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    Mixtures of thermoplastic polyamides
    24.
    发明授权
    Mixtures of thermoplastic polyamides 失效
    热塑性聚氨酯的混合物

    公开(公告)号：US3875129A

    公开(公告)日：1975-04-01

    申请号：US41563673

    申请日：1973-11-14

    Applicant: HOECHST AG

    Inventor： HERWIG WALTER ,  CHERDRON HARALD ,  BRINKMANN LUDWIG

    IPC: C08G69/02 ,  C08L77/00 ,  C08G41/04

    CPC classification number: C08L77/00 ,  C08G69/02 ,  C08L77/06 ,  C08L2666/20

    Abstract: There are disclosed and claimed novel mixtures of thermoplastic polyamides, namely mixtures of at least one polyamide derived from 1,3-bis-aminomethyl-cyclohexane, which optionally is partly replaced by 1,4-bis-aminomethyl-cyclohexane and optionally at least one aliphatic diamine, at least one aromatic dicarboxylic acid and optionally at least one aliphatic dicarboxylic acid, and optionally at least one aminocarboxylic acid, with at least one polyamide each of the polyamide 6 and/or polyamide 6,6 types. The mixtures of the invention combine good mechanical with good flow properties.

    Abstract translation: 公开并要求新的热塑性聚酰胺混合物，即至少一种衍生自1,3-双氨基甲基 - 环己烷的聚酰胺的混合物，其任选地部分被1,4-双氨基甲基 - 环己烷取代，并且任选地至少一个 脂族二胺，至少一种芳族二羧酸和任选的至少一种脂族二羧酸，以及任选的至少一种氨基羧酸，至少一种聚酰胺6和/或聚酰胺6,6类型的聚酰胺。 本发明的混合物结合良好的机械性能和良好的流动性能。

    Flame resistant thermoplastic polyesters
    25.
    发明授权
    Flame resistant thermoplastic polyesters 失效
    耐火热塑性聚酯

    公开(公告)号：US3865780A

    公开(公告)日：1975-02-11

    申请号：US38442673

    申请日：1973-08-01

    Applicant: HOECHST AG

    Inventor： HERWIG WALTER ,  RACKY WERNER

    IPC: C08L67/00 ,  C08G63/00 ,  C08G63/78 ,  C08K5/5397 ,  C09K3/28

    CPC classification number: C08K5/5397 ,  C08L67/02

    Abstract: Flame resistant molding compositions from linear saturated polyesters and an alkali metal salt of a dialkylphosphinylalkanesulfonic acid of the formula

    WHERE R1 and R2 each are alkyl having from 1 to 4 carbon atoms, n represents integers of from 1 to 12 and Me is an alkali metal atom.

    Abstract translation: 来自线性饱和聚酯的阻燃模塑组合物和式WHERE R 1和R 2的二烷基氧膦基 - 链烷磺酸的碱金属盐各自是具有1至4个碳原子的烷基，n表示1至12的整数，Me是碱 金属原子。

    Thermoplastic moulding compositions on the basis of saturated polyesters
    27.
    发明授权
    Thermoplastic moulding compositions on the basis of saturated polyesters 失效

    公开(公告)号：US3619267A

    公开(公告)日：1971-11-09

    申请号：US3619267D

    申请日：1969-04-18

    Applicant: HOECHST AG

    Inventor： WEISSERMEL KLAUS ,  KERN RUDOLF ,  HERWIG WALTER ,  BREITSCHAFT SIEGFRIED

    IPC: C08J3/00 ,  C08L67/02 ,  B32B27/06 ,  B32B27/36

    CPC classification number: C08L67/02 ,  C08J3/00 ,  C08L2666/14 ,  C08L2666/54

    Abstract: Thermoplastic moulding compositions on the basis of saturated linear polyesters which comprises coating the polyester granules with neutralized or partially neutralized slats of montan wax or of esters of montan wax. The present invention relates to thermoplastic moulding compositions on the basis of saturated polyesters, which moulding compositions have improved properties. It has been proposed to produce shaped articles from thermoplastic moulding compositions comprising saturated linear polyesters of aromatic dicarboxylic acids. It has also been proposed to add to polyethylene terephthalate finely divided inorganic substances as nucleating agents to increase the speed of crystallization of the injection moulded polyester in the mould. By this step the crystallinity and the density of the injection moulded articles are increased and therewith the dimensional stability and stability of shape at elevated temperature are improved. As solid inorganic substances there have been proposed, for example metal oxides, alkaline earth metal salts, talc powder, glass powder, or metals. The inorganic substances should have a particle size of less than 2 microns. It has likewise been proposed further to increase the speed of crystallization by adding to the polyesters a mixture of the inorganic nucleating agents with specific epoxides. In copending application Ser. No. 817,545 filed concurrently herewith, a process for the manufacture of rapidly crystallizing moulding compositions on the basis of saturated linear polyesters is described in which the polyester mixed with inert inorganic solids and specific epoxides is coated, after the usual aftercondensation, with a salt of a montan wax or of a montan wax ester. By the addition of montan wax salts or salts of montan wax esters to the polyester composition containing inorganic nucleating agents and specific epoxides, the injection cycle can be considerably shortened and therewith the rate of production increased without the utilitarian properties of the polyester being detrimentally affected. Further experiments have revealed that the aforesaid process can be further simplified. It has now been found that thermoplastic moulding compositions on the basis of saturated linear polyesters having advantageous properties can be prepared by coating polyester granules having a moisture content below 0.01 percent by weight and a reduced specific viscosity of at least l.25 dl./g, measured with a 1 percent solution in a 60:40 mixture of phenol and tetrachloroethane at 25* C., with 0.01 to 1 percent by weight, preferably 0.1 to 0.8 percent by weight and more preferably 0.3 to 0.7 percent by weight, calculated on the polyester, of neutral or partially neutralized salts of montan wax or of montan wax esters. The present process, in which the polyester gRanules are merely coated with salts of montan wax or of montan wax esters, has a plurality of advantages over the aforesaid processes. The montanates are better compatible with the polyester than inorganic solids. As the montan wax salts melt during processing they are more finely divided in the polyester and thus more effective. Moreover agglomerates, which may cause flaws when inorganic solids are added and reduce the impact strength of the injection moulded articles, are not formed. As polyester, polyethylene terephthalate is used in the first place. Other suitable polyesters are, for example polycyclohexane-1,4-dimethylol terephthalate or polyesters containing as acid component, in addition to terephthalic acid, up to 5 mole percent of other aromatic or aliphatic dicarboxylic acids, such as isophthalic acid, naphthalene-2,6-dicarboxylic acid or adipic acid, or as alcoholic component, in addition to ethylene glycol, up to 30 mole percent of other aliphatic diols, such as 2,2-dimethylpropane-diol-1,3) or butane-diol-(1,4), or up to 1 percent of tetrols, for example 1,1,4,4-tetramethylolcyclohexane. Polyesters of hydroxycarboxylic acids may also be used. The polyesters should have a reduced specific viscosity of from 0.6 to 2.0 dl./g., preferably 0.9 to 1.6 dl./g., measured with a 1 percent polymer solution in a 60:40 mixture of phenol and tetrachloroethane at 25* C. Especially good results are obtained with polyesters having a reduced specific viscosity of from 1.1 to 1.5 dl./g. Montan acid is an acid mixture essentially consisting of aliphatic monocarboxylic acids having 26 to 32 carbon atoms in the chain. Suitable salts of montan wax contain as cation metals of main groups I- III of the Periodic system, preferably Li, Na, K, Be, Mg, Ca, and A1, sodium montanates being preferred. As partially neutralized salts of montan wax there are used salts obtained by reacting montan acid with 0.1 to 1 equivalent of alkali metal hydroxide or alkali metal oxide, preferably salts obtained with 0.25 to 0.9 equivalent of sodium hydroxide. Salts of montan wax esters that can be used are obtained by partial esterification of montan acids with up to 0.90 equivalent, preferably 0.5 to 0.8 equivalent of dihydric alcohols having two to four carbon atoms in the alkylene group, with subsequent neutralization with oxides or hydroxides of the metals specified above. Especially suitable diols are, for example, ethylene glycol, 1,2-propane-diol, 1,3-propane-diol, 1,3-butanediol and 1,4-butane-diol. The desired effect of the salts of montan wax or of montan wax esters as nucleating agent and mould release agent can only be obtained if the finished granules are coated with the said compounds after the usual drying and after-condensation. By coating the finished polyester granules with the montan wax salt or the salt of a montan wax ester there are obtained not only a rapid crystallization of the moulded article in the mould and better mould release properties, but simultaneously the granules are protected against the absorption of moisture. To obtain unobjectionable injection moulded articles the polyester moulding composition should contain as little moisture as possible, preferably less than 0.0l percent by weight. In order to bring about crystallization in the mould the mould must be maintained at a temperature of at least 110* C. A rapid crystallization and therewith short injection cycles are obtained with mould temperatures in the range of from 120* to 150* C., preferably of from 135* to 145* C. Tests were carried out using the injection mould for a program control dial of a washing machine wherein the dial was pressed out of the mould by very sharp ejector pins. The injection cycle was defined after which the ejector pins did just not penetrate into the finished moulded articles and the article fell from the mould almost by itself. The following examples serve to illustrate the invention but they are not intended to limit it thereto, the percentages are percent by weight, calculated on the polyethylene terephthalate.

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