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公开(公告)号：BR0113545A
公开(公告)日：2003-07-15
申请号：BR0113545
申请日：2001-08-02
Inventor： SCHUETTE RUEDIGER , BALDUF TORSTEN , BECKER CATRIN , HEMME INA , BERTSCH-FRANK BIRGIT , WILDNER WERNER , ROLLMANN JUERGEN , MARKOWZ GEORG
IPC: B01F5/00 , B01F5/04 , B01F13/00 , B01J3/04 , B01J8/00 , B01J8/02 , B01J19/00 , B01J19/24 , C01B15/029 , C07B61/00 , C07C45/35 , C07C47/21 , C07C47/22 , C07C51/25 , C07C57/04 , C07C57/05 , C07D301/12 , C07D303/04 , F28D9/00 , F28F3/12
Abstract: Two reactants are introduced into a slot-shaped reaction space (3) of a reactor. The space is formed between lateral surfaces (2) of two equally large and right parallelepipedal wall elements (1) comprising solid plates. The reactants are introduced from the edge of the slot-shaped reaction spaces situated on the same side of the block. Two reactants are introduced into a slot-shaped reaction space of a reactor. The spaces are formed between lateral surfaces of two equally large and right parallelepipedal wall elements comprising solid plates. The wall elements are arranged interchangeably in a block within the virtual parallelepiped. The reactants are introduced from edge regions of the slot-shaped reaction spaces situated on the same side of the block. The reactants are conducted as a reaction mixture through the reaction spaces in the same direction in parallel flows. A fluid heat exchange medium is conducted through tubular cavities (5) extending in the interior of the wall elements to obtain the desired reaction. An independent claim is also included for apparatus comprising the reactor in which the slot-shaped reaction spaces are capable of having the reactants supplied from the same side of the block. The reaction spaces are oriented to guide the reaction mixture in the same direction in parallel flows.
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公开(公告)号：TR200002858T2
公开(公告)日：2000-12-21
申请号：TR200002858
申请日：1999-03-31
Applicant: DEGUSSA
Inventor： BERTSCH-FRANK BIRGIT , BALDUF TORSTEN , BECKER-BALFANZ CATRIN , HEMME INA , ROLLMANN JURGEN , SCHUTTE RUDIGER , WILDNER WERNER
IPC: B01J8/02 , C01B15/029
Abstract: An aqueous solution of hydrogen peroxide is produced by direct synthesis from hydrogen and oxygen in the presence of a heterogeneous catalyst. According to the invention, a gas mixture comprising H2 and O2, essentially saturated or supersaturated with water (=containing fog) is fed into a reactor containing the catalyst. The volume ratio of the gas mixture fed in (standard liters per hour) to liquid removed (liters per hour) is adjusted to a value equal to or greater than 15,000, especially 20,000 to 50,000, and the gas mixture leaving the reactor is recycled after replenishment with H2, O2, and H2O vapor. Solutions with high H2O2 concentration can be obtained according to the invention without additional concentration.
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公开(公告)号：AU3706799A
公开(公告)日：1999-11-01
申请号：AU3706799
申请日：1999-03-31
Applicant: DEGUSSA
Inventor： BERTSCH-FRANK BIRGIT , BALDUF TORSTEN , BECKER-BALFANZ CATRIN , HEMME INA , ROLLMANN JURGEN , SCHUTTE RUDIGER , WILDNER WERNER
IPC: B01J8/02 , C01B15/029
Abstract: An aqueous solution of hydrogen peroxide is produced by direct synthesis from hydrogen and oxygen in the presence of a heterogeneous catalyst. According to the invention, a gas mixture comprising H2 and O2, essentially saturated or supersaturated with water (=containing fog) is fed into a reactor containing the catalyst. The volume ratio of the gas mixture fed in (standard liters per hour) to liquid removed (liters per hour) is adjusted to a value equal to or greater than 15,000, especially 20,000 to 50,000, and the gas mixture leaving the reactor is recycled after replenishment with H2, O2, and H2O vapor. Solutions with high H2O2 concentration can be obtained according to the invention without additional concentration.
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公开(公告)号：PL173925B1
公开(公告)日：1998-05-29
申请号：PL31103594
申请日：1994-02-28
Applicant: DEGUSSA
Inventor： BERTSCH-FRANK BIRGIT , KLASEN CLAAS-JUERGEN , LIESER THOMAS , MUELLER KLAUS , BEWERSDORF MARTIN
Abstract: PCT No. PCT/EP94/00576 Sec. 371 Date Oct. 2, 1995 Sec. 102(e) Date Oct. 2, 1995 PCT Filed Feb. 28, 1994 PCT Pub. No. WO94/24044 PCT Pub. Date Oct. 27, 1994Sodium percarbonate is often used in the form of coated particles to increase its storage stability in detergents. Sodium percarbonate particles coated in accordance with the invention have a coating containing reaction products from the reaction of a dialkali metal tetraborate or alkali metal pentaborate with aqueous hydrogen peroxide. Preferred coating components are: perborax with the formula Na2B4O7xH2O2, where n =2 or 4. The coated sodium percarbonate particles are produced by coating the percarbonate particles using a solution containing the reaction products mentioned above. Detergent, bleaching and cleaning compositions containing sodium percarbonate particles coated in accordance with the invention are distinguished by very high stability in storage.
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公开(公告)号：ES2113102T3
公开(公告)日：1998-04-16
申请号：ES94915106
申请日：1994-04-23
Applicant: DEGUSSA
Inventor： BERTSCH-FRANK BIRGIT , BEWERSDORF MARTIN , KLASEN CLAAS-JURGEN , LIESER THOMAS , MULLER KLAUS , ROLLMANN JURGEN
Abstract: In the prior art, sodium percarbonate is coated with compounds which produce a stabilizing action in order to increase the shelf life. There is a need for an improved, boron-free, coating for sodium percarbonate. Proposed by the invention is a particle coating containing sodium carbonate plus one or more optionally partly hydrated magnesium compounds, preferably magnesium sulphate, in a single coat or in separate coats. The coating preferably contains two coats. The particles are produced by spraying aqueous solutions containing the coating compounds on to sodium percarbonate in a fluidized bed and at the same time evaporating off the water. Their long shelf life makes particles coated in this way suitable for use in washing, bleaching and cleaning agents.
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Patent Agency Ranking
公开(公告)号：DE59405122D1
公开(公告)日：1998-02-26
申请号：DE59405122
申请日：1994-04-23
Applicant: DEGUSSA
Inventor： BERTSCH-FRANK BIRGIT , BEWERSDORF MARTIN , KLASEN CLAAS-JUERGEN , LIESER THOMAS , MUELLER KLAUS , ROLLMANN JUERGEN
Abstract: In the prior art, sodium percarbonate is coated with compounds which produce a stabilizing action in order to increase the shelf life. There is a need for an improved, boron-free, coating for sodium percarbonate. Proposed by the invention is a particle coating containing sodium carbonate plus one or more optionally partly hydrated magnesium compounds, preferably magnesium sulphate, in a single coat or in separate coats. The coating preferably contains two coats. The particles are produced by spraying aqueous solutions containing the coating compounds on to sodium percarbonate in a fluidized bed and at the same time evaporating off the water. Their long shelf life makes particles coated in this way suitable for use in washing, bleaching and cleaning agents.
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公开(公告)号：AT156096T
公开(公告)日：1997-08-15
申请号：AT94909085
申请日：1994-02-28
Applicant: DEGUSSA
Inventor： BERTSCH-FRANK BIRGIT , KLASEN CLAAS-JUERGEN , LIESER THOMAS , MUELLER KLAUS , BEWERSDORF MARTIN
Abstract: PCT No. PCT/EP94/00576 Sec. 371 Date Oct. 2, 1995 Sec. 102(e) Date Oct. 2, 1995 PCT Filed Feb. 28, 1994 PCT Pub. No. WO94/24044 PCT Pub. Date Oct. 27, 1994Sodium percarbonate is often used in the form of coated particles to increase its storage stability in detergents. Sodium percarbonate particles coated in accordance with the invention have a coating containing reaction products from the reaction of a dialkali metal tetraborate or alkali metal pentaborate with aqueous hydrogen peroxide. Preferred coating components are: perborax with the formula Na2B4O7xH2O2, where n =2 or 4. The coated sodium percarbonate particles are produced by coating the percarbonate particles using a solution containing the reaction products mentioned above. Detergent, bleaching and cleaning compositions containing sodium percarbonate particles coated in accordance with the invention are distinguished by very high stability in storage.
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28.发明专利
公开(公告)号：PL312608A1
公开(公告)日：1996-04-29
申请号：PL31260894
申请日：1994-04-23
Applicant: DEGUSSA
Inventor： BERTSCH-FRANK BIRGIT , BEWERSDORF MARTIN , KLASEN CLAAS-JUERGEN , LIESER THOMAS , MUELLER KLAUS , ROLLMANN JUERGEN
Abstract: In the prior art, sodium percarbonate is coated with compounds which produce a stabilizing action in order to increase the shelf life. There is a need for an improved, boron-free, coating for sodium percarbonate. Proposed by the invention is a particle coating containing sodium carbonate plus one or more optionally partly hydrated magnesium compounds, preferably magnesium sulphate, in a single coat or in separate coats. The coating preferably contains two coats. The particles are produced by spraying aqueous solutions containing the coating compounds on to sodium percarbonate in a fluidized bed and at the same time evaporating off the water. Their long shelf life makes particles coated in this way suitable for use in washing, bleaching and cleaning agents.
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公开(公告)号：HU9600079D0
公开(公告)日：1996-03-28
申请号：HU9600079
申请日：1994-04-23
Applicant: DEGUSSA
Inventor： BERTSCH-FRANK BIRGIT , BEWERSDORF MARTIN , KLASEN CLAAS-JUERGEN , LEISER THOMAS , MUELLER KLAUS , ROLLMANN JUERGEN
Abstract: In the prior art, sodium percarbonate is coated with compounds which produce a stabilizing action in order to increase the shelf life. There is a need for an improved, boron-free, coating for sodium percarbonate. Proposed by the invention is a particle coating containing sodium carbonate plus one or more optionally partly hydrated magnesium compounds, preferably magnesium sulphate, in a single coat or in separate coats. The coating preferably contains two coats. The particles are produced by spraying aqueous solutions containing the coating compounds on to sodium percarbonate in a fluidized bed and at the same time evaporating off the water. Their long shelf life makes particles coated in this way suitable for use in washing, bleaching and cleaning agents.
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公开(公告)号：FI954808A0
公开(公告)日：1995-10-09
申请号：FI954808
申请日：1995-10-09
Applicant: DEGUSSA
Inventor： BERTSCH-FRANK BIRGIT , KLASEN CLAAS-JUERGEN , LIESER THOMAS , MUELLER KLAUS , BEWERSDORF MARTIN
Abstract: PCT No. PCT/EP94/00576 Sec. 371 Date Oct. 2, 1995 Sec. 102(e) Date Oct. 2, 1995 PCT Filed Feb. 28, 1994 PCT Pub. No. WO94/24044 PCT Pub. Date Oct. 27, 1994Sodium percarbonate is often used in the form of coated particles to increase its storage stability in detergents. Sodium percarbonate particles coated in accordance with the invention have a coating containing reaction products from the reaction of a dialkali metal tetraborate or alkali metal pentaborate with aqueous hydrogen peroxide. Preferred coating components are: perborax with the formula Na2B4O7xH2O2, where n =2 or 4. The coated sodium percarbonate particles are produced by coating the percarbonate particles using a solution containing the reaction products mentioned above. Detergent, bleaching and cleaning compositions containing sodium percarbonate particles coated in accordance with the invention are distinguished by very high stability in storage.
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