Abstract:
The present invention relates to a rapidly curable, silicone-free release coating composition comprising (a) between about 50 and about 95 wt. % of a vinyl ether having the formula: C n H2n+1O-CH=CH2 , wherein n has a value of from 8 to 20, op- tionally containing a cationically polymerizable comonomer; (b) between abou t 5 and about 50 wt. % of a multifunctional vinyl ether monomer and (c) between about 0.1 and about 10 wt. % of an onium salt photoinitiator.
Abstract:
The present invention relates to a rapidly curable, silicone-free release coating composition comprising (a) between about 50 and about 95 wt. % of a vinyl ether having the formula: CnH2n+1 O-CH = CH2, wherein n has a value of from 8 to 20, optionally containing a cationically polymerizable comonomer; (b) between about 5 and about 50 wt. % of a multifunctional vinyl ether monomer and (c) between about 0.1 and about 10 wt.% of an onium salt photoinitiator.
Abstract:
A radiation curable composition is provided herein which comprises suitably about 50-90 parts, preferably about 60-80 parts, by weight, of a multifunctional acrylate monomer, suitably with 3-6 acrylate groups, preferably pentaerythritol triacrylate or trimethylolpropane triacrylate, about 10-50 parts by weight, preferably about 20-40 parts, by weight, of a divinyl ether monomer having both a hydrophobic backbone and an abrasion-resistant moiety, which is preferably the divinylether of cyclohexane dimethanol, and a radiation curing initiator, suitably a cationic initiator, and preferably, in combination with a free radical initiator.
Abstract:
2083848 9204383 PCTABS00011 This invention relates to a coating composition which can be cured by exposure to radiation energy in the presence of a cationic photoinitiator. The composition comprises a mixture of between about 1 and about 75 wt. % of a reactive vinyl or alk-1-enyl ether cyclocarbonate having formula (I) wherein R is hydrogen or lower alkyl; R' is C2 to C4 alkylene; n has a value of from 0 to 4 and n' has a value of from 1 to 4 and between about 99 and about 25 wt. % of a polymerizable compound containing an onium salt initiator which is normally insoluble in said polymerizable compound or a mixture thereof. The invention also relates to the use of the composition as a protective coating on a substrate. Preferably, the cyclocarbonate is prepared by a two-stage liquid phase process wherein an alk-2-enyl glycidyl ether having formula (II) wherein R is hydrogen or lower alkyl; R' is C2 to C4 alkylene, n has a value of from 1 to 4 and n' has a value of from 0 to 4, is catalytically isomerized to the corresponding alk-1-enyl glycidyl ether in the first-stage of the reaction and the reaction mixture of the first-stage, containing the isomerization catalyst is then contacted with carbon dioxide in the presence of a phase transfer catalyst under a pressure ranging from atmospheric to about 400 psig in the second stage of the reaction.
Abstract:
The present invention relates to a rapidly curable, silicone-free release coating composition comprising (a) between about 50 and about 95 wt. % of a vinyl ether having the formula: CnH2n+1O-CH=CH2, wherein n has a value of from 8 to 20, optionally containing a cationically polymerizable comonomer; (b) between about 5 and about 50 wt. % of a multifunctional vinyl ether monomer and (c) between about 0.1 and about 10 wt. % of an onium salt photoinitiator.
Abstract translation:本发明涉及可快速固化的不含硅酮的剥离涂料组合物,其包含(a)约50-约95wt。 具有下式的乙烯基醚:C n H 2n + 1 O-CH = CH 2,其中n的值为8至20,任选含有阳离子可聚合共聚单体; (b)约5至约50wt。 (c)约0.1-约10wt。%的多官能乙烯基醚单体和(c) %的鎓盐光引发剂。
Abstract:
A radiation curable release coating composition comprising, by weight, (a) 10-90 % of an acrylate-functional silicone resin, (b) 10-90 % of a vinylether monomer as reactive diluent therein, and (c) a photoinitiator.
Abstract:
This invention relates to a reactive diluent mixture employed in a free radical polymerization of film-forming monomers which comprises between about 25 and about 90 wt. % N-vinyl lactam containing 6 to 9 carbon atoms and between about 10 and about 75 wt. % of a non-cyclic vinyl amide having from 3 to 7 carbon atoms which is employed in a concentration of between about 10 and about 50 wt. % based on total film forming monomers.