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21.发明公开
公开(公告)号：EP1907181A1
公开(公告)日：2008-04-09
申请号：EP06749328.8
申请日：2006-03-30
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： HALE, Wesley, Raymond , PECORINI, Thomas, Joseph , STEWART, Mark, Edward , ROGERS, Martin, Emerson , GILLIAM, Spencer, Allen , CLIFFTON, Michael, Duane , CRAWFORD, Emmett, Dudley , PORTER, David, Scott , CONNELL, Gary, Wayne
CPC classification number: B32B27/34 , B29B17/0042 , B29B2911/14906 , B29K2067/00 , B32B27/08 , B32B27/18 , B32B27/36 , B32B2250/24 , B32B2264/105 , B32B2307/412 , B32B2307/716 , B32B2307/7244 , B32B2307/7246 , B32B2553/00 , C08G63/199 , C08L67/02 , C08L77/00 , C08L2205/02 , Y02W30/62 , C08L2666/20
Abstract: Disclosed are transparent, multilayered articles having high transparency and low haze and a process for their preparation. The multilayer articles comprise at least one layer which contains at least one polyester comprising 2,2,4,4- tetramethyl-1 ,3-cyclobutanediol and a separate layer which contains copolyamide or homogeneous blend of polyamides. The polyester component and the polyamide component have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
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22.发明公开POLYESTER BASED COBALT CONCENTRATES FOR OXYGEN SCAVENGING COMPOSITIONS 有权钴精矿聚酯基础SAUERSTOFFSPÜLENDE组合物
公开(公告)号：EP1824920A2
公开(公告)日：2007-08-29
申请号：EP05852745.8
申请日：2005-12-02
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： STEWART, Mark, Edward , SHARPE, Emerson, Eston, Jr. , GAMBLE, Benjamin, Bradford , STAFFORD, Steven, Lee , ESTEP, Robert, Noah , WILLIAMS, James, Carl , CLARK, Thomas, Roger
IPC: C08K5/09 , C08G63/60 , C08F283/04 , C08G69/48 , C08L67/02
CPC classification number: C08K5/098 , C08L67/02 , C08L77/00 , Y10T428/1352 , Y10T428/1383 , C08L2666/14
Abstract: A solid concentrate is provided having a combination of a transition metal present in an amount ranging from 1000 to 40,000 ppm (weight by metal) and a polyester polymer present in an amount of at least 40 wt.% based on the weight of the concentrate. Concentrates made with highly modified polyester polymers are easy to compound with transition metals forming less brittle polymer upon melt extrusion. Bottle preforms and oxygen scavenging bottles can be made from these concentrates by combining solid polyester particles, solid polyamide particles, and solid these concentrate particles c into an melt processing zone, forming a melt, and forming an article directly from the melt. The b* color and the L* color and the haze levels of the preforms are improved over the preforms made with liquid carriers instead of solid concentrates. The particles are also advantageously simultaneously dried in a drying zone under conditions effective to at least partially remove moisture from the blend to thereby further improve the b* color and L* color.
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公开(公告)号：EP1203051A1
公开(公告)日：2002-05-08
申请号：EP00952643.5
申请日：2000-08-08
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： BERNARD, Linda, Gail , CLAUBERG, Horst , CYR, Michael, John , GILMER, John, Walker , MATAYABAS, James, Christopher, Jr. , OWENS, Jeffrey, Todd , STEWART, Mark, Edward , TURNER, Sam, Richard , BAGRODIA, Shriram
CPC classification number: B82Y30/00 , C08J5/005 , C08J2377/00 , C08K3/34 , C08K7/00 , C08K2201/008 , C08L77/00
Abstract: The present invention relates to polymer-platelet particle composites comprising at least one polyamide resin, at least one oxygen scavenging system, and platelet particles derived from at least one layered silicate material.
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公开(公告)号：EP2125930A1
公开(公告)日：2009-12-02
申请号：EP07862728.8
申请日：2007-12-11
Applicant: EASTMAN CHEMICAL COMPANY
CPC classification number: C08G63/52 , C08L67/02 , C08L67/06 , C08L2666/18
Abstract: Oxygen-scavenging polyester compositions are disclosed that include residues of one or more unsaturated diols, for example, 2-butene-l,4-diol, and residues of one or more aliphatic dicarboxylic acids, for example adipic acid. The compositions may be used as concentrates, and may be blended, for example, with one or more polyethylene terephthalate homopolymers or copolymers, to obtain compositions suitable for use in packaging, providing oxygen-scavenging effect.
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25.发明授权TRANSPARENT, OXYGEN-SCAVENGING COMPOSITIONS AND ARTICLES PREPARED THEREFROM 有权由其制成的透明OXYGEN捕手组合物和制品
公开(公告)号：EP1869122B1
公开(公告)日：2009-11-18
申请号：EP06736793.8
申请日：2006-03-02
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： HALE, Wesley, Raymond , PECORINI, Thomas, Joseph , STEWART, Mark, Edward , ROGERS, Martin, Emerson c/o EASTMAN CHEMICAL COMPANY , GILLIAM, Spencer, Allen , CLIFFTON, Michael, Duane , SHELBY, Marcus David
IPC: C08L67/02
CPC classification number: C08L69/00 , B32B27/08 , B32B27/18 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2250/24 , B32B2264/105 , B32B2270/00 , B32B2307/412 , B32B2307/738 , B32B2307/74 , B32B2439/60 , C08K3/08 , C08L67/00 , C08L67/02 , C08L77/00 , C08L2205/02 , C08L2205/03 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/20 , C08L2666/14 , C08L2666/18
Abstract: Disclosed are oxygen-scavenging polymer compositions having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, a copolyamide or a transamidized, homogeneous blend of a least two polyamides, and a metal catalyst. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties.
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Patent Agency Ranking26.发明授权
公开(公告)号：EP1913085B1
公开(公告)日：2008-10-15
申请号：EP06740072.1
申请日：2006-03-30
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： HALE, Wesley, Raymond , PECORINI, Thomas, Joseph , STEWART, Mark, Edward , ROGERS, Martin, Emerson , GILLIAM, Spencer, Allen , CLIFFTON, Michael, Duane , CRAWFORD, Emmett, Dudley , PORTER, David, Scott , CONNELL, Gary, Wayne
CPC classification number: B32B27/34 , B29B17/0042 , B29B2911/14906 , B29K2067/00 , B32B27/08 , B32B27/18 , B32B27/36 , B32B2250/24 , B32B2264/105 , B32B2307/412 , B32B2307/716 , B32B2307/7244 , B32B2307/7246 , B32B2553/00 , C08G63/199 , C08L67/02 , C08L77/00 , C08L2205/02 , Y02W30/62 , C08L2666/20
Abstract: Disclosed are oxygen-scavenging polymer compositions having high transparency and low haze comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-l ,3-cyclobutanediol, a copolyamide or a transamidized, homogeneous blend of a least two polyamides, and a metal catalyst. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties.
Abstract translation: 公开了具有高透明度和低雾度的除氧聚合物组合物，其包含至少一种包含2,2,4,4-四甲基-1,3-环丁二醇的聚酯，共聚酰胺或至少两种转酰胺化的均匀共混物 聚酰胺和金属催化剂。 不相容混合物的组分具有相差大约0.006至大约-0.0006的折射率。 折射率的小差异能够将再研磨料掺入聚合物组合物中以制造透明成型制品。 本发明的共混物可用于生产成型制品，例如片材，薄膜，管，瓶，预成型件和型材。 这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔体加工性，同时保持优异的机械性能
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公开(公告)号：EP1871837A1
公开(公告)日：2008-01-02
申请号：EP06736755.7
申请日：2006-03-02
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： HALE, Wesley, Raymond , PECORINI, Thomas, Joseph , STEWART, Mark, Edward , ROGERS, Martin, Emerson , GILLIAM, Spencer, Allen , CLIFFTON, Michael, Duane , SHELBY, Marcus David
CPC classification number: B29B17/0042 , C08K3/08 , C08L67/00 , C08L67/02 , C08L69/00 , C08L77/00 , C08L2205/02 , Y02W30/62 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/20 , C08L2666/14
Abstract: Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.
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28.发明公开POLYESTER/POLYAMIDE BLEND HAVING IMPROVED FLAVOR RETAINING PROPERTY AND CLARITY 审中-公开具有改进的风味保存性质和清晰度聚酯/聚酰胺共混
公开(公告)号：EP1819505A2
公开(公告)日：2007-08-22
申请号：EP05850004.2
申请日：2005-11-28
Applicant: EASTMAN CHEMICAL COMPANY
IPC: B29D22/00 , B65D23/00 , C08K5/04 , C08L77/00 , C08G63/127
CPC classification number: B65D81/266 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29C49/0005 , B29C49/04 , B29C49/06 , B29C51/002 , B29K2067/00 , B29K2077/00 , B29K2995/0067 , B60C1/0008 , C08K5/098 , C08K2201/008 , C08L67/02 , C08L77/06 , Y10T428/1352 , C08L77/00 , C08L2666/20
Abstract: This invention relates to a polyester/polyamide blend having an excellent gas barrier property. More particularly, the present invention relates to combinations of a polyethylene terephthalate polymer and a polyamide polymer having an excellent gas barrier property and short oxygen scavenging induction periods, where the polyamide polymer has a C:A terminal group concentration ratio of 2:1 or more and a C + A terminal group concentration of at least 0.17 meq/g of polyamide polymer, wherein C represents a cumulative total of a terminal carboxyl group concentration and a terminal hydrocarbyl group concentration expressed in meq/g of polyamide, and A represents a terminal amine group concentration expressed in meq/g of polyamide.
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公开(公告)号：EP1203051B1
公开(公告)日：2003-06-11
申请号：EP00952643.5
申请日：2000-08-08
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： BERNARD, Linda, Gail , CLAUBERG, Horst,#c/o Eastman Chemical Company , CYR, Michael, John , GILMER, John, Walker , MATAYABAS, James, Christopher, Jr. , OWENS, Jeffrey, Todd , STEWART, Mark, Edward , TURNER, Sam, Richard , BAGRODIA, Shriram
CPC classification number: B82Y30/00 , C08J5/005 , C08J2377/00 , C08K3/34 , C08K7/00 , C08K2201/008 , C08L77/00
Abstract: The present invention relates to polymer-platelet particle composites comprising at least one polyamide resin, at least one oxygen scavenging system, and platelet particles derived from at least one layered silicate material.
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30.发明授权
公开(公告)号：EP0564514B1
公开(公告)日：1995-11-15
申请号：EP92901619.4
申请日：1991-12-17
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： STEWART, Mark, Edward
IPC: C08L67/02
CPC classification number: C08L67/02 , C08L23/00 , C08L2666/12
Abstract: Disclosed are polymer compositions having improved impact strength, comprising copolyesters of terephthalic acid, ethylene glycol and 1,4-cyclohexanedimethanol with epoxy functional polyolefins.
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