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    VINYL ETHER FUNCTIONAL OLIGOMERS AND METHODS FOR MAKING AND USING SAME
    21.
    发明申请
    VINYL ETHER FUNCTIONAL OLIGOMERS AND METHODS FOR MAKING AND USING SAME 有权
    乙烯基功能低聚物及其制备和使用方法

    公开(公告)号：US20130184371A1

    公开(公告)日：2013-07-18

    申请号：US13825200

    申请日：2011-09-29

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C08F222/14

    CPC classification number: C08F222/14 ,  B33Y70/00 ,  C07C69/734 ,  C07C2601/14 ,  C08F216/125

    Abstract: The present invention includes vinyl ether functional oligomers and methods for their preparation, the method including alternating free radical copolymerization of a dialkyl maleate or dialkyl fumerate monomer with a multifunctional vinyl ether monomer in the presence of a solvent with a high chain transfer constant. Also within the scope of the invention are uses for the vinyl ether functional oligomers compositions of this invention, including radiation curable coatings, adhesives, printing inks and composites.

    Abstract translation: 本发明包括乙烯基醚官能低聚物及其制备方法，该方法包括在具有高链转移常数的溶剂存在下，将马来酸二烷基酯或富马酸二烷基酯单体与多官能乙烯基醚单体交替进行自由基共聚。 本发明的范围还包括本发明的乙烯基醚官能低聚物组合物的用途，包括可辐射固化涂料，粘合剂，印刷油墨和复合材料。

    SILOXANE MONOMERS AND OLIGOMERS
    22.
    发明申请
    SILOXANE MONOMERS AND OLIGOMERS 有权
    硅氧烷单体和低聚物

    公开(公告)号：US20090176958A1

    公开(公告)日：2009-07-09

    申请号：US12397377

    申请日：2009-03-04

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C08G77/08

    CPC classification number: C07F7/1892 ,  B33Y70/00 ,  C07F7/0874 ,  C08G77/04 ,  C08G77/045 ,  C08G77/38 ,  C09D183/06

    Abstract: A process for preparing a cationically photopolymerizable siloxane oligomer, that includes: combining a platinum group catalyst, a hydrosiloxane compound selected from and a vinyl or allyl compound comprising a cationically photopolymerizable functionality; and then contacting the product with oxygen in the presence of the catalyst to form the cationically photopolymerizable multifunctional siloxane oligomer. R1 and R3 are independently fluoroethyl, methyl or phenyl.

    Abstract translation: 一种制备阳离子光聚合的硅氧烷低聚物的方法，其包括：将铂族催化剂，选自以下的氢硅氧烷化合物和包含阳离子光聚合官能团的乙烯基或烯丙基化合物组合; 然后在催化剂存在下使产物与氧接触以形成阳离子可光聚合的多官能硅氧烷低聚物。 R1和R3独立地是氟乙基，甲基或苯基。

    Epoxidation of ricinic compounds using a phase-transfer catalyst
    24.
    发明授权
    Epoxidation of ricinic compounds using a phase-transfer catalyst 失效
    使用相转移催化剂对蓖麻毒素化合物进行环氧化

    公开(公告)号：US6051725A

    公开(公告)日：2000-04-18

    申请号：US220605

    申请日：1998-12-28

    Applicant: James V. Crivello ,  Srinivasan Chakrapani

    Inventor： James V. Crivello ,  Srinivasan Chakrapani

    IPC: C07D303/42 ,  C07D30/12

    CPC classification number: C07D301/12 ,  C07D303/42

    Abstract: Unsaturated or polyunsaturated, conjugated or nonconjugated hydrocarbons are reacted with an oxidizing agent including hydroperoxides and monopersulfate compounds in the presence of phase-transfer catalysts. Suitable hydrocarbons include ricinic compounds such as castor oil and dehydrated castor oil. The phase-transfer catalysts include novel tungsten peroxo complexes, such as quaternary ammonium tetrakis (diperoxotungsto) phosphates, and crown ethers. Other additives opionally utilized include pH buffers, alkaline compounds, and solvents.

    Abstract translation: 在相转移催化剂存在下，不饱和或多不饱和的共轭或非共轭烃与包括氢过氧化物和单过硫酸盐化合物在内的氧化剂反应。 合适的烃包括蓖麻油和蓖麻油等蓖麻油。 相转移催化剂包括新型钨过氧配合物，例如季铵四（二过氧钨）磷酸盐和冠醚。 所用的其他添加剂包括pH缓冲液，碱性化合物和溶剂。

    Process for the direct polymerization of allyl ethers, crotyl ethers and allyl alcohols
    25.
    发明授权
    Process for the direct polymerization of allyl ethers, crotyl ethers and allyl alcohols 失效
    烯丙基醚，巴豆酯和烯丙醇的直接聚合方法

    公开(公告)号：US5886115A

    公开(公告)日：1999-03-23

    申请号：US801952

    申请日：1997-02-18

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C08F4/06 ,  C08F4/26 ,  C08F4/42 ,  C08F4/70 ,  C08F16/08 ,  C08F16/20

    CPC classification number: C08F16/20 ,  C08F16/08 ,  C08F4/26

    Abstract: A process for the direct polymerization of allyl ethers, crotyl ethers and allyl alcohols is disclosed. The process comprises bringing into reactive proximity an allyl ether, crotyl ether or allyl alcohol compound; a transition metal carbonyl complex catalyst; and a cocatalyst bearing at least one silicon-hydrogen bond. Preferably, the catalyst is a cobalt carbonyl complex, and most preferably, the catalyst is dicobalt octacarbonyl. While virtually any compound bearing at least one silicon-hydrogen bond can be used as cocatalyst, phenylsilane is the most preferred. The process promotes the polymerization of allyl alcohols, mono-, di-, tri-, tetra- and multifunctional allyl and crotyl ether monomers, as well as terminal and pendent allyl and crotyl ether functional groups within oligomers and polymers.

    Abstract translation: 公开了烯丙基醚，巴豆基醚和烯丙醇的直接聚合方法。 该方法包括使烯丙基醚，巴豆基醚或烯丙醇化合物反应接近; 过渡金属羰基络合物催化剂; 和具有至少一个硅 - 氢键的助催化剂。 优选地，催化剂是羰基钴络合物，最优选地，催化剂是八羰基二钴。 尽管实际上任何具有至少一个硅氢键的化合物都可以用作助催化剂，但最优选苯基硅烷。 该方法促进烯丙醇，单 - ，二 - ，三 - ，四 - 和多官能烯丙基和巴豆基醚单体以及低聚物和聚合物中末端和侧链烯丙基和巴豆基醚官能团的聚合。

    Propenyl ether monomers for photopolymerization
    26.
    发明授权
    Propenyl ether monomers for photopolymerization 失效
    用于光聚合的丙烯基醚单体

    公开(公告)号：US5567858A

    公开(公告)日：1996-10-22

    申请号：US571200

    申请日：1995-12-12

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C08F2/46 ,  C08F16/32 ,  C07C43/11

    CPC classification number: C08F16/32

    Abstract: Propenyl ether monomers of formula VA(OCH.dbd.CHCH.sub.3).sub.nwherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

    Abstract translation: 式V A（OCH = CHCH 3）n的丙烯基醚单体，其中n是1至6的整数，A选自环醚，聚醚和烷烃。 当阳离子光引发剂暴露于光化辐射时，单体易于聚合形成可用于涂料，密封剂，清漆和粘合剂的聚（丙烯基醚）。 还公开了用于制备包含式V化合物与特定阳离子光引发剂的聚合物涂层的组合物，以及由烯丙基卤化物和容易获得的醇制备单体的方法。 该方法包括将所得烯丙基醚重排为丙烯基醚。

    Photocurable compositions of polyindane and 1,3-diisopropenylbenzene, and coating process
    27.
    发明授权
    Photocurable compositions of polyindane and 1,3-diisopropenylbenzene, and coating process 失效
    聚茚二酮和1,3-二异丙烯基苯的光固化组合物及涂布方法

    公开(公告)号：US5350604A

    公开(公告)日：1994-09-27

    申请号：US988218

    申请日：1992-12-09

    Applicant: James V. Crivello

    Inventor： James V. Crivello

    IPC: C08F12/34 ,  C08F277/00 ,  B05D1/26 ,  B05D3/12

    CPC classification number: C08F12/34 ,  C08F277/00

    Abstract: A process for cationically polymerizing 1,3-diisopropenylbenzene to produce a polymer which is predominantly a polyindane is disclosed. The resulting polyindanes are novel compounds useful as low dielectric constant coatings. Compositions containing 1,3-diisopropenylbenzene and cationic photoinitiators, and optionally containing a polyindane useful for preparing coatings, are disclosed as are processes for coating substrates using the compositions.

    Abstract translation: 公开了一种使1,3-二异丙烯基苯阳离子聚合以产生主要为聚茚的聚合物的方法。 所得聚茚二醇是可用作低介电常数涂层的新型化合物。 公开了包含1,3-二异丙烯基苯和阳离子光引发剂的组合物，以及任选地含有用于制备涂层的聚茚丹酮的组合物，是使用该组合物涂覆基材的方法。

    Preparation of epoxysilicon compounds using rhodium catalysts
    29.
    发明授权
    Preparation of epoxysilicon compounds using rhodium catalysts 失效
    使用铑催化剂制备环氧化合物

    公开(公告)号：US5169962A

    公开(公告)日：1992-12-08

    申请号：US583524

    申请日：1990-09-17

    Applicant: James V. Crivello ,  Ming-Xin Fan

    Inventor： James V. Crivello ,  Ming-Xin Fan

    IPC: B01J31/20 ,  B01J31/22 ,  B01J31/24 ,  B01J31/30 ,  C07B61/00 ,  C07F7/08 ,  C07F7/21 ,  C08G59/20 ,  C08G59/30 ,  C08G77/38 ,  C08L83/06

    CPC classification number: C08G77/38 ,  C07F7/0879 ,  C08L83/06

    Abstract: A method for making an epoxyfunctional organosilicon compound is provided, comprising the step of reacting at a temperature of from about 25.degree. to about 100.degree. C. a mixture comprising (A) an ethylenically unsaturated epoxide; (B) an organohydrogenpolysiloxane or organohydrogensilane; and (C) a rhodium complex catalyst selected from the group consisting of:(i) RhX.sub.3 (SR.sub.2).sub.3 ;(ii) RhX.sub.3 .multidot.xH.sub.2 O;(iii) [RhX(norbornadiene)].sub.2 ;(iv) RhX(CO)(R.sub.3 P).sub.3 ;(v) RhX(R.sub.3 P).sub.3 ; and(vi) [RhCl(cyclooctadiene)].sub.2 ;wherein X is a halogen atom, x is a number equal to 3 or 4, and R is an alkyl radical having from 1 to 8 inclusive carbon atoms, aryl, aralkyl, or alkaryl radical or the R.sub.3.sup.1 SiQ-- group in which Q represents a divalent aliphatic hydrocarbon radical having from 1 to 6 inclusive carbon atoms and R.sup.1 represents an alkyl radical having from 1 to 8 inclusive carbon atoms, aryl, aralkyl, or alkaryl radical or a (CH.sub.3).sub.3 Si-- radical.

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