公开(公告)号：DE69636810D1

公开(公告)日：2007-02-15

申请号：DE69636810

申请日：1996-05-24

Applicant: KAO CORP

Inventor： SHONAKA MASAFUMI ,  HASEBE KEIKO ,  HAYASHI MASAHARU

IPC: C12N1/00 ,  C12N9/42 ,  B01D19/04 ,  C12N1/38 ,  C12P1/00 ,  C12P7/48 ,  C12P13/14 ,  C12R1/15 ,  C12R1/465 ,  C12R1/685

Abstract: An antifoaming agent for fermentation, which comprises (A) a reaction product obtained by the addition polymerization of 50 to 250 moles of ethylene oxide and propylene oxide (the molar ratio of ethylene oxide to propylene oxide = 1:1 to 1:4 ) to 1 mole of a mixture composed of an oil or fat and a polyhydric alcohol containing at least three hydroxyl groups; and (B) a fatty acid, an alcohol, a polyoxyalkylene polyhydric alcohol ether, a polyoxyalkylene alkyl ether, a polyoxyalkylene fatty acid ester, a polyoxyalkylene alkyl ether fatty acid ester and/or a polyoxyalkylene polymer. The above antifoaming agent has both foam-breaking effects and foam-inhibiting effects so that it has excellent antifoaming effects and does not adversely affect the fermentation production.

公开(公告)号：DE69826673T2

公开(公告)日：2005-11-10

申请号：DE69826673

申请日：1998-07-10

Applicant: KAO CORP

Inventor： SUZUKI TADAYUKI ,  HAYASHI MASAHARU ,  KURITA KAZUHIKO ,  HIOKI YUICHI

IPC: A01N25/04 ,  A01N25/30 ,  A01N31/02 ,  A01N31/14

Abstract: There are provided an effect enhancer for an agricultural chemical and an a chemical formulation which is not pharmaceutically harmful to various crops and can be safely used and which has an excellent effect enhancing function to various agricultural chemicals. The effect enhancer for the agricultural chemical comprises, as an effective component, a compound represented by the following formula (I): R-O[(EO)x(PO)y](EO)z-H, wherein EO is an oxyethylene group; PO is an oxypropylene group; R is a straight-chin or branched alkyl group or alkenyl group having 6 to 30 carbon atoms; x is a value of 1 to 30 on the average; y is a value of 1 to 30 on the average, and z is a value of 1 to 30 on the average. The agricultural chemical formulation composes the above-mentioned surfactant and a technical grade of active ingredient or an active compound for an agricultural chemical.

公开(公告)号：CA2214996C

公开(公告)日：2005-10-04

申请号：CA2214996

申请日：1996-03-14

Applicant: SUMITOMO RUBBER IND ,  FUJI LATEX CO ,  KAO CORP

Inventor： KANAMARU EIJI ,  NAKADE SHINICHI ,  OCHI ATSUKO ,  KUGA AKIHITO ,  TANAKA YASUYUKI ,  SEKIGUCHI KAZUHIRO ,  HAYASHI MASAHARU ,  SAKAKI TOSHIAKI

IPC: C08C1/04 ,  C08J5/02 ,  C11D3/386 ,  C12N9/48

Abstract: A method for producing a formed product of deproteinized natural rubber latex capable of reducing a content of an allergen in a natural rubber latex material to a level sufficient to keep the latex from being harmful to the human body without decreasing yields of the product and deteriorating formability of the latex. In the method, cleaning removal of a non-rubber content is carried out after each of protein decomposition, prevulcanization and forming. An aqueous alkali solution, ammonia, water containing free chlorine in an amount of 0.005 to 0.02 by weight or alcohol-water mixed liquid containing alcohol in an amount of to 80% by weight is used as cleaning liquid for the cleaning removal. The method is suitably applied to production of a natural rubber product such as a rubber glove, a condom, a catheter, a foam rubber material and the like.

公开(公告)号：AT280193T

公开(公告)日：2004-11-15

申请号：AT96906014

申请日：1996-03-14

Applicant: FUJI LATEX CO ,  SUMITOMO RUBBER IND ,  KAO CORP

Inventor： TANAKA YASUYUKI ,  NAKADE SHINICHI ,  OCHI ATSUKO ,  SAKAKI TOSHIAKI ,  HAYASHI MASAHARU ,  SEKIGUCHI KAZUHIRO ,  KUGA AKIHITO ,  KANAMARU EIJI

IPC: C08C1/04 ,  C08J3/24 ,  C08J5/00 ,  C08J5/02 ,  C08L7/02

Abstract: A method for producing a formed product of deproteinized natural rubber latex capable of reducing a content of an allergen in a natural rubber latex material to a level sufficient to keep the latex from being harmful to the human body without decreasing yields of the product and deteriorating formability of the latex. In the method, cleaning removal of a non-rubber content is carried out after each of protein decomposition, prevulcanization and forming. An aqueous alkali solution, ammonia, water containing free chlorine in an amount of 0.005 to 0.02% by weight or alcohol-water mixed liquid containing alcohol in an amount of 5 to 80% by weight is used as cleaning liquid for the cleaning removal. The method is suitably applied to production of a natural rubber product such as a rubber glove, a condom, a catheter, a foam rubber material and the like.

公开(公告)号：DE69910714D1

公开(公告)日：2003-10-02

申请号：DE69910714

申请日：1999-11-05

Applicant: KAO CORP

Inventor： HAYASHI MASAHARU ,  SUZUKI TADAYUKI ,  KAMEI MASATOSHI ,  HAYASHI TOSHIO ,  KURITA KAZUHIKO

IPC: A01N31/04 ,  A01N31/02

Abstract: The present invention provides a plant-activating agent which effects no chemical injury on plant and which makes an activity of plant improve efficiently. That is to say, the present invention provides a plant-activating composition comprising a mono-alcohol having 12 to 24 carbon atoms and one group selected from (i) a chelating agent, (ii) a surfactant and a chelating agent, (iii) a fertilizer component and a chelating agent and (iv) a surfactant, a fertilizer component and a chelating agent.

公开(公告)号：MY115377A

公开(公告)日：2003-05-31

申请号：MYPI9502716

申请日：1995-09-13

Applicant: SUMITOMO RUBBER IND ,  KAO CORP ,  FUJI LATEX CO ,  NITTO DENKO CORP

Inventor： TANAKA YASUYUKI ,  SAKAKI TOSHIAKI ,  KAWASAKI ATSUKO ,  HAYASHI MASAHARU ,  KANAMARU EIJI ,  SHIBATA KAZUHIKO

IPC: C08J3/09 ,  C08C1/04 ,  C08C19/08 ,  C08F8/50

Abstract: A DEPOLYMERIZED NATURAL RUBBER IS DISCLOSED, WHICH IS A LIQUID RUBBER HAVING A NUMBER-AVERAGE MOLECULAR WEIGHT OF FROM 2,000 TO 50,000 OBTAINED BY THE DEPOLYMERIZATION OF A DEPROTEINIZED NATURAL RUBBER. A PROCESS FOR THE PREPARATION OF A DEPOLYMERIZED NATURAL RUBBER IS ALSO DISCLOSED, WHICH COMPRISES DISSOLVING A DEPROTEINIZED NATURAL RUBBER INTO AN ORGANIC SOLVENT SO AS TO GIVE A CONCENTRATION OF FROM 1 TO 30BY WEIGHT AND THEN CARRYING OUT AIR OXIDATION OF THE RESULTING SOLUTION IN THE PRESENCE OF A METALLIC CATALYST. THE DEPOLYMERIZED NATURAL RUBBER CAN PROVIDE THE SAME PHYSICAL PROPERTIES AS ORDINARY VULCANIZED RUBBERS, EXHIBITS NO ODOR OR COLOR CHARACTERISTIC TO NATURAL RUBBERS AND CAUSES NO IMMEDIATE ALLERGY INDUCED BY PROTEIN.

公开(公告)号：AU716117B2

公开(公告)日：2000-02-17

申请号：AU7066296

申请日：1996-11-07

Applicant: KAO CORP ,  NITTO DENKO CORP ,  SUMITOMO RUBBER IND

Inventor： TANAKA YASUYUKI ,  SAKAKI TOSHIAKI ,  KAWASAKI ATSUKO ,  HAYASHI MASAHARU ,  KANAMARU EIJI ,  SHIBATA KAZUHIKO

IPC: C08C1/04 ,  C08C19/08 ,  C08F8/50 ,  C08J11/22 ,  C08F8/06

Abstract: Described is a process for the production of depolymerized natural rubber, which makes it possible to obtain, at high reaction efficiency, of depolymerized natural rubber in the liquid form and having a narrow molecular weight distribution; and also a process for the production of depolymerized natural rubber which is free from odor or coloring peculiar to natural rubber and is also free from the danger of immediate allergy derived from protein. The process according to the present invention comprises adding a carbonyl compound to a natural rubber latex, and then subjecting the resulting natural rubber to air oxidation in the presence of a radical forming agent or adding a carbonyl compound to the latex of deproteinized natural rubber and then subjecting the deproteinized natural rubber to air oxidation optionally in the presence of a radical forming agent.

公开(公告)号：ES2139249T3

公开(公告)日：2000-02-01

申请号：ES95937167

申请日：1995-11-22

Applicant: KAO CORP

Inventor： KURITA KAZUHIKO ,  HASEBE KEIKO ,  YAMAGUCHI KATSUHIKO ,  HAYASHI MASAHARU ,  HIOKI YUICHI

IPC: A01N25/10 ,  A01N25/30 ,  A01N33/12 ,  A01N37/02 ,  A01N37/06 ,  A01N65/06 ,  A01P3/00

Abstract: PCT No. PCT/JP95/02382 Sec. 371 Date May 22, 1997 Sec. 102(e) Date May 22, 1997 PCT Filed Nov. 22, 1995 PCT Pub. No. WO96/16539 PCT Pub. Date Jun. 6, 1996An adjuvant composition for agricultural chemicals comprising at least one sorbitan/fatty acid ester surfactant (A) and at least one surfactant (B) selected from the group consisting of resin acid surfactants and anionic oligomer or polymer type quaternary ammonium salt surfactants can be used for various crops in safety without causing injury thereof to the crops, and can enhance the efficacies of various agricultural chemicals.

公开(公告)号：DE69419839T2

公开(公告)日：1999-12-16

申请号：DE69419839

申请日：1994-05-10

Applicant: KAO CORP ,  SUMITOMO RUBBER IND

Inventor： TANAKA YASUYUKI ,  HIOKI YUICHI ,  HAYASHI MASAHARU ,  ICHIKAWA NAOYA ,  SAKAKI TOSHIAKI

IPC: C08C1/00 ,  C08C1/04 ,  C08C1/06

公开(公告)号：DE69507228T2

公开(公告)日：1999-06-17

申请号：DE69507228

申请日：1995-09-14

Applicant: SUMITOMO RUBBER IND ,  KAO CORP ,  FUJI LATEX CO ,  NITTO DENKO CORP

Inventor： TANAKA YASUYUKI ,  SAKAKI TOSHIAKI ,  KAWASAKI ATSUKO ,  HAYASHI MASAHARU ,  KANAMARU EIJI ,  SHIBATA KAZUHIKO

IPC: C08C1/04 ,  C08C19/08 ,  C08F8/50

Abstract: A depolymerized natural rubber is disclosed, which is a liquid rubber having a number-average molecular weight of from 2,000 to 50,000 obtained by the depolymerization of a deproteinized natural rubber. A process for the preparation of a depolymerized natural rubber is also disclosed, which comprises dissolving a deproteinized natural rubber into an organic solvent so as to give a concentration of from 1 to 30 % by weight and then carrying out air oxidation of the resulting solution in the presence of a metallic catalyst. The depolymerized natural rubber can provide the same physical properties as ordinary vulcanized rubbers, exhibits no odor or color characteristic to natural rubbers and causes no immediate allergy induced by protein.