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1.发明申请
公开(公告)号：WO2008088528A1
公开(公告)日：2008-07-24
申请号：PCT/US2007/025275
申请日：2007-12-11
Applicant: EASTMAN CHEMICAL COMPANY
CPC classification number: C08G63/52 , C08L67/02 , C08L67/06 , C08L2666/18
Abstract: Oxygen-scavenging polyester compositions are disclosed that include residues of one or more unsaturated diols, for example, 2-butene-l,4-diol, and residues of one or more aliphatic dicarboxylic acids, for example adipic acid. The compositions may be used as concentrates, and may be blended, for example, with one or more polyethylene terephthalate homopolymers or copolymers, to obtain compositions suitable for use in packaging, providing oxygen-scavenging effect.
Abstract translation: 公开了含氧清除的聚酯组合物，其包括一种或多种不饱和二醇的残基，例如2-丁烯-1,4-二醇，以及一种或多种脂族二羧酸（例如己二酸）的残基。 组合物可以用作浓缩物，并且可以与例如一种或多种聚对苯二甲酸乙二醇酯均聚物或共聚物混合，以获得适合用于包装的组合物，提供除氧效果。
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公开(公告)号：WO2008082468A1
公开(公告)日：2008-07-10
申请号：PCT/US2007/025325
申请日：2007-12-11
Applicant: EASTMAN CHEMICAL COMPANY
IPC: C08G63/00
CPC classification number: C08G63/54 , C08G63/676 , C08G63/826
Abstract: Oxygen-scavenging polyester compositions are disclosed that comprise one or more polyesters having incorporated therein residues of 3-hexenedioic acid and terephthalic acid. The compositions may further comprise residues of one or more aliphatic dicarboxylic acids such as adipic acid. One or more of the polyesters of the compositions may comprise significant amounts of repeating units of polyethylene terephthalate as homopolymers or copolymers, making them suitable for us in packaging compositions having oxygen-scavenging properties.
Abstract translation: 公开了含氧清除的聚酯组合物，其包含一种或多种已加入3-己烯二酸和对苯二甲酸残基的聚酯。 组合物还可以包含一种或多种脂肪族二羧酸如己二酸的残基。 组合物的一种或多种聚酯可以包含显着量的聚对苯二甲酸乙二醇酯作为均聚物或共聚物的重复单元，使得它们适合于具有除氧性能的包装组合物。
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3.发明申请
公开(公告)号：WO2008127542A1
公开(公告)日：2008-10-23
申请号：PCT/US2008/003998
申请日：2008-03-27
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： SIMS, Susan, Rae , STEWART, Mark, Edward , JENKINS, Jason, Christopher , ARMENTROUT, Rodney, Scott , COLHOUN, Frederick, Leslie
IPC: C08L67/02
CPC classification number: C08L67/02 , C08G63/84 , C08K5/098 , C08L77/06 , C08L2666/20
Abstract: Polymer blends suitable for packaging are disclosed that include a transition metal; one or more polyamide homopolymers or copolymers; and one or more polyethylene terephthalate homopolymers or copolymers obtained by a melt phase polymerization using a catalyst system comprising aluminum atoms in an amount, for example, from about 3 ppm to about 60 ppm and one or more alkaline earth metal atoms, alkali metal atoms, or alkali compound residues in an amount, for example, from about 1 ppm to about 25 ppm, in each case based on the weight of the one or more polyethylene terephthalate homopolymers or copolymers. The polymer blends disclosed exhibit improved oxygen-scavenging activity compared with blends made using polymers prepared with conventional catalyst systems.
Abstract translation: 公开了适用于包装的聚合物共混物，其包括过渡金属; 一种或多种聚酰胺均聚物或共聚物; 和一种或多种通过熔融相聚合获得的聚对苯二甲酸乙二醇酯均聚物或共聚物，其使用包含例如约3ppm至约60ppm的铝原子和一种或多种碱土金属原子的碱金属原子的催化剂体系， 或碱金属化合物残基，其量例如为约1ppm至约25ppm，基于一种或多种聚对苯二甲酸乙二醇酯均聚物或共聚物的重量。 与使用用常规催化剂体系制备的聚合物制备的共混物相比，所公开的聚合物共混物显示出改进的除氧活性。
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4.发明申请
公开(公告)号：WO2006137961A1
公开(公告)日：2006-12-28
申请号：PCT/US2006/012660
申请日：2006-03-30
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： HALE, Wesley , PECORINI, Thomas, Joseph , STEWART, Mark, Edward , ROGERS, Martin, Emerson , GILLIAM, Spencer, Allen , CLIFFTON, Michael, Duane , CRAWFORD, Emmett, Dudley , PORTER, David, Scott , CONNELL, Gary, Wayne
CPC classification number: B32B27/34 , B29B17/0042 , B29B2911/14906 , B29K2067/00 , B32B27/08 , B32B27/18 , B32B27/36 , B32B2250/24 , B32B2264/105 , B32B2307/412 , B32B2307/716 , B32B2307/7244 , B32B2307/7246 , B32B2553/00 , C08G63/199 , C08L67/02 , C08L77/00 , C08L2205/02 , Y02W30/62 , C08L2666/20
Abstract: Disclosed are transparent, multilayered articles having high transparency and low haze and a process for their preparation. The multilayer articles comprise at least one layer which contains at least one polyester comprising 2,2,4,4- tetramethyl-1 ,3-cyclobutanediol and a separate layer which contains copolyamide or homogeneous blend of polyamides. The polyester component and the polyamide component have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
Abstract translation: 公开了具有高透明度和低雾度的透明多层制品及其制备方法。 多层制品包含至少一层，其含有至少一种包含2,2,4,4-四甲基-1,3-环丁二醇的聚酯和含有共聚酰胺或聚酰胺的均匀混合物的单独层。 聚酯组分和聚酰胺组分的折射率相差约0.006至约-0.0006。 折射率的小差异使得可以将再研磨物掺入制品的一层或多层中同时保持高透明度。 这些制品可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 可以将金属催化剂并入一个或多个层中以赋予氧气清除性能。
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公开(公告)号：WO2006094148A1
公开(公告)日：2006-09-08
申请号：PCT/US2006/007489
申请日：2006-03-02
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： HALE, Wesley, Raymond , PECORINI, Thomas, Joseph , STEWART, Mark, Edward , ROGERS, Martin, Emerson , GILLIAM, Spencer, Allen , CLIFFTON, Michael, Duane
CPC classification number: B29B17/0042 , C08K3/08 , C08L67/00 , C08L67/02 , C08L69/00 , C08L77/00 , C08L2205/02 , Y02W30/62 , Y10T428/13 , Y10T428/1334 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/31725 , Y10T428/31736 , Y10T428/31739 , C08L2666/20 , C08L2666/14
Abstract: Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.
Abstract translation: 公开了一种制备成形制品的方法，例如片材，膜，管，瓶，预成型件和型材，具有高透明度和低雾度，包括一种或多种选自聚酯，聚碳酸酯和/或其中的热塑性聚合物的不混溶共混物 聚芳酯，以及至少两种聚酰胺的共聚酰胺或酰胺化的均匀共混物。 不混溶共混物的组分具有约0.006至约-0.0006的折射率。 折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。 这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 可以将金属催化剂引入到组合物中以产生具有除氧性能的成形制品。
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Patent Agency Ranking
公开(公告)号：WO2006062816A3
公开(公告)日：2006-06-15
申请号：PCT/US2005/043609
申请日：2005-12-02
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： STEWART, Mark, Edward , SHARPE, Emerson, Eston, Jr. , GAMBLE, Benjamin, Bradford , STAFFORD, Steven, Lee , ESTEP, Robert, Noah , WILLIAMS, James, Carl , CLARK, Thomas, Roger
IPC: C08K5/09 , C08G63/60 , C08F283/04 , C08G69/48 , C08L67/02
Abstract: A solid concentrate is provided having a combination of a transition metal present in an amount ranging from 1000 to 40,000 ppm (weight by metal) and a polyester polymer present in an amount of at least 40 wt.% based on the weight of the concentrate. Concentrates made with highly modified polyester polymers are easy to compound with transition metals forming less brittle polymer upon melt extrusion. Bottle preforms and oxygen scavenging bottles can be made from these concentrates by combining solid polyester particles, solid polyamide particles, and solid these concentrate particles c into an melt processing zone, forming a melt, and forming an article directly from the melt. The b* color and the L* color and the haze levels of the preforms are improved over the preforms made with liquid carriers instead of solid concentrates. The particles are also advantageously simultaneously dried in a drying zone under conditions effective to at least partially remove moisture from the blend to thereby further improve the b* color and L* color.
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公开(公告)号：WO2023027910A1
公开(公告)日：2023-03-02
申请号：PCT/US2022/040390
申请日：2022-08-16
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： SHELBY, Marcus, David , STEWART, Mark, Edward , MAINE, James, Collins , DORTON, Tanner, Storm , ALLEN, John, Michael , LI, Yong
Abstract: A dry spinning system and process are used to produce cellulose ester fibers. The process utilizes one or more of N,N-dimethylformamide, N,N- dimethylacetamide, dimethyl sulfoxide, or mixtures thereof as the dissolution solvent. The process minimizes or avoids discoloration of the fibers.
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8.发明申请TRANSPARENT OXYGEN-SCAVENGING COMPOSITIONS CONTAINING POLYESTERS COMPRISING A CYCLOBUTANEDIOL AND ARTICLES PREPARED THEREFROM 审中-公开包含CYCLOBUTANIIIOLOL和其制备的制品的透明聚氧乙烯的透明氧气组合物
公开(公告)号：WO2007001534A1
公开(公告)日：2007-01-04
申请号：PCT/US2006/011693
申请日：2006-03-30
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： HALE, Wesley, Raymond , PECORINI, Thomas, Joseph , STEWART, Mark, Edward , ROGERS, Martin, Emerson , GILLIAM, Spencer, Allen , CLIFFTON, Michael, Duane , CRAWFORD, Emmett, Dudley , PORTER, David, Scott , CONNELL, Gary, Wayne
CPC classification number: B32B27/34 , B29B17/0042 , B29B2911/14906 , B29K2067/00 , B32B27/08 , B32B27/18 , B32B27/36 , B32B2250/24 , B32B2264/105 , B32B2307/412 , B32B2307/716 , B32B2307/7244 , B32B2307/7246 , B32B2553/00 , C08G63/199 , C08L67/02 , C08L77/00 , C08L2205/02 , Y02W30/62 , C08L2666/20
Abstract: Disclosed are oxygen-scavenging polymer compositions having high transparency and low haze comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-l ,3-cyclobutanediol, a copolyamide or a transamidized, homogeneous blend of a least two polyamides, and a metal catalyst. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties.
Abstract translation: 公开了具有高透明度和低雾度的除氧聚合物组合物，其包含至少一种包含2,2,4,4-四甲基-1,3-环丁二醇，共聚酰胺或经酰胺化，均匀混合的至少两种聚酯的不混溶共混物 聚酰胺和金属催化剂。 不混溶共混物的组分具有约0.006至约-0.0006的折射率。 折射率的小差异使得能够将再研磨物掺入聚合物组合物中以产生透明成型制品。 本发明的共混物可用于生产成形制品，例如片材，薄膜，管，瓶，预型件和型材。 这些制品可以具有一层或多层，并且可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。
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9.发明申请PREPARATION OF TRANSPARENT MULTILAYERED ARTICLES FROM POLYESTERS AND HOMOGENEOUS POLYAMIDE BLENDS 审中-公开透明多层织物从聚酯和均匀聚酰胺混合物的制备
公开(公告)号：WO2006094167A1
公开(公告)日：2006-09-08
申请号：PCT/US2006/007535
申请日：2006-03-02
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： HALE, Wesley, Raymond , PECORINI, Thomas, Joseph , STEWART, Mark, Edward , ROGERS, Martin, Emerson , GILLIAM, Spencer, Allen , CLIFFTON, Michael, Duane
CPC classification number: C08L69/00 , B32B2272/00 , B32B2305/70 , B32B2307/412 , C08K3/08 , C08L67/00 , C08L67/02 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2205/02 , C08L2666/20 , C08L2666/14
Abstract: Disclosed is a process for the preparation of multilayered, shaped articles having high transparency and low haze having at least one layer contains one or more thermoplastic polymers selected from polyesters, polycarbonates, and homogeneous blends thereof, and a separate layer which contains a transamidized, homogeneous blend of a least two polyamides. The thermoplastic polymer components and the polyamide components have refractive indices which differ by about 0.006 to about -0.0006. The small difference in the refractive indices enable the incorporation of regrind into one or more of the layers of the article while maintaining high clarity. These articles can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into one or more layers to impart oxygen-scavenging properties.
Abstract translation: 公开了一种制备具有高透明度和低雾度的多层成形制品的方法，其具有至少一层包含一种或多种选自聚酯，聚碳酸酯及其均匀共混物的热塑性聚合物，以及含有酰胺化均匀的单独层 混合至少两种聚酰胺。 热塑性聚合物组分和聚酰胺组分的折射率相差约0.006至约-0.0006。 折射率的小差异使得可以将再研磨物掺入制品的一层或多层中同时保持高透明度。 这些制品可以表现出改进的优异的阻隔性能和良好的熔融加工性，同时保持优异的机械性能。 可以将金属催化剂并入一个或多个层中以赋予氧气清除性能。
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10.发明申请
公开(公告)号：WO1995015360A1
公开(公告)日：1995-06-08
申请号：PCT/US1994013126
申请日：1994-11-14
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： EASTMAN CHEMICAL COMPANY , STACK, Gary, Michael , STEWART, Mark, Edward , SEYMOUR, Robert, William
IPC: C08L67/02
CPC classification number: C08L23/08 , C08L63/00 , C08L101/06 , C08L2205/12 , C08L2666/18
Abstract: This invention relates to a blend comprising: (a) about 50 to about 98 weight percent of an isotropic polymer containing at least one epoxy functional monomer having at least one epoxy group, and (b) about 2 to about 50 weight percent of a liquid crystalline polyester.
Abstract translation: 本发明涉及一种共混物，其包含：（a）约50至约98重量％的含有至少一个具有至少一个环氧基的环氧官能单体的各向同性聚合物，和（b）约2至约50重量％的液体 结晶聚酯。
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