ACCELERATED REDUCTION OF ORGANIC SUBSTANCES WITH BORANES

    公开(公告)号:CA2700067A1

    公开(公告)日:2009-03-26

    申请号:CA2700067

    申请日:2008-09-18

    Applicant: BASF SE

    Abstract: In a process for the accelerated reduction of organic substrates, selected from the group consisting of ester, amides, nitriles, acids, ketones, imines or mixtures thereof, the substrates are reacted with an amine borane, sulfide borane or ether borane complex as a borane source in the presence of organic accelerator compounds containing both Lewis acidic and Lewis basic sites in their structure, of which the Lewis acidic site can coordinate with the carbonyl or nitrile or imine group of the substrate and the Lewis basic site can coordinate with the borane.

    Pyridine borane complexes
    23.
    发明专利

    公开(公告)号:AU2007298924A1

    公开(公告)日:2008-03-27

    申请号:AU2007298924

    申请日:2007-09-20

    Applicant: BASF SE

    Abstract: The present invention relates to new borane complexes with substituted pyridines, a process for the synthesis of new borane complexes with substituted pyridines, solutions comprising new borane complexes with substituted pyridines and a method of using new borane complexes with substituted pyridines for organic reactions.

    Process for synthesis of dialkoxyorganoboranes

    公开(公告)号:AU2011202304A1

    公开(公告)日:2012-12-06

    申请号:AU2011202304

    申请日:2011-05-18

    Applicant: BASF SE

    Abstract: Process for synthesis of dial koxyorga noboranes Abstract 5 The invention relates to a process for the synthesis of dialkoxyorganoboranes, in par ticular to a process for the synthesis of dialkoxyorganoboranes by an ester exchange reaction. Moreover, the invention relates to a process for the synthesis of organo oxazaborolidine catalysts (organo-CBS) and of trialkylboroxins. Furthermore, the inven tion relates to methods of using dialkoxyorganoboranes for the preparation of organo 10 CBS catalysts and in Suzuki-type coupling reactions.

    PROCESS TO PURIFY DIALKYL SULFIDES
    29.
    发明专利

    公开(公告)号:CA2730707A1

    公开(公告)日:2010-01-21

    申请号:CA2730707

    申请日:2009-07-10

    Applicant: BASF SE

    Abstract: The invention relates to new processes to prepare low odor dialkyl sulfides, the low odor dialkyl sulfides obtainable by these processes and to methods of using these low odor dialkyl sulfides. Moreover, the invention relates to a process to prepare dialkyl sulfide borane complexes of high purity, the dialkyl sulfide borane complexes obtainable by this process and to a process for enantioselective reductions employing these dialkyl sulfide borane complexes of high purity as reducing agent.

    PYRIDINE BORANE COMPLEXES
    30.
    发明专利

    公开(公告)号:CA2663677A1

    公开(公告)日:2008-03-27

    申请号:CA2663677

    申请日:2007-09-20

    Applicant: BASF SE

    Abstract: The present invention relates to new borane complexes with substituted py ridines, a process for the synthesis of new borane complexes with substitute d pyridines, solutions comprising new borane complexes with substituted pyri dines and a method of using new borane complexes with substituted pyridines for organic reactions.

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