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    Process for the preparation of polyaddition compounds
    23.
    发明申请
    Process for the preparation of polyaddition compounds 审中-公开
    制备加聚化合物的方法

    公开(公告)号：US20070142608A1

    公开(公告)日：2007-06-21

    申请号：US11638626

    申请日：2006-12-13

    Applicant: Hans Laas ,  Bernd Sojka ,  Michael Grahl ,  Josef Sanders ,  Wolfgang Fischer ,  Reinhard Halpaap

    Inventor： Hans Laas ,  Bernd Sojka ,  Michael Grahl ,  Josef Sanders ,  Wolfgang Fischer ,  Reinhard Halpaap

    IPC: C08G18/00

    CPC classification number: C08G18/798 ,  C08G18/0895 ,  C08G18/12 ,  C08G18/227 ,  C08G18/2825 ,  C08G18/4277 ,  C08G18/664 ,  C08G2150/20 ,  C08G18/42

    Abstract: The present invention relates to a novel process for the preparation of polyaddition products, to the products obtainable by this process and to their use as starting components in the production of polyurethane plastics. The process includes the reaction of A) polyisocyanates with uretdione groups having a mean isocyanate functionality of at least 2.0, optionally with the concomitant use of B) other diisocyanates and/or polyisocyanates, different from A, in an amount of up to 70 wt. %, based on the total weight of components A) and B), with C) polyols in the molecular weight range 62-2000 having a mean functionality of at least 2.0, or mixtures of polyols and optionally D) other isocyanate-reactive monofunctional compounds in an amount of up to 40 wt. %, based on the total weight of components C) and D). An equivalent ratio of isocyanate groups to isocyanate-reactive groups of 1.8:1 to 0.6:1 is maintained in the reactants, and the reaction is carried out in the presence of at least one bismuth-containing catalyst.

    Abstract translation: 本发明涉及一种制备加聚产物的新方法，可通过该方法获得的产品及其作为聚氨酯塑料生产中起始组分的用途。 该方法包括A）多异氰酸酯与平均异氰酸酯官能度至少为2.0的脲二酮基团的反应，任选地伴随使用B）与A不同的其它二异氰酸酯和/或多异氰酸酯，其量高达70wt。 基于组分A）和B）的总重量，C）分子量范围为62-2000的平均官能度至少为2.0的多元醇，或多元醇和任选的D）混合物的其它异氰酸酯反应性单官能化合物 其量可高达40wt。 ％，基于组分C）和D）的总重量。 在反应物中保持异氰酸酯基与异氰酸酯反应性基团的当量比为1.8:1至0.6:1，反应在至少一种含铋催化剂存在下进行。

    Tertiary amines having carbonate and urethane groups
    27.
    发明授权
    Tertiary amines having carbonate and urethane groups 失效
    具有碳酸酯和氨基甲酸酯基团的叔胺

    公开(公告)号：US5705672A

    公开(公告)日：1998-01-06

    申请号：US510830

    申请日：1995-08-03

    Applicant: Klaus Konig ,  Ulrich Liman ,  Josef Sanders

    Inventor： Klaus Konig ,  Ulrich Liman ,  Josef Sanders

    IPC: C07C271/20 ,  C08G18/18 ,  C08G71/02 ,  C07C271/00

    CPC classification number: C08G18/1841 ,  C07C271/20 ,  C08G2101/00

    Abstract: Tertiary amines having carbonate and urethane groups and optionally hydroxyl groups are produced by reacting a) a polyhydric alcohol and b) a primary-tertiary diamine with c) a carbonic acid derivative selected from the group consisting of optionally cyclic carbonates, urea, phosgene and bis-chlorocarbonates of alcohols of the same type as those used as component a). This reaction may be carried out in one or two steps. The tertiary amines produced by this process are useful as catalysts, which may optionally be incorporated into an isocyanate-reactive material, in the isocyanate addition reaction for the production of polyurethane plastics. These tertiary amines are particularly useful for the production of foam backed plastic films.

    Abstract translation: 具有碳酸酯和氨基甲酸酯基团和任选的羟基的叔胺通过使a）多元醇和b）伯 - 叔二胺与c）选自任选环状碳酸酯，脲，光气和双 与用作组分a）相同类型的醇的氯代碳酸酯。 该反应可以在一个或两个步骤中进行。 通过该方法生产的叔胺可用作用于生产聚氨酯塑料的异氰酸酯加成反应中的催化剂，其可任选地并入异氰酸酯反应性材料中。 这些叔胺特别可用于生产泡沫塑料膜。

    N, N-disubstituted oligourethanes and polyurethanes, a process for their preparation, and their use in the production of plastics
    29.
    发明授权
    N, N-disubstituted oligourethanes and polyurethanes, a process for their preparation, and their use in the production of plastics 失效
    N，N-二取代的低聚氨酯和聚氨酯，其制备方法及其在塑料生产中的应用

    公开(公告)号：US5099058A

    公开(公告)日：1992-03-24

    申请号：US501212

    申请日：1990-03-29

    Applicant: Josef Sanders ,  Dieter Dieterich

    Inventor： Josef Sanders ,  Dieter Dieterich

    IPC: C07C323/25 ,  C07C269/02 ,  C07C271/12 ,  C07C271/16 ,  C07C271/28 ,  C07C275/04 ,  C08G18/32 ,  C08G18/38 ,  C08G18/64

    CPC classification number: C07C271/28 ,  C07C269/02 ,  C07C271/12 ,  C08G18/3831

    Abstract: The present invention relates to N,N-disubstituted compounds containing urethane groups and terminal hydroxyl groups corresponding to the general formula ##STR1## wherein X is the residue of a strong memobasic or polybasic acid remaining after dissociation of the proton or protons of said acid or a hydroxyl group;Y is an n-functional hydrocarbon group having a molecular weight of from about 15 to about 8000 (preferably from about 300 to about 4000) and optionally interrupted by oxygen, sulfur, or silicon atoms, or by ester, carbonate, urea, N-monosubstituted urethane, or N,N-disubstituted urethane groups;1.sub.R hydrogen or a hydrocarbon group having a molecular weight of from about 15 to about 200;2.sub.R is the radical of an alkylating or arylating agent; and is an integer of from 2 to about 6.The present invention further relates to a process for preparing such compounds and to a method for using such compounds in the production of plastics.

    Abstract translation: 本发明涉及含有氨基甲酸酯基的N，N-二取代的化合物和对应于通式为“IMAGE”的末端羟基，其中X是在所述酸的质子或质子解离之后剩余的强碱性或多元酸的残基，或 羟基; Y是分子量为约15至约8000（优选约300至约4000）且任选被氧，硫或硅原子间隔的n官能烃基，或由酯，碳酸酯，脲，N- 单取代氨基甲酸酯或N，N-二取代的氨基甲酸酯基; 1R氢或分子量为约15至约200的烃基; 2R是烷基化或芳基化剂的基团; 并且为2至约6的整数。本发明还涉及一种制备这种化合物的方法以及在制备塑料中使用这些化合物的方法。

    Process for the preparation of aromatic polyamines
    30.
    发明授权
    Process for the preparation of aromatic polyamines 失效
    制备芳族聚酰胺的方法

    公开(公告)号：US5091582A

    公开(公告)日：1992-02-25

    申请号：US558947

    申请日：1990-07-27

    Applicant: Josef Sanders ,  Gerhard Grogler ,  Dieter Dieterich

    Inventor： Josef Sanders ,  Gerhard Grogler ,  Dieter Dieterich

    IPC: C08G65/32 ,  C08G18/40 ,  C08G18/46 ,  C08G18/50 ,  C08G18/61 ,  C08G18/63 ,  C08G65/322 ,  C08G65/333 ,  C08L63/00

    CPC classification number: C08G65/33389 ,  C08G18/40 ,  C08G18/4615 ,  C08G18/4623 ,  C08G18/5027 ,  C08G18/61 ,  C08G18/632 ,  C08G65/322 ,  C08L63/00

    Abstract: The present invention thus relates to new compounds containing aminophenoxy end groups corresponding to the formula ##STR1## wherein R.sub.1 denotes an n-valent group as obtained by the removal of hydroxyl groups from an n-valent polyhydroxyl compound having a molecular weight of about 400 to about 12,000, preferably 400 to about 6,000,R.sub.2 denotes an integer with a value from 2 to 8, preferably from 2 to 4.The present invention also relates to a process for the preparation of these compounds containing aminophenoxy end groups by reacting a polyhydroxyl compound with a halogenated nitrobenzene in the presence of an alkaline compound and subsequently hydrogenating the nitrophenoxy adducts obtained to form the corresponding aminophenoxy adducts.Lastly, the present invention relates to the use of the compounds containing aminophenoxy end groups as starting components for the production of polyurethane plastics by the isocyanate polyaddition process.

    Abstract translation: 因此，本发明涉及对应于式“IMAGE”的含有氨基苯氧基端基的新化合物，其中R1表示通过从分子量为约400的n价多羟基化合物除去羟基而获得的n价基团， 约12,000，优选400至约6,000，R 2表示2至8，优选2至4的整数。本发明还涉及一种通过使多羟基化合物反应制备含有氨基苯氧基端基的这些化合物的方法 与卤代硝基苯在碱性化合物的存在下，然后氢化所得的硝基苯氧基加成物形成相应的氨基苯氧基加合物。 最后，本发明涉及含有氨基苯氧基端基的化合物作为起始组分用于通过异氰酸酯加聚方法生产聚氨酯塑料的用途。

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