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公开(公告)号:BR7409779A
公开(公告)日:1976-05-25
申请号:BR977974
申请日:1974-11-21
Applicant: HOECHST AG
IPC: C08B11/187 , A61L15/28 , C08B11/14 , C08B11/193 , C08B15/10 , C08B11/08 , C08B11/12
Abstract: This invention relates to an improvement in the process for the production of water-adsorbing, but largely water-insoluble, cellulose ethers, in which cellulose is alkalized in the presence of alkali and isopropanol as a reaction medium and is so reacted with an etherification agent that by etherification only a water-soluble cellulose ether is produced, and in which process a modification agent which is able to react with the still free hydroxyl groups of the cellulose anhydro glucose groups in an alkaline reaction medium is reacted before, during, or after the etherification, the improvement comprising effecting the etherification of cellulose to carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose, or methylhydroxyethyl cellulose, reacting with the modification agent in the presence of 0.8 to 7.5 parts by weight of isopropanol, based upon the cellulose weight, and employing a modification agent being one of the formulae HOHH H ¦ PARALLEL ¦¦ ¦ (I) H2C=C-C-N-C-R1 and (II) H2C=C-SO2-NH2, ¦ R2 R1 in formula I being hydroxyl, or an acylamino or etherified carbamino group, and R2 in formula I being hydrogen or a carboxyl group.
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公开(公告)号:BR7409528A
公开(公告)日:1976-05-25
申请号:BR952874
申请日:1974-11-13
Applicant: HOECHST AG
Inventor: LASK H , HOLST A , KOSTRZEWA M
Abstract: This invention relates to an improvement in the process for the production of water-adsorbing, but largely water-insoluble, cellulose ethers, in which cellulose is alkalized in the presence of alkali hydroxide and isopropanol as a reaction medium and is so reacted with an etherification agent that by etherification only a water-soluble cellulose ether is produced, and in which process the cellulose is reacted with a cross-linking agent which is polyfunctional towards cellulose in an alkaline reaction medium before, during, or after the etherification of the cellulose, the improvement comprising effecting the etherification of cellulose to carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose, or methylhydroxyethyl cellulose, reacting the cellulose with the polyfunctional cross-linking agent in the presence of 0.8 to 7.5 parts by weight of isopropanol, based upon the cellulose weight, and employing as the cross-linking agent acrylamido methylene chloroacetamide, dichloroacetic acid or phosphorus oxychloride or a compound in which at least two groups functional towards cellulose are THE ACRYLIC AMINO GROUP CH2=CH-C-N- PARALLEL ¦ O the chlorine azomethine group -N=C- ¦ Cl OR THE ALLYLOXY AZOMETHINE GROUP -N=C-O-CH2-CH=CH2 . ¦
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公开(公告)号:DK129875A
公开(公告)日:1975-09-29
申请号:DK129875
申请日:1975-03-26
Applicant: HOECHST AG
Inventor: HOLST A , KOSTRZEWA M , LASK H
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公开(公告)号:FI329274A
公开(公告)日:1975-05-16
申请号:FI329274
申请日:1974-11-13
Applicant: HOECHST AG
Inventor: HOLST A , KOSTRZAWA M , LASK H
IPC: C08B11/187 , A61L15/28 , C08B11/00 , C08B15/10 , C08B
Abstract: This invention relates to an improvement in the process for the production of water-adsorbing, but largely water-insoluble, cellulose ethers, in which cellulose is alkalized in the presence of alkali hydroxide and isopropanol as a reaction medium and is so reacted with an etherification agent that by etherification only a water-soluble cellulose ether is produced, and in which process the cellulose is reacted with a cross-linking agent which is polyfunctional towards cellulose in an alkaline reaction medium before, during, or after the etherification of the cellulose, the improvement comprising effecting the etherification of cellulose to carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose, or methylhydroxyethyl cellulose, reacting the cellulose with the polyfunctional cross-linking agent in the presence of 0.8 to 7.5 parts by weight of isopropanol, based upon the cellulose weight, and employing as the cross-linking agent acrylamido methylene chloroacetamide, dichloroacetic acid or phosphorus oxychloride or a compound in which at least two groups functional towards cellulose are THE ACRYLIC AMINO GROUP CH2=CH-C-N- PARALLEL ¦ O the chlorine azomethine group -N=C- ¦ Cl OR THE ALLYLOXY AZOMETHINE GROUP -N=C-O-CH2-CH=CH2 . ¦
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公开(公告)号:SE431458B
公开(公告)日:1984-02-06
申请号:SE7605036
申请日:1976-05-03
Applicant: HOECHST AG
IPC: A61F13/472 , A61F13/15 , A61F13/53 , A61L15/28 , A61L15/60 , C08B11/08 , C08B11/187 , C08B15/00 , C08B15/10 , C08B11/00
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公开(公告)号:AU502704B2
公开(公告)日:1979-08-02
申请号:AU1361476
申请日:1976-05-04
Applicant: HOECHST AG
IPC: A61F13/472 , A61F13/15 , A61F13/53 , A61L15/28 , A61L15/60 , C08B11/08 , C08B11/187 , C08B15/00 , C08B15/10
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公开(公告)号:DK107478A
公开(公告)日:1978-09-13
申请号:DK107478
申请日:1978-03-10
Applicant: HOECHST AG
Inventor: HOLST A , LASK H , NISCHITZ E , FISCHER W
IPC: D04H1/42 , D04H1/425 , D04H1/4258 , D04H1/435 , D04H1/46 , D04H1/488 , D04H1/587 , D04H1/64 , D04H
Abstract: This invention relates to a bonded fiber web capable of absorbing water vapor and composed of synthetic, natural or regenerated fibers with a uniformly incorporated additive of at least one polymer, said additive comprising fibrous particles of at least one swellable carbohydrate derivative or a swellable modified carbohydrate derivative. The invention also relates to a process for the manufacture of the bonded fiber web.
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公开(公告)号:SE7709478A
公开(公告)日:1977-08-23
申请号:SE7709478
申请日:1977-08-23
Applicant: HOECHST AG
Inventor: HOLST A , KOSTRZEWA M , LASK H
IPC: C08L101/00 , A61L15/28 , B01J47/12 , C08J5/22 , C08J7/04 , C08J9/28 , C08L1/00 , C08L1/06 , C08L1/08 , C08L1/26 , C08L67/00 , C08L77/00 , D01F1/10 , D01F2/28 , D06M15/09 , C08J5/18
CPC classification number: B01D71/10 , A61L15/28 , B01D69/141 , B01J47/12 , C08J5/2212 , C08J7/047 , C08J9/28 , C08J2301/02 , C08L1/08 , D01F2/28 , D06M15/09 , C08L1/26
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