meaning given under formula (I) and A stands for oxygen or sulphur, with a halogenation reagent. The process is characterized in that the triorganophosphane oxide or triorganophosphane sulphide is used in catalytic amounts. The invention also concerns the halogenation product of the cyclopropyl ketone obtained according to this process and a process for reacting it to form cyclopropylacetylene.

Abstract translation: 本发明涉及一种用至少一种通式Iin的二卤代三有机基磷烷卤化环丙基甲基酮的方法，其中基团R可以相同或不同，表示饱和或不饱和的脂族C 1 -C 20烃基，苯基或 （C 1 -C 4烷基）苯基，其可任选被一个或两个氟，氯和/或硝基取代，P代表磷，Hal代表氯，溴或碘，温度为800°至130° ℃，其中通式（I）的二卤代三有机膦原位由通式IIin的三有机膦氧化物或三有机膦烷硫化物原位合成，其中R如上文关于式I所定义，A表示氧或硫，使用 一种卤化剂，其中三有机膦氧化物或三有机基硫化物以催化量使用于在所述方法中得到的环丙基甲基酮的卤化产物，t o将所述卤化产物转化为环丙基乙烯基的方法。

公开(公告)号：EP1259473B1

公开(公告)日：2005-10-26

申请号：EP01919355.6

申请日：2001-02-28

Applicant: BASF Aktiengesellschaft

Inventor： STAMM, Armin ,  KNEUPER, Heinz-Josef ,  HENKELMANN, Jochem ,  WEBER, Theodor ,  BUSCH, Ralph

IPC: C07C51/60 ,  C07C53/50

CPC classification number: C07C51/60 ,  C07C53/50

Abstract: The invention relates to a method for producing chlorocarboxylic acid chlorides of formula (I), wherein R?1 and R2¿, independently from one another, mean a hydrogen atom, an organic radical containing carbon, a halogen, a nitro or cyano group and Y means an alkylene chain having 1 to 10 carbon atoms in the chain which is unsubstituted or is substituted by organic radicals that contain carbon, by halogen, nitro and/or cyano groups, whereby the alkylene chain can be interrupted by an ether-, thioether-, tertiary amino- or keto group, whereby the organic radicals of Y and/or R1 and/or R2 can be connected to one another and thereby form a non-aromatic system, whereby said radicals contain carbon, by converting a lactone of formula (II), wherein R1, R2 and Y have the aforementioned meanings, using a hydrogen chloride and phosgene in the presence of a catalyst. Hydrogen chloride is added before and/or while phosgene is added. The hydrogen chloride is only introduced at a temperature of at least 60 °C. A pyridine compound is used as the catalyst.

公开(公告)号：EP1212281B1

公开(公告)日：2004-08-11

申请号：EP00960571.8

申请日：2000-08-31

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： BUSCH, Ralph ,  KNEUPER, Heinz-Josef ,  WEBER, Theodor ,  MÜLLER, Winfried ,  STAMM, Armin ,  HENKELMANN, Jochem

IPC: C07C51/60 ,  C07C51/64

CPC classification number: C07C51/64 ,  C07C51/60

Abstract: The invention relates to a method for producing acid chlorides by converting carboxylic acids with carbon oxychlorides or thionyl chloride in the presence of a catalyst adduct of an N,N-disubstituted formamide of general formula (I) and carbon oxychloride or thionyl chloride. In the formula, R and R , independently from one another, mean C1- to C4-alkyl or R and R together mean a C4- or C5-alkylene chain. According to the inventive method, hydrogen chloride is added during and/or after the conversion.

公开(公告)号：EP1440056A1

公开(公告)日：2004-07-28

申请号：EP02785232.6

申请日：2002-10-17

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： ROHDE, Thorsten ,  STAMM, Armin ,  HENKELMANN, Jochem

IPC: C07C263/10

CPC classification number: C07C263/10 ,  C07C2601/14 ,  C07C265/14 ,  C07C265/08 ,  C07C265/10 ,  C07C265/12

Abstract: The invention relates to a method for producing isocyanates by reacting the corresponding primary amines with phosgene in an inert solvent, while using 0.01 to 50 mole percent of a sulfoxide, a sulfone or mixtures thereof, based on the total quantity of the primary amine and isocyanate produced in the reaction solution.

Abstract translation: 本发明涉及一种通过相应的伯胺与光气在惰性溶剂中反应制备异氰酸酯的方法，同时使用基于伯胺和异氰酸酯总量的0.01至50摩尔百分比的亚砜，砜或其混合物 在反应溶液中产生。

公开(公告)号：EP1265837B1

公开(公告)日：2004-06-09

申请号：EP00977582.6

申请日：2000-11-27

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： GÖTZ, Roland ,  GÖTZ, Norbert ,  KEIL, Michael ,  WOLF, Bernd ,  STEINMETZ, Adrian ,  STAMM, Armin ,  HENKELMANN, Jochem

IPC: C07C51/60 ,  C07C63/10

CPC classification number: C07C51/60 ,  C07C63/10

Abstract: The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R1 to R4 can be the same or different and represent hydrogen C¿1?-C4 alkyl, halogen or trifluoromethyl, by reacting benzo-condensed lactones of formula (II), in which R?1 to R4¿ have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.

公开(公告)号：EP1208082B1

公开(公告)日：2004-04-07

申请号：EP00951530.5

申请日：2000-08-23

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： STAMM, Armin ,  KNEUPER, Heinz-Josef ,  THIL, Lucien ,  HENKELMANN, Jochem

IPC: C07C263/10

CPC classification number: C07C263/10 ,  C07C2601/14 ,  C07C265/08 ,  C07C265/10 ,  C07C265/12

公开(公告)号：EP1087945B1

公开(公告)日：2003-10-08

申请号：EP99964476.8

申请日：1999-06-14

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： STAMM, Armin ,  HENKELMANN, Jochem

IPC: C07D233/60

CPC classification number: C07D231/12 ,  C07D233/56 ,  C07D249/08

Abstract: A method for producing carbonyldiimidazole from imidazole and phosgene in an inert solvent, wherein the coupled imidazole-hydrochloride product is separated from the obtained reaction mixture in the form of a melt by means of phase separation.

公开(公告)号：EP1259472A1

公开(公告)日：2002-11-27

申请号：EP01909800.3

申请日：2001-02-28

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： STAMM, Armin ,  GÖTZ, Roland ,  HENKELMANN, Jochem ,  CLOSS, Friedrich ,  KNEUPER, Heinz-Josef

IPC: C07C51/60 ,  C07C53/50

CPC classification number: C07C51/60 ,  C07C53/50

Abstract: The invention relates to a method for producing chlorocarboxylic acid chlorides of formula (I), wherein R?1 and R2¿, independently from one another, mean a hydrogen atom, an organic radical containing carbon, a halogen, a nitro or cyano group and Y means an alkylene chain having 1 to 10 carbon atoms in the chain which is unsubstituted or is substituted by organic radicals that contain carbon, by halogen, nitro and/or cyano groups, whereby the alkylene chain can be interrupted by an ether-, thioether-, tertiary amino- or keto group, whereby the organic radicals of Y and/or R1 and/or R2 can be connected to one another and thereby form a non-aromatic system, whereby said radicals contain carbon, by converting a lactone of formula (II), wherein R1, R2 and Y have the aforementioned meanings, using a chlorination means in the presence of a chlorination catalyst and in the presence of a boron compound.

Abstract translation: 本发明涉及制备式（I）的氯代羧酸氯化物的方法，其中R 1和R 2彼此独立地表示氢原子，含碳的有机基团，卤素，硝基或氰基，和 Y表示在未被取代或被含有碳的有机基团取代的链中具有1至10个碳原子的亚烷基链，其通过卤素，硝基和/或氰基基团取代，其中亚烷基链可被醚 - ，硫醚 - 叔氨基或酮基，其中Y和/或R 1和/或R 2的有机基团可以彼此连接并由此形成非芳族体系，由此所述基团含有碳，通过将式 （II）化合物，其中R1，R2和Y具有上述含义，使用氯化方法在氯化催化剂存在下和在硼化合物存在下进行。

公开(公告)号：EP1212273A2

公开(公告)日：2002-06-12

申请号：EP00972657.1

申请日：2000-08-31

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： BUSCH, Ralph ,  KNEUPER, Heinz-Josef ,  WEBER, Theodor ,  MÜLLER, Winfried ,  STAMM, Armin ,  HENKELMANN, Jochem

IPC: C07C51/00

CPC classification number: C07C51/64 ,  C07C53/42

Abstract: The invention relates to a method for purifying acid chlorides which have been produced by converting carboxylic acids with carbon oxychloride or thionyl chloride in the presence of a catalyst adduct. The acid chlorides are treated with a hydro halide of carboxylic acid amides of general formula (I), wherein R1 stands for hydrogen or C¿1?- to C3-alkyl; R?2 and R3¿, independently from one another, mean C¿1?- to C4-alkyl or R?2 and R3¿ together mean a C¿4?- or C5-alkylene chain. The thus purified acid chloride is isolated by separation said acid chloride from the carboxylic acid amide hydro halide-phase.