ACCELERATED REDUCTION OF ORGANIC SUBSTANCES WITH BORANES
    1.
    发明申请
    ACCELERATED REDUCTION OF ORGANIC SUBSTANCES WITH BORANES 审中-公开
    加速减少有机物质与波兰

    公开(公告)号:WO2009037307A2

    公开(公告)日:2009-03-26

    申请号:PCT/EP2008062432

    申请日:2008-09-18

    Abstract: In a process for the accelerated reduction of organic substrates, selected from the group consisting of ester, amides, nitriles, acids, ketones, imines or mixtures thereof, the substrates are reacted with an amine borane, sulfide borane or ether borane complex as a borane source in the presence of organic accelerator compounds containing both Lewis acidic and Lewis basic sites in their structure, of which the Lewis acidic site can coordinate with the carbonyl or nitrile or imine group of the substrate and the Lewis basic site can coordinate with the borane.

    Abstract translation: 在加速还原有机底物的方法中,选自酯,酰胺,腈,酸,酮,亚胺或其混合物,底物与胺硼烷,硫化硼烷或醚硼烷络合物作为硼烷反应 来源于其结构中含有路易斯酸性和路易斯碱性位点的有机促进剂化合物,其中路易斯酸性位点可与底物的羰基或腈或亚胺基团配位,路易斯碱性位点可与硼烷配位。

    ACCELERATED REDUCTION OF ORGANIC SUBSTANCES WITH BORANES

    公开(公告)号:SG184773A1

    公开(公告)日:2012-10-30

    申请号:SG2012070173

    申请日:2008-09-18

    Applicant: BASF SE

    Abstract: 24 Abstract ACCELERATED REDUCTION OF ORGANIC SUBSTANCES WITH BORANESIn a process for the accelerated reduction of organic substrates, selected from the group consisting of ester, amides, nitriles, acids, ketones, imines or mixtures thereof, the substrates are reacted with an amine borane, sulfide borane or ether borane complex as a borane source in the presence of organic accelerator compounds containing both Lewis acidic and Lewis basic sites in their structure, of which the Lewis acidic site can coordinate with the carbonyl or nitrile or imine group of the substrate and the Lewis basic site can coordinate with the borane.No suitable figure

    COMPLEJOS DE PIRIDINA BORADO.
    4.
    发明专利

    公开(公告)号:ES2362311T3

    公开(公告)日:2011-07-01

    申请号:ES07820436

    申请日:2007-09-20

    Applicant: BASF SE

    Abstract: Complejos boránicos de fórmula (1) **Fórmula** en donde R1 y R2 representan independientemente entre sí alquilo C1-C8, alcoxi C1-C8, alcoxi(C1-C8)-alquilo(C1-C8) o halógeno, con la condición de que R1 y R2 no sean al mismo tiempo metilo cuando R2 está en la posición 4 o 6 del anillo de piridina.

    7.
    发明专利
    未知

    公开(公告)号:AT478080T

    公开(公告)日:2010-09-15

    申请号:AT07765528

    申请日:2007-06-26

    Applicant: BASF SE

    Abstract: The present invention relates to a borane ether complex of the formula 1, wherein R1 to R4 represent independently from each other hydrogen, C1-C4-alkyl, C3-C6-cycloalkyl or a substituent of the formula CH2OR5, wherein R5 is C1-C4-alkyl or C3-C6-cycloalkyl, or two adjacent substituents R1 to R4 together are a divalent group selected from the group consisting of -CH2CH2-, -CH(CH3)CH2-, -CH2CH2CH2-, -CH(CH3)CH(CH3)-, -CH(CH2CH3)CH2-, -C(CH3)2C(CH3)2-, -CH2C(CH3)2CH2- and -(CH2)6- to form with the -CH-CH- moiety of the tetrahydrofuran ring a cyclic structure, with the provision that at least one of the substituents R1 to R4 is not hydrogen. The invention also relates to a method of using new borane complexes with substituted tetrahydrofuran ethers for organic reactions.

    PROCEDIMIENTO PARA LA SINTESIS DE DIALCOXIORGANOBORANOS.

    公开(公告)号:ES2329171T3

    公开(公告)日:2009-11-23

    申请号:ES06763613

    申请日:2006-06-09

    Applicant: BASF SE

    Abstract: Un procedimiento para la preparación de dialcoxiorganoboranos (3) de la fórmula R 1 -B(OR 2 ) 2, que comprende la etapa de hacer reaccionar una triorganoboroxina (1) de la fórmula (R 1 -BO)3 y un trialquilborato (2) de la fórmula B (OR 2 )3, en las que R 1 es alquilo C1-C20, cicloalquilo C3-C10, arilo C6-C14, aralquilo C7-C24, alcarilo C7-C24, alquenilo C2-C20, cicloalquenilo C5-C15, alquinilo C2-C20, CH2SiMe3, alquilo C1-C20 sustituido y R 2 es alquilo C1-C20, o dos grupos R 2 en los compuestos (2) o (3) junto con el resto -BO 2- forman una estructura cíclica de la fórmula con el grupo divalente R 3 seleccionado del grupo que consiste en -CH 2CH 2-, -CH(CH 3)CH 2-, -CH 2CH 2CH 2-, -CH (CH 3)CH(CH 3)-, -CH(CH 2CH 3)CH 2-, -C(CH 3) 2C(CH 3) 2-, -CH 2C(CH 3) 2CH 2-, -(CH 2) 6-, orto-C 6H 4 u orto-C 6H 3-alquilo.

    Borane ether complexes
    9.
    发明专利

    公开(公告)号:AU2007263842A1

    公开(公告)日:2008-01-03

    申请号:AU2007263842

    申请日:2007-06-26

    Applicant: BASF SE

    Abstract: The present invention relates to a borane ether complex of the formula 1, wherein R1 to R4 represent independently from each other hydrogen, C1-C4-alkyl, C3-C6-cycloalkyl or a substituent of the formula CH2OR5, wherein R5 is C1-C4-alkyl or C3-C6-cycloalkyl, or two adjacent substituents R1 to R4 together are a divalent group selected from the group consisting of -CH2CH2-, -CH(CH3)CH2-, -CH2CH2CH2-, -CH(CH3)CH(CH3)-, -CH(CH2CH3)CH2-, -C(CH3)2C(CH3)2-, -CH2C(CH3)2CH2- and -(CH2)6- to form with the -CH-CH- moiety of the tetrahydrofuran ring a cyclic structure, with the provision that at least one of the substituents R1 to R4 is not hydrogen. The invention also relates to a method of using new borane complexes with substituted tetrahydrofuran ethers for organic reactions.

    PURIFICATION OF DIALKYL SULFIDES WITH BASIC METAL ALCOHOLATES AND/OR ALKALI OR ALKALINE EARTH METALS

    公开(公告)号:CA2730707C

    公开(公告)日:2016-09-13

    申请号:CA2730707

    申请日:2009-07-10

    Applicant: BASF SE

    Abstract: The invention relates to new processes to prepare low odor dialkyl sulfides, the low odor dialkyl sulfides obtainable by these processes and to methods of using these low odor dialkyl sulfides. Moreover, the invention relates to a process to prepare dialkyl sulfide borane complexes of high purity, the dialkyl sulfide borane complexes obtainable by this process and to a process for enantioselective reductions employing these dialkyl sulfide borane complexes of high purity as reducing agent. The process comprises bringing a dialkyl sulfide into contact with a base, and/or at least one alkali or alkaline earth metal. The base may be a metal alcoholate a metal oxide, a metal or alkylammonium hydroxide, a metal or alkylammonium carbonate, a metal enolate, a metal amide or a metal hydride. The process may contain a step of reacting the product with an electrophile and a further step of distilling out the dialkyl sulfide.

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