公开(公告)号：DE112005000193A5

公开(公告)日：2008-06-19

申请号：DE112005000193

申请日：2005-02-19

Applicant: BASF SE

Inventor： KLASS KATRIN ,  HAHN THILO ,  HENKELMANN JOCHEM

IPC: C07C29/42 ,  C07C29/17 ,  C07C29/38 ,  C07C29/56 ,  C07C33/042

Abstract: Process for preparing a propargyl alcohol of the formula I in which R 1 is a C 130 -alkyl, C 3-8 -cycloalkyl, C 2-20 -alkoxyalkyl, C 6-14 -aryl, C 7-20 -alkoxyarl, C 7-20 -aralkyl, C 7-20 -alkylaryl radical or H, by reacting a corresponding aldehyde of the formula R 1 -CHO with acetylene in the presence of ammonia and a catalytic amount of an alkali metal hydroxide, alkaline earth metal hydroxide or alkali metal alkoxide in the range from 0.6 to 10 mol % based on the aldehyde used, and also processes for preparing an allyl alcohol of the formulae II and III starting from the propargyl alcohol I prepared in accordance with the invention.