公开(公告)号：JPS62120352A

公开(公告)日：1987-06-01

申请号：JP26787786

申请日：1986-11-12

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  KLEBER ROLF ,  JAECKEL LOTHAR

IPC: C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C269/02 ,  C07C271/10 ,  C07C271/20 ,  C07C271/24 ,  C07C271/28 ,  C07C275/04 ,  C07C275/62 ,  C07C301/00 ,  C07C303/40 ,  C07C311/01 ,  C08G18/28 ,  C08G18/30 ,  C08G18/38 ,  C08G65/38 ,  C08G65/48 ,  C08G73/06 ,  D06M13/02 ,  D06M13/322 ,  D06M15/568 ,  D06M15/576

公开(公告)号：CA1328461C

公开(公告)日：1994-04-12

申请号：CA571196

申请日：1988-07-06

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  LIEBIGER MARTIN

IPC: C07F7/10 ,  C08G18/61 ,  C08G18/80 ,  C08G77/38 ,  C08G77/385 ,  C08G77/388 ,  C08G77/46 ,  D06M15/653 ,  D06M15/657 ,  C08G77/26 ,  D06M13/513

Abstract: of the disclosure Urethanes containing fluorine and polysiloxane, processes for their preparation, and their use The novel urethanes are composed essentially of fluoroalcohol-isocyanate adducts as the fluoro component and a polysiloxane component, the two components being combined in a structurally specific manner. The novel urethanes are prepared by reacting the fluoroalcohol-isocyanate adducts with the polysiloxane in a molar ratio of 1 to 2:1 at a temperature of 30 to 130.degree.C. The novel urethanes are preferably used for finishing textiles, to which they also impart the property of a soft handle in addition to good hydrophobicity and oleophobicity. They are also suitable for finishing leather, skins and wood.

公开(公告)号：CA1296018C

公开(公告)日：1992-02-18

申请号：CA541102

申请日：1987-07-02

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  KLEBER ROLF ,  JAECKEL LOTHAR

IPC: C07C275/06 ,  C07C67/00 ,  C07C239/00 ,  C07C257/10 ,  C07C271/42 ,  C07C275/04 ,  C07C275/62 ,  C07C275/64 ,  C07C311/01 ,  C07C313/00 ,  C07C315/04 ,  C07C317/22 ,  C07C317/36 ,  C07C317/44 ,  C08G18/28 ,  C08G18/32 ,  D06M13/425 ,  D06M15/576 ,  C07C271/06 ,  C07C275/40

Abstract: of the disclosure: Urethanes formed from aliphatic fluoroalcohols, isocyanates and aromatic compounds, a process for their preparation and their use The molecule of the new urethanes contains an aliphatic fluoroalcohol, an isocyanate and an aromatic dihydroxy, diamino, aminohydroxy, aminocarboxy or hydroxycarboxy compound. They are prepared by reacting an aliphatic fluoroalcohol with a diisocyanate or triisocyanate to give the fluoroalcohol/isocyanate adduct and by reacting this adduct with said aromatic compound to give the desired urethanes composed of an aliphatic fluoroalcohol, an isocyanate and the bifunctional aromatic compound mentioned, and also be reacting a urethane of this type which also carries an active hydrogen atom on the bifunctional aromatic compound, with an isocyanate compound containing one or more isocyanate groups. The new urethanes are preferably used for imparting an oleophobic and hydrophobic finish to textiles and leather.

公开(公告)号：BR8806934A

公开(公告)日：1989-08-29

申请号：BR8806934

申请日：1988-12-28

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  KLEBER ROLF ,  JAECKEL LOTHAR

IPC: C07C271/08 ,  C07C271/28 ,  C07C271/36 ,  C07C271/38 ,  C07C271/40 ,  C07C271/42 ,  C07C275/14 ,  C07C275/28 ,  C07C275/62 ,  C07C311/03 ,  C08G18/28 ,  C08G18/32 ,  D06M13/02 ,  D06M13/322 ,  D06M13/342 ,  D06M13/402 ,  D06M13/425 ,  D06M13/428 ,  D06M13/432 ,  D06M13/438 ,  D06M15/576 ,  C07C125/04 ,  C07C127/24 ,  C14C9/00 ,  D06M13/38

Abstract: The novel urethanes are synthesised from aliphatic fluoroalcohol, isocyanate and a specific substituted phenol or aniline compound. They are prepared by reaction of an aliphatic fluoroalcohol with a di- or triisocyanate to form a fluoroalcohol/isocyanate adduct and by reaction of this adduct with a specific substituted phenol or aniline to give the desired urethanes. The urethanes are preferably used for the oleophobic and hydrophobic finishing of textiles and leather.

公开(公告)号：AU1876188A

公开(公告)日：1989-01-12

申请号：AU1876188

申请日：1988-07-06

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  LIEBIGER MARTIN

IPC: C07F7/10 ,  C08G18/61 ,  C08G18/80 ,  C08G77/38 ,  C08G77/385 ,  C08G77/388 ,  C08G77/46 ,  D06M15/653 ,  D06M15/657 ,  C08G77/40 ,  C09D3/72 ,  C09D3/82 ,  C14C3/18 ,  D06M15/643

Abstract: The novel urethanes are composed essentially of fluoroalcohol-isocyanate adducts as the fluoro component and a polysiloxane component, the two components being combined in a structurally specific manner. The novel urethanes are prepared by reacting the fluoroalcohol-isocyanate adducts with the polysiloxane in a molar ratio of 1 to 2:1 at a temperature of 30 DEG to 130 DEG C. The novel urethanes are preferably used for finishing textiles, to which they also impart the property of a soft handle in addition to good hydrophobicity and oleophobicity. They are also suitable for finishing leather, skins and wood.

公开(公告)号：DD257828A5

公开(公告)日：1988-06-29

申请号：DD30453687

申请日：1987-07-02

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK ,  KLEBER ROLF ,  JAECKEL LOTHAR

IPC: C07C275/06 ,  C07C67/00 ,  C07C239/00 ,  C07C257/10 ,  C07C271/42 ,  C07C275/04 ,  C07C275/62 ,  C07C275/64 ,  C07C311/01 ,  C07C313/00 ,  C07C315/04 ,  C07C317/22 ,  C07C317/36 ,  C07C317/44 ,  C08G18/28 ,  C08G18/32 ,  D06M13/425 ,  D06M15/576 ,  C07C125/04

Abstract: The molecule of the new urethanes contains an aliphatic fluoroalcohol, an isocyanate and an aromatic dihydroxy, diamino, aminohydroxy, aminocarboxy or hydroxycarboxy compound. They are prepared by reacting an aliphatic fluoroalcohol with a diisocyanate or triisocyanate to give the fluoroalcohol/isocyanate adduct and by reacting this adduct with said aromatic compound to give the desired urethanes composed of an aliphatic fluoroalcohol, an isocyanate and the bifunctional aromatic compound mentioned, and also be reacting a urethane of this type which also carries an active hydrogen atom on the bifunctional aromatic compound, with an isocyanate compound containing one or more isocyanate groups. The new urethanes are preferably used for imparting an oleophobic and hydrophobic finish to textiles and leather.

公开(公告)号：CA2144228A1

公开(公告)日：1995-09-10

申请号：CA2144228

申请日：1995-03-08

Applicant: HOECHST AG

Inventor： PROSSEL GUENTER ,  KNAUP WOLFGANG ,  WEHOWSKY FRANK

IPC: B01J23/40 ,  C07B61/00 ,  C07C211/15 ,  C07C215/12 ,  C07C229/12 ,  C07C303/32 ,  C07C309/13 ,  C07C309/14 ,  C07C215/08 ,  C11D1/92

Abstract: New saturated fluoroalkylamines and carboxyalkylbetaines and alkylsulfobetaines derived therefrom, and mixtures containing the new fluoroalkylamines and mixtures containing the new fluorobetaines are described. The saturated fluoroalkylamines conform to the formula below in which n is an integer from 3 to 17 and R1 and R2 are C1 to C4-alkyl, C1 to C4-hydroxyalkyl or hydrogen, with the proviso that only one of the two substituents R1 and R2 is hydrogen. The carboxyalkylbetaines and sulfobetaines and the mixtures thereof are highly effective products for reducing the surface tension of water/air systems and the interfacial tension of water/hydrocarbon systems.

公开(公告)号：CA1276165C

公开(公告)日：1990-11-13

申请号：CA517160

申请日：1986-08-29

Applicant: HOECHST AG

Inventor： BATHELT HEINRICH ,  EHRL WINFRIED ,  WEHOWSKY FRANK ,  KLEBER ROLF ,  LOTZ WERNER ,  GLENZ WOLFGANG ,  HERDT HUBERT ,  JACKEL LOTHAR ,  MAST JAN-HILBERT ,  HINTERMEIER KARL ,  MUELLER MANFRED

IPC: C09K3/18 ,  B27K3/38 ,  C07C67/00 ,  C07C239/00 ,  C07C271/06 ,  C07C271/28 ,  C08G65/32 ,  C09K3/00 ,  C14C9/00 ,  D06M13/02 ,  D06M13/224 ,  D06M13/322 ,  D06M13/342 ,  D06M13/345 ,  D06M13/425 ,  D06M13/428 ,  D06M13/463 ,  D06M101/00 ,  D06M101/02 ,  D06M101/10 ,  D06M101/12 ,  C14C11/00

Abstract: of the disclosure The novel urethanes correspond to the formula I below in which a denotes a number from 5 to 17 and b denotes a number from 1 to 7. These urethanes are prepared by reacting the corresponding perfluoroalkylethanol/epichlorohydrin adducts with toluelene diisocyanates. The novel aqueous dispersions are essentially composed of the novel urethanes, cationic or betaine emulsifiers and non-ionic emulsifiers, water-insoluble carboxylic and/or dicarboxylic acid esters and alkanediols or polyalkanediols which can be etherified on one or both sides, in water. The novel urethanes and the novel aqueous dispersions are used to impart an oleophobic and hydrophobic finish to textiles, leather and furs. They are also suitable for the treatment of unpainted timber, for example unpainted furniture.

公开(公告)号：AU591395B2

公开(公告)日：1989-11-30

申请号：AU6209586

申请日：1986-08-29

Applicant: HOECHST AG

Inventor： BATHELT HEINRICH ,  EHRL WINFRIED ,  WEHOWSKY FRANK ,  KLEBER ROLF ,  LOTZ WERNER ,  GLENZ WOLFGANG ,  HERDT HUBERT ,  JACKEL LOTHAR ,  MAST JAN-HILBERT ,  HINTERMEIER KARL ,  MULLER MANFRED

IPC: C09K3/18 ,  B27K3/38 ,  C07C67/00 ,  C07C239/00 ,  C07C271/06 ,  C07C271/28 ,  C08G65/32 ,  C09K3/00 ,  C14C9/00 ,  D06M13/02 ,  D06M13/224 ,  D06M13/322 ,  D06M13/342 ,  D06M13/345 ,  D06M13/425 ,  D06M13/428 ,  D06M13/463 ,  D06M101/00 ,  D06M101/02 ,  D06M101/10 ,  D06M101/12 ,  C07C125/073 ,  D06M13/40

Abstract: The novel urethanes correspond to the formula I below in which a denotes a number from 5 to 17 and b denotes a number from 1 to 7. These urethanes are prepared by reacting the corresponding perfluoroalkylethanol/epichlorohydrin adducts with toluelene diisocyanates. The novel aqueous dispersions are essentially composed of the novel urethanes, cationic or betaine emulsifiers and non-ionic emulsifiers, water-insoluble carboxylic and/or dicarboxylic acid esters and alkanediols or polyalkanediols which can be etherified on one or both sides, in water. The novel urethanes and the novel aqueous dispersions are used to impart an oleophobic and hydrophobic finish to textiles, leather and furs. They are also suitable for the treatment of unpainted timber, for example unpainted furniture.

公开(公告)号：DD272463A5

公开(公告)日：1989-10-11

申请号：DD31811988

申请日：1988-07-20

Applicant: HOECHST AG

Inventor： WEHOWSKY FRANK

IPC: C08G65/32 ,  C07D301/26 ,  C07D303/16 ,  C07D303/22 ,  C07D303/24 ,  C08G18/30 ,  C08G18/50 ,  C07D303/08

Abstract: Perfluoroalkyl-containing epoxides of the formula 1 in which Rf is a perfluoroalkyl-containing radical, X is halogen, a is 1 to 4 and b is 0 to 20, are prepared by reacting a fluoroalcohol/ epihalohydrin adduct of the formula 2 in which Rf, X, a and b have the meanings mentioned, with alkali metal hydroxide or alkaline earth metal hydroxide in the form of an aqueous solution in the presence of phase-transfer catalysts and at a pH of 9 to 12. The perfluoroalkyl-containing epoxides are those of the formula 3 in which Rf, X and a have the meanings mentioned and b is 1 to 20. The epoxides in question are advantageous monomers for the preparation of fluorine-containing epoxy resins and epoxy copolymers, which in turn are good finishing agents for textiles and leather.