公开(公告)号：JP2011173938A

公开(公告)日：2011-09-08

申请号：JP2010036852

申请日：2010-02-23

Applicant: Kao Corp ,  花王株式会社

Inventor： GOTO HIDEKI ,  MATSUI YOSHIAKI ,  SHIBA KENICHI ,  MURAI YUTAKA

IPC: C11D3/37 ,  C08F290/06

Abstract: PROBLEM TO BE SOLVED: To provide a method for stably producing a polymer builder which can be stably mixed to a liquid detergent containing a surfactant in high concentration and having excellent color and perfume of a solution.
SOLUTION: When the polymer builder for a detergent is produced by polymerizing a specified unsaturated carboxylic acid-based monomer (I) represented by general formula (I) and a specified allyl ether-based monomer (II) represented by general formula (II) in a liquid reaction medium in the presence of a polymerization initiator, 1 to 10 mol% persulfate to total number of moles of the monomer (I) and the monomer (II) is used as the polymerization initiator and a liquid reaction medium containing ≥15 wt.% lower alcohol in a total liquid reaction medium is used as the liquid reaction medium.
COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 解决问题的方法：提供稳定地制备可稳定地混合到含有高浓度表面活性剂的液体洗涤剂并具有优异的溶液颜色和香料的聚合物助洗剂的方法。 解决方案：当通过聚合由通式（I）表示的指定的不饱和羧酸基单体（I）和由通式（I）表示的指定的烯丙基醚类单体（II） II）在液体反应介质中，在聚合引发剂存在下，使用1至10mol％过硫酸酯与单体（I）和单体（II）的总摩尔数作为聚合引发剂和含有 使用总液体反应介质中的≥15重量％的低级醇作为液体反应介质。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2010285556A

公开(公告)日：2010-12-24

申请号：JP2009141134

申请日：2009-06-12

Applicant: Kao Corp ,  花王株式会社

Inventor： MATSUI YOSHIAKI ,  SHIBA KENICHI ,  GOTO HIDEKI

IPC: C11D3/37 ,  C08F216/20 ,  C08F220/04 ,  C08F290/06

Abstract: PROBLEM TO BE SOLVED: To provide a polymer builder for clothing detergent which can be stably blended into a liquid clothing detergent, exhibits excellent sludge dispersibility even in high hardness, and also has excellent hydrolysis resistance. SOLUTION: The polymer builder for a clothing detergent is composed of a polymer compound which has a structural unit (A) derived from a specified unsaturated carboxylic acid base monomer and a structural unit (B) originated from a specified unsaturated polyalkylene oxide base monomer, and in which the mass ratio of the structural unit (A) to the structure unit (B) is 1:99 to 29:71, and the proportion of the structural unit (A) and the structural unit (B) in the whole structural unit is ≥85 mass%, or is composed of a salt of the polymer compound. COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 待解决的问题：为了提供可稳定地混合到液体衣物洗涤剂中的衣物洗涤剂用聚合物助洗剂，即使在高硬度下也显示出优异的污泥分散性，并且还具有优异的耐水解性。 解决方案：用于衣物洗涤剂的聚合物助洗剂由具有由特定的不饱和羧酸基单体衍生的结构单元（A）和源自特定的不饱和聚环氧烷基的结构单元（B）的聚合物化合物组成 单体，结构单元（A）与结构单元（B）的质量比为1:99〜29:71，结构单元（A）和结构单元（B）的比例在 整个结构单元为≥85质量％，或由高分子化合物的盐组成。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2007204597A

公开(公告)日：2007-08-16

申请号：JP2006024910

申请日：2006-02-01

Applicant: Kao Corp ,  Nitto Boseki Co Ltd ,  日東紡績株式会社 ,  花王株式会社

Inventor： NAKADA YASUHITO ,  HASHIMOTO MITSUMASA ,  MIZU TOSHIHIKO ,  SHIBA KENICHI ,  MIYANAGA SEIICHI ,  NAKAMURA GENICHI

IPC: C08G75/22

Abstract: PROBLEM TO BE SOLVED: To provide a new diallylamine-based copolymer useful as a component of a treating agent for a rigid surface; to provide a method for producing the copolymer; and to provide the treating agent for the rigid surface containing the copolymer. SOLUTION: The diallylamine-based copolymer has a constituent unit derived from diallylamines, a constituent unit derived from an ethylenically unsaturated sulfonic acid compound and/or an ethylenically unsaturated carboxylic acid compound, and a constituent unit derived from sulfur dioxide. The method for producing the diallylamine-based copolymer involves copolymerizing monomers constituting each of the above constituent units in a polar solvent in the presence of a radical initiator. The treating agent for the rigid surface contains the diallylamine-based copolymer. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供可用作刚性表面处理剂的组分的新的二烯丙基胺基共聚物; 提供共聚物的制造方法; 并提供含有共聚物的刚性表面的处理剂。 解决方案：二烯丙基胺系共聚物具有来自二烯丙基胺的构成单元，来自烯键式不饱和磺酸化合物和/或烯键式不饱和羧酸化合物的构成单元和源自二氧化硫的构成单元。 二烯丙基胺系共聚物的制造方法包括在自由基引发剂的存在下，在极性溶剂中共聚构成上述各构成单元的单体。 用于刚性表面的处理剂含有二烯丙基胺类共聚物。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2005120202A

公开(公告)日：2005-05-12

申请号：JP2003355993

申请日：2003-10-16

Applicant: Kao Corp ,  花王株式会社

Inventor： MORII NORIYUKI ,  NAKAGAWA YOSUKE ,  TSUKUDA KAZUKUNI ,  SHIBA KENICHI

IPC: C11D3/37

Abstract: PROBLEM TO BE SOLVED: To provide a hard-surface treatment composition which is capable of imparting the drying accelerating effect and finishing improving effect to the hard surfaces of water-section facilities.
SOLUTION: The composition contains (b) water and (a) a copolymer containing a polymerization unit derived from a dicarboxylic acid-based monomer expressed by formula (I) (wherein, R
1 is A-B-X, but A is -O- or -NR
3 , R
3 is -H, -CH
3 or the like, B is -C
2 H
4 -, or -C
3 H
6 -, X is -NR
4 R
5 or the like, R
4 and R
5 are each -H, -CH
3 or the like) and containing a polymerization unit derived from an olefin-based monomer expressed by formula (II) (wherein, R
2 is a 4-12C alkyl group, a 6-12C aryl group or the like).
COPYRIGHT: (C)2005,JPO&NCIPI

Abstract translation: 要解决的问题：提供能够赋予水分设施的硬表面的干燥促进效果和整理改善效果的硬表面处理组合物。 组合物含有（b）水和（a）含有衍生自由式（I）表示的二羧酸类单体的聚合单元的共聚物（其中，R SP = 1 / 但是A为-O-或-NR 3 SP 3，R 3为-H，-CH 3 SB 3等，B为-C 2 H 4，或-C 3 SB 3，X是-NR SP 4， / SP> R 5 等，R 4 和R 5 分别为-H，-CH 3 或类似物），并且含有由式（II）表示的烯烃类单体衍生的聚合单元（式中，R 2 = 4-12C烷基，6-12元芳基或 喜欢）。 版权所有（C）2005，JPO＆NCIPI

公开(公告)号：JP2002302575A

公开(公告)日：2002-10-18

申请号：JP2001104231

申请日：2001-04-03

Applicant: KAO CORP

Inventor： SHIBA KENICHI ,  MIYANAGA SEIICHI

IPC: C08L23/02 ,  C08K3/00

Abstract: PROBLEM TO BE SOLVED: To provide a resin composition containing an inorganic solid uniformly dispersed in a synthetic resin, keeping the transparency of the resin and having excellent appearance such as surface smoothness and gloss. SOLUTION: The resin composition contains (A) 100 pts.wt. of a polyolefin polymer or copolymer containing at least one kind of olefin unit selected from ethylene unit and propylene unit as the polymer unit in an amount of >=50 mol%, (B) 0.1-10 pts.wt. of a polyether having a polymer unit of formula (I) (R is a 1-30C univalent hydrocarbon group; and p is >=10) and (C) 20-200 pts.wt. of an inorganic solid and further satisfies formula (II); 0

公开(公告)号：JP2011012150A

公开(公告)日：2011-01-20

申请号：JP2009156622

申请日：2009-07-01

Applicant: Kao Corp ,  花王株式会社

Inventor： SHIBA KENICHI ,  GOTO HIDEKI ,  MATSUI YOSHIAKI ,  MURAI YUTAKA ,  SHIMOKAWA YOSHIFUMI

IPC: C11D3/37 ,  C08F216/14

Abstract: PROBLEM TO BE SOLVED: To provide a method for stably producing a polymer builder capable of being stably blended even with a liquid detergent containing a high concentration of a surfactant and excellent in color and odor.SOLUTION: This method for producing the polymer builder for a detergent by performing the polymerization reaction of a specific unsaturated carboxylic acid-based monomer (I) such as acrylic acid, and a specific allyl ether-based monomer (II) such as a polyethylene glycol monoallyl ether, by using a liquid reaction medium in a reaction vessel uses a liquid containing a lower alcohol as the liquid reaction medium, and includes putting-in the monomers (I) and (II) of predetermined amounts in the reaction vessel in advance before the initiation of the polymerization, and then adding the remaining monomers (I) and (II) after the initiation of the polymerization to the reaction vessel.

Abstract translation: 要解决的问题：提供一种用于稳定地制备能够稳定地掺入含有高浓度表面活性剂的液体洗涤剂并且具有优异的颜色和气味的聚合物助洗剂的方法。溶液：用于生产聚合物助洗剂的方法 通过使用例如丙烯酸等特定的不饱和羧酸系单体（I）和特定的烯丙基醚类单体（II）如聚乙二醇单烯丙基醚进行聚合反应，通过使用液体反应介质 反应容器使用含有低级醇的液体作为液体反应介质，并且包括在聚合开始之前预先在反应容器中加入预定量的单体（I）和（II），然后加入剩余的 单体（I）和（II）在聚合开始后进入反应容器。

公开(公告)号：JP2007045991A

公开(公告)日：2007-02-22

申请号：JP2005234067

申请日：2005-08-12

Applicant: Kao Corp ,  花王株式会社

Inventor： MIZUKOSHI TAKAFUMI ,  SHIBA KENICHI ,  MORII NORIYUKI ,  NAKAGAWA YOSUKE

IPC: C11D3/22 ,  B08B17/02

Abstract: PROBLEM TO BE SOLVED: To provide a water draining property-giving agent for a hard surface, capable of giving good water draining properties to the hard surface of plastic, glass, metal, etc., especially, capable of giving sustainability of water drainage thereto, and to provide a detergent for the hard surface containing the same.
SOLUTION: This water draining property-giving agent for the hard surface contains a cationized polysaccharide having a weight-average molecular weight of 1,000,000 to 10,000,000. The detergent for the hard surface contains the water draining property-giving agent and a surfactant. A method for giving the sustainability of the water drainage to the hard surface comprises applying the water draining property-giving agent or the detergent to the hard surface.
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：为了提供用于硬表面的排水性能赋予剂，能够对塑料，玻璃，金属等的硬表面赋予良好的排水性，特别是能够赋予可持续性 对其进行排水，并为含有该洗涤剂的硬表面提供洗涤剂。 解决方案：硬表面的排水性赋予剂含有重均分子量为1,000,000〜10,000,000的阳离子化多糖。 用于硬表面的洗涤剂含有排水性能赋予剂和表面活性剂。 将排水的可持续性提供给硬表面的方法包括将排水性能赋予剂或洗涤剂施用于硬表面。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006143843A

公开(公告)日：2006-06-08

申请号：JP2004334407

申请日：2004-11-18

Applicant: Kao Corp ,  花王株式会社

Inventor： NAKAGAWA YOSUKE ,  MORII NORIYUKI ,  TSUKUDA KAZUKUNI ,  SHIBA KENICHI ,  MIZUKOSHI TAKAFUMI

IPC: C11D3/37

CPC classification number: C11D3/3769

Abstract: PROBLEM TO BE SOLVED: To provide a cleaning agent imparting good drying promotion effect to a hard surface of a place equipped with a water supply and having excellent liquid stability.
SOLUTION: The cleaning agent for hard surface contains (a) a polymer compound having a cationic group such as a cation-modified polyvinyl alcohol containing a specific constitutional unit, (b) a surfactant and (c) water.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供对配备有供水的场所的硬表面赋予良好的干燥促进效果并且具有优异的液体稳定性的清洗剂。 解决方案：用于硬表面的清洁剂包含（a）具有阳离子基团的聚合物化合物，例如含有特定结构单元的阳离子改性的聚乙烯醇，（b）表面活性剂和（c）水。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2003313600A

公开(公告)日：2003-11-06

申请号：JP2003043942

申请日：2003-02-21

Applicant: Kao Corp ,  花王株式会社

Inventor： AIHARA SHIN ,  KOMATSU YOSUKE ,  TSUKUDA KAZUKUNI ,  MIYANAGA SEIICHI ,  SHIBA KENICHI

IPC: C11D17/00 ,  C08F218/02 ,  C08F220/34 ,  C08F220/60 ,  C08F226/02 ,  C11D1/38 ,  C11D3/37 ,  C11D7/22

Abstract: PROBLEM TO BE SOLVED: To provide a stain-proof detergent for a hard surface, having excellent stain-proof effect and no corrosion problem of metallic materials.
SOLUTION: This stain-proof agent for the hard surface comprises a polymer having, in a molecule, a monomer unit A containing at least one selected from quarternary ammonium groups and an amino group and a monomer unit B represented by -SO
2 - at a specified ratio.
COPYRIGHT: (C)2004,JPO

Abstract translation: 要解决的问题：提供用于硬表面的防污洗涤剂，具有优异的防污效果，并且没有金属材料的腐蚀问题。 解决方案：用于硬表面的防污剂包括在分子中具有含有选自季铵基和氨基中的至少一种的单体单元A和由-SO 3表示的单体单元B的聚合物， SB> 2 。 版权所有（C）2004，JPO

公开(公告)号：JP2001158871A

公开(公告)日：2001-06-12

申请号：JP34277599

申请日：1999-12-02

Applicant: KAO CORP

Inventor： SHIBA KENICHI ,  MIYANAGA SEIICHI ,  ODA TAKU

IPC: C09G1/16 ,  C08G65/04 ,  C08L21/00 ,  C08L101/00 ,  C09C3/10 ,  C09D201/00

Abstract: PROBLEM TO BE SOLVED: To provide an inorganic solid surface-modifying agent which can efficiently largely improve the affinity of the inorganic solid with a medium in a small amount and gives a non-affected composition, even when a large amount of the inorganic solid is compounded. SOLUTION: This inorganic solid surface-modifying agent represented by the general formula (I): -(CHX-CHY-O)p-(Z)q- [X is H, a 1 to 30C hydrocarbon which may contain one or more carboxyl groups, hydroxyl groups, or ester groups, or the like, Y is a 6 to 30C hydrocarbon group which may contain one or more ester groups, or the like; Z is a polymer unit originated from a monomer which can be copolymerized with a polymerization unit represented by the formula: (CHX-CHY-O); (p)>=4, and (q)>=0], and the inorganic solid whose surface is at least partially coated with the surface-modifying agent, and a composition containing the surface-modifying agent and the inorganic solid.