公开(公告)号：AU7505287A

公开(公告)日：1988-01-07

申请号：AU7505287

申请日：1987-07-02

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  KLEBER ROLF ,  JAECKEL LOTHAR

IPC: C07C275/06 ,  C07C67/00 ,  C07C239/00 ,  C07C257/10 ,  C07C271/42 ,  C07C275/04 ,  C07C275/62 ,  C07C275/64 ,  C07C311/01 ,  C07C313/00 ,  C07C315/04 ,  C07C317/22 ,  C07C317/36 ,  C07C317/44 ,  C08G18/28 ,  C08G18/32 ,  D06M13/425 ,  D06M15/576 ,  C07C127/19 ,  C07C125/075 ,  C07C125/077 ,  C07C147/10 ,  C14C9/00 ,  C07C127/24 ,  D06M13/38

Abstract: The molecule of the new urethanes contains an aliphatic fluoroalcohol, an isocyanate and an aromatic dihydroxy, diamino, aminohydroxy, aminocarboxy or hydroxycarboxy compound. They are prepared by reacting an aliphatic fluoroalcohol with a diisocyanate or triisocyanate to give the fluoroalcohol/isocyanate adduct and by reacting this adduct with said aromatic compound to give the desired urethanes composed of an aliphatic fluoroalcohol, an isocyanate and the bifunctional aromatic compound mentioned, and also be reacting a urethane of this type which also carries an active hydrogen atom on the bifunctional aromatic compound, with an isocyanate compound containing one or more isocyanate groups. The new urethanes are preferably used for imparting an oleophobic and hydrophobic finish to textiles and leather.

公开(公告)号：AU6504186A

公开(公告)日：1987-05-21

申请号：AU6504186

申请日：1986-11-12

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  KLEBER ROLF ,  JAECKEL LOTHAR

IPC: C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C269/02 ,  C07C271/10 ,  C07C271/20 ,  C07C271/24 ,  C07C271/28 ,  C07C275/04 ,  C07C275/62 ,  C07C301/00 ,  C07C303/40 ,  C07C311/01 ,  C08G18/28 ,  C08G18/30 ,  C08G18/38 ,  C08G65/38 ,  C08G65/48 ,  C08G73/06 ,  D06M13/02 ,  D06M13/322 ,  D06M15/568 ,  D06M15/576 ,  C07C125/073 ,  C07C125/077 ,  C07C127/24 ,  C07C127/15

Abstract: The novel urethanes, in addition to at least one perfluoroalkyl group, also contain epichlorohydrin groups and dialcohol radicals in the molecule. They are prepared by reacting a fluorine-containing alcohol with epichlorohydrin to give the perfluoroalkyl-epichlorohydrin adduct, reacting this adduct with a di- or triisocyanate to give the perfluoroalkyl-epichlorohydrin-isocyanate adduct and by reacting this adduct with a dialcohol or a monoetherified dialcohol to give the desired urethanes having a perfluoroalkyl group and having epichlorohydrin groups and dialcohol radicals, and by reacting a suitable urethane compound of this type with a perfluoroalkyl-containing di- or triisocyanate to give the desired urethanes having a plurality of perfluoroalkyl groups and having epichlorohydrin groups and dialcoholradicals. The novel urethanes are preferably used for the oleophobic and hydrophobic finishing of textiles.

公开(公告)号：BR8604126A

公开(公告)日：1987-04-22

申请号：BR8604126

申请日：1986-08-29

Applicant: HOECHST AG

Inventor： BATHELT HEINRICH ,  EHRL WINFRIED ,  WEHOWSKY FRANK ,  KLEBER ROLF ,  LOTZ WERNER ,  GLENZ WOLFGANG ,  HERDT HUBERT ,  JACKEL LOTHAR ,  MAST JAN-HILBERT ,  HINTERMEIER KARL ,  MULLER MANFRED

IPC: C09K3/18 ,  B27K3/38 ,  C07C67/00 ,  C07C239/00 ,  C07C271/06 ,  C07C271/28 ,  C08G65/32 ,  C09K3/00 ,  C14C9/00 ,  D06M13/02 ,  D06M13/224 ,  D06M13/322 ,  D06M13/342 ,  D06M13/345 ,  D06M13/425 ,  D06M13/428 ,  D06M13/463 ,  D06M101/00 ,  D06M101/02 ,  D06M101/10 ,  D06M101/12 ,  C07C125/073

Abstract: The novel urethanes correspond to the formula I below in which a denotes a number from 5 to 17 and b denotes a number from 1 to 7. These urethanes are prepared by reacting the corresponding perfluoroalkylethanol/epichlorohydrin adducts with toluelene diisocyanates. The novel aqueous dispersions are essentially composed of the novel urethanes, cationic or betaine emulsifiers and non-ionic emulsifiers, water-insoluble carboxylic and/or dicarboxylic acid esters and alkanediols or polyalkanediols which can be etherified on one or both sides, in water. The novel urethanes and the novel aqueous dispersions are used to impart an oleophobic and hydrophobic finish to textiles, leather and furs. They are also suitable for the treatment of unpainted timber, for example unpainted furniture.

公开(公告)号：CA1305174C

公开(公告)日：1992-07-14

申请号：CA587105

申请日：1988-12-28

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  KLEBER ROLF ,  JAECKEL LOTHAR

IPC: C07C271/08 ,  C07C271/28 ,  C07C271/36 ,  C07C271/38 ,  C07C271/40 ,  C07C271/42 ,  C07C275/14 ,  C07C275/28 ,  C07C275/62 ,  C07C311/03 ,  C08G18/28 ,  C08G18/32 ,  D06M13/02 ,  D06M13/322 ,  D06M13/342 ,  D06M13/402 ,  D06M13/425 ,  D06M13/428 ,  D06M13/432 ,  D06M13/438 ,  D06M15/576 ,  C14C11/00

Abstract: 23221-4576 of the disclosure Urethanes made from aliphatic fluorinated alcohols, isocyanates and substituted aromatic compounds, a process for their preparation, and their use. Novel urethanes of the general formula (1), in which Rf denotes, for example, a C4-C20 perfluoroalkyl, R1 is H or C1-C4 alkyl, X is an integer from 1 to 4, Y is an integer from 0 to 10, m and n are integers from 1 to 2, the sum m + n being at most 3, and A is, for example, a phenylene or toluylene group are disclosed. The novel urethanes are synthesized from an aliphatic fluorinated alcohol, an isocyanate and a specific substituted phenol or aniline compound. They are prepared by reacting an aliphatic fluorinated alcohol with a di - or triisocyanate to form a fluorinated alcohol/isocyanate adduct and reacting this adduct with a certain substituted phenol or aniline to form the urethanes intended. The novel urethanes are preferably used for oleophobic and hydrophobic finishing of textiles and leather.

公开(公告)号：AT66914T

公开(公告)日：1991-09-15

申请号：AT86115437

申请日：1986-11-07

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  KLEBER ROLF ,  JAECKEL LOTHAR

IPC: C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C269/02 ,  C07C271/10 ,  C07C271/20 ,  C07C271/24 ,  C07C271/28 ,  C07C275/04 ,  C07C275/62 ,  C07C301/00 ,  C07C303/40 ,  C07C311/01 ,  C08G18/28 ,  C08G18/30 ,  C08G18/38 ,  C08G65/38 ,  C08G65/48 ,  C08G73/06 ,  D06M13/02 ,  D06M13/322 ,  D06M15/568 ,  D06M15/576

公开(公告)号：CA2033312A1

公开(公告)日：1991-06-29

申请号：CA2033312

申请日：1990-12-27

Applicant: HOECHST AG

Inventor： KNAUP WOLFGANG ,  WEHOWSKY FRANK ,  SCHMITT NORBERT

IPC: C09K23/46 ,  C07C213/04 ,  C07C217/28 ,  C07C217/50 ,  C07C229/12 ,  C07C229/22 ,  C07C309/14 ,  C09K23/42 ,  C11D1/00 ,  C07C229/04 ,  C07C309/10 ,  B01F17/16 ,  C07C217/42

Abstract: HOE 89/F 921 of the disclosure: Surface-active compounds having a perfluoroalkyl group and a nitrogen-containing aliphatic radical, a process for their preparation and their use The new compounds have the formula below in which Rf is a perfluoroalkyl radical having 4 to 20 carbon atoms, x is 1 to 4, y is 1 to 10, X is Br, Cl or I, and R1 and R2 are hydrogen or a C1 to C4-alkyl radical or a water-solubilizing aliphatic radical, with the proviso that at least one of the two substituents and R2 is a water-solubilizing aliphatic radical. The surface-active compounds described are prepared by reacting a suitable epoxide with a suitable amine. They are used in particular for the preparation of foaming agents.

公开(公告)号：AU606489B2

公开(公告)日：1991-02-07

申请号：AU2749488

申请日：1988-12-23

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  KLEBER ROLF ,  JAECKEL LOTHAR

IPC: C07C271/08 ,  C07C271/28 ,  C07C271/36 ,  C07C271/38 ,  C07C271/40 ,  C07C271/42 ,  C07C275/14 ,  C07C275/28 ,  C07C275/62 ,  C07C311/03 ,  C08G18/28 ,  C08G18/32 ,  D06M13/02 ,  D06M13/322 ,  D06M13/342 ,  D06M13/402 ,  D06M13/425 ,  D06M13/428 ,  D06M13/432 ,  D06M13/438 ,  D06M15/576 ,  C07C127/24 ,  C07C125/075

Abstract: The novel urethanes are synthesised from aliphatic fluoroalcohol, isocyanate and a specific substituted phenol or aniline compound. They are prepared by reaction of an aliphatic fluoroalcohol with a di- or triisocyanate to form a fluoroalcohol/isocyanate adduct and by reaction of this adduct with a specific substituted phenol or aniline to give the desired urethanes. The urethanes are preferably used for the oleophobic and hydrophobic finishing of textiles and leather.

公开(公告)号：AU602225B2

公开(公告)日：1990-10-04

申请号：AU1876188

申请日：1988-07-06

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  LIEBIGER MARTIN

IPC: C07F7/10 ,  C08G18/61 ,  C08G18/80 ,  C08G77/38 ,  C08G77/385 ,  C08G77/388 ,  C08G77/46 ,  D06M15/653 ,  D06M15/657 ,  C08G77/40 ,  C09D3/72 ,  C09D3/82 ,  C14C3/18 ,  D06M15/643

Abstract: The novel urethanes are composed essentially of fluoroalcohol-isocyanate adducts as the fluoro component and a polysiloxane component, the two components being combined in a structurally specific manner. The novel urethanes are prepared by reacting the fluoroalcohol-isocyanate adducts with the polysiloxane in a molar ratio of 1 to 2:1 at a temperature of 30 DEG to 130 DEG C. The novel urethanes are preferably used for finishing textiles, to which they also impart the property of a soft handle in addition to good hydrophobicity and oleophobicity. They are also suitable for finishing leather, skins and wood.

公开(公告)号：DD271333A5

公开(公告)日：1989-08-30

申请号：DD31759188

申请日：1988-07-05

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  LIEBIGER MARTIN

IPC: C07F7/10 ,  C08G18/61 ,  C08G18/80 ,  C08G77/38 ,  C08G77/385 ,  C08G77/388 ,  C08G77/46 ,  D06M15/653 ,  D06M15/657 ,  C08G18/32

Abstract: The novel urethanes are composed essentially of fluoroalcohol-isocyanate adducts as the fluoro component and a polysiloxane component, the two components being combined in a structurally specific manner. The novel urethanes are prepared by reacting the fluoroalcohol-isocyanate adducts with the polysiloxane in a molar ratio of 1 to 2:1 at a temperature of 30 DEG to 130 DEG C. The novel urethanes are preferably used for finishing textiles, to which they also impart the property of a soft handle in addition to good hydrophobicity and oleophobicity. They are also suitable for finishing leather, skins and wood.

公开(公告)号：BR8803657A

公开(公告)日：1989-02-14

申请号：BR8803657

申请日：1988-07-21

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK

IPC: C08G65/32 ,  C07D301/26 ,  C07D303/16 ,  C07D303/22 ,  C07D303/24 ,  C08G18/30 ,  C08G18/50

Abstract: Perfluoroalkyl-containing epoxides of the formula 1 in which Rf is a perfluoroalkyl-containing radical, X is halogen, a is 1 to 4 and b is 0 to 20, are prepared by reacting a fluoroalcohol/ epihalohydrin adduct of the formula 2 in which Rf, X, a and b have the meanings mentioned, with alkali metal hydroxide or alkaline earth metal hydroxide in the form of an aqueous solution in the presence of phase-transfer catalysts and at a pH of 9 to 12. The perfluoroalkyl-containing epoxides are those of the formula 3 in which Rf, X and a have the meanings mentioned and b is 1 to 20. The epoxides in question are advantageous monomers for the preparation of fluorine-containing epoxy resins and epoxy copolymers, which in turn are good finishing agents for textiles and leather.