公开(公告)号：JP2001072767A

公开(公告)日：2001-03-21

申请号：JP25387399

申请日：1999-09-08

Applicant: KAO CORP

Inventor： TAKIGUCHI HITOSHI ,  MIYANAGA SEIICHI ,  ODA TAKU ,  TSUNODA YUZO

IPC: C08K9/04 ,  C08G73/04 ,  C08L21/00 ,  C08L79/02 ,  C08L91/06 ,  C08L101/00 ,  C08L101/16 ,  C09D179/02

Abstract: PROBLEM TO BE SOLVED: To provide a surface modifier for an inorganic solid, which can markedly improve the affinity of an inorganic solid for a medium at good efficiency even when used in a small amount and can therefore give a composition less prone to being adversely affected even when it contains a large amount of an inorganic solid. SOLUTION: Provided are a surface modifier for an inorganic solid, comprising a poly(N-acylalkyleneimine) having polymer units represented by the formula, wherein R1 is H, a 1-50C hydrocarbon group, a group derived by replacing part or all of the hydrogen atoms of the hydrocarbon group by fluorine atoms, or a silicon-containing group; and a is 2 or 3, an organic solid at least part of whose surface is coated with the modifier, and a composition containing the modifier and an inorganic solid.

公开(公告)号：JP2001048771A

公开(公告)日：2001-02-20

申请号：JP22421699

申请日：1999-08-06

Applicant: KAO CORP

Inventor： TAKIGUCHI HITOSHI ,  MIYANAGA SEIICHI ,  ODA TAKU

IPC: A61K8/00 ,  A61K8/72 ,  A61K8/86 ,  A61Q1/00 ,  A61Q1/04 ,  A61Q1/10 ,  A61Q1/12 ,  A61Q19/00 ,  A61K7/48 ,  A61K7/00

Abstract: PROBLEM TO BE SOLVED: To obtain a cosmetic excellent in water oil and abrasion resistances and flexibility of a coating film, capable of preventing wetting, uneven spread and vanishing of cosmetic ingredients, good in makeup lasting quality, excellent in stability and useful for a foundation, etc., by including a specific polyether. SOLUTION: This cosmetic is obtained by including a polyether represented by the formula [X]m-[Y]n [X is represented by formula I; R1 to R3 are each H, methyl or ethyl; (a) is 1 or 2; Rf is a group in which a part or all of Hs in a 1-32C hydrocarbon are substituted by fluorines; Y is formula II or the like; R4 is H or a 1-32C hydrocarbon; R5 to R7 are each H, methyl or ethyl; b is 1 or 2; m/(m+n) is 0.2-1, with the proviso that (m+n) is >=10] in an amount of preferably 0.5-30 wt.%. The above polyether is obtained by polymerizing, e.g. 3-(1H,1H,5H-octafluoropentyloxy)-1,2-epoxypropane in the presence of a catalyst.

公开(公告)号：JP2001039845A

公开(公告)日：2001-02-13

申请号：JP21385899

申请日：1999-07-28

Applicant: KAO CORP

Inventor： TAKIGUCHI HITOSHI ,  MIYANAGA SEIICHI ,  ODA TAKU

IPC: A61K8/00 ,  A61K8/30 ,  A61K8/89 ,  A61Q5/06 ,  A61Q17/00 ,  A61Q19/00 ,  C08L83/06 ,  A61K7/40 ,  A61K7/00 ,  A61K7/48

Abstract: PROBLEM TO BE SOLVED: To obtain a cosmetic capable of compatibilizing the skin-care effect and the hair-care effect at a high level by including a specific polyether. SOLUTION: The objective cosmetic contains a polyether expressed by formula [X]m-[Y]n [the m X-groups are each a group expressed by formula I (R1 to R3 are each H, methyl or ethyl; G is a 1-20C bivalent saturated hydrocarbon group or a 6-30C arylene, R4 to R8 are each a 1-30C hydrocarbon group or a 1-200 Si siloxy or polysiloxy group; (a) is 1 or 2; (b) is 0 or 1; (c) is numbers having an average value of 1-500 or a single integer of 1-20), the n Y-groups are group of formula II, formula III or formula (CH2)f-O (R13 to R14, R17 and R18 are each H, methyl or ethyl; R16 is a 1-32C hydrocarbon group; R19 and R20 are each H, carboxyl or the like; (e) is 1 or 2; (f) is 2-6); (m) and (n) are numbers satisfying the formulas m/(m+n)=0.2 to 1 and m+n>=10]. The content of the polyether is preferably 0.001-30 wt.%.

公开(公告)号：JP2001011170A

公开(公告)日：2001-01-16

申请号：JP18133399

申请日：1999-06-28

Applicant: KAO CORP

Inventor： TAKIZAWA NOBUYUKI ,  MIYANAGA SEIICHI ,  ODA TAKU

IPC: C08G64/32

Abstract: PROBLEM TO BE SOLVED: To conveniently and economically obtain a high molecular weight polycarbonate useful in the fields of cosmetics, household articles and chemicals by copolymerizing a substituted epoxide with carbon dioxide in the presence of a specific rare earth metal compound and a reducing compound. SOLUTION: The objective polycarbonate (e.g. a compound of formula II, and the like.) is obtained by reacting (C) a substituted epoxide such as stearyl glycidyl ether with (D) carbon dioxide in the presence of (A) a rare earth metal compound [e.g. samarium tris(2,2,6,6-tetramethyl-3,5-heptanedionate), or the like] of formula I (wherein M is a rare earth element selected from Sc, Y and lanthanides; and L1 to L3 are each an oxygen-binding ligand) and (B) a reducing compound such as methylaluminoxane usually in an inactive solvent such as toluene preferably at -30 deg.C to 160 deg.C.

公开(公告)号：JPH10102089A

公开(公告)日：1998-04-21

申请号：JP25621596

申请日：1996-09-27

Applicant: KAO CORP

Inventor： ODA TAKU ,  KAWAMUKI HIROSHI

IPC: C11D1/83 ,  C08G65/24 ,  C08G65/32 ,  C11D3/37

Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition capable of improving an effect to a skin and a rinsing property without damaging primary cleaning and foaming properties by blending a hydrophilic polyether-based copolymer in a specific amount to a conventional detergent. SOLUTION: This liquid detergent composition for a hard surface contains (A) 1-70wt.% anionic surfactant, (B) 0.5-20wt.% nonionic surfactant and (C) 0.001-10wt.% hydrophilic polyether-based copolymer having a structural unit of the formula (R , R are each a 1-20C alkyl which may have hydroxyl; Y is a 1-10C alkylene which may have hydroxyl). Thus, a detergent composition of a practical value having an extremely mild effect to a skin and an excellent rinsing property, and not causing a roughness in the skin, can be expected.

公开(公告)号：JPH09235369A

公开(公告)日：1997-09-09

申请号：JP3961796

申请日：1996-02-27

Applicant: KAO CORP

Inventor： ODA TAKU ,  KAWAMUKI HIROSHI

IPC: C08G65/32 ,  C08G65/321 ,  C11D1/90 ,  C11D3/37

Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition containing a specific hydrophilic polyether polymer, excellent in adhesivity to flushing toilets, excellent in the prevention of loose stool adhesion due to the hydrophilic action, capable of maintaining the effect over a long period and having an excellent cleansing effect. SOLUTION: This cleanser composition contains a hydrophilic polyether polymer containing a structural unit of formula I [R , R are each a 1-20C (hydroxy)alkyl; Y is a 1-10C (hydroxy)alkylene[ ]e.g. the polymer having a weight-average mol.wt. of 500-5000000, concretely a hydroxyethylmethylbetaine- polyether polymer having a structure of formula II ((n) is 50-200)]. The polymer is preferably added to the composition so as to give a concentration of 0.5-100ppm, especially 1-50ppm, in used water such as flushing water.

公开(公告)号：JPH08291206A

公开(公告)日：1996-11-05

申请号：JP30572995

申请日：1995-11-24

Applicant: KAO CORP

Inventor： HORI NAOMI ,  ODA TAKU ,  TAYA TAKAKO ,  MITA KATSUMI

IPC: A61K8/00 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/06 ,  C08F20/34 ,  C08F20/52 ,  C08F220/26 ,  C08F220/28 ,  C08F220/34 ,  C08F220/56 ,  A61K7/06 ,  A61K7/11

Abstract: PURPOSE: To obtain a film-forming resin not causing stickiness even under high moisture, capable of retaining the set hair style for a long time, also excellent in hair washing and cleaning property and useful for hair cosmetic, etc., by using (meth)acrylamide-based monomer having a specific low molecular weight. CONSTITUTION: This resin is obtained by copolymerizing (A) 30-80wt.% (meth) acrylamide-based monomer of formula I (R is H or methyl; R and R are each H or a 4-12C alkyl) with (B) 2-50wt.% (meth)acrylamide-based monomer of formula II (R and R are each H of a 1-3C alkyl) and (C) 0-30wt.% (meth) acrylic ester-based monomer or (meth)acrylamide-based monomer of formula III [R is a 2-3C alkylene; R and R are each methyl or ethyl; (a) is 0 or 1] and (D) 0-40wt.% (meth)acrylic ester=based monomer of formula IV [R and R are each a 2-4C alkylene; R is H or a 1-10C alkyl or phenyl; (b) and (c) are each 0 or 50].

公开(公告)号：JPH07173395A

公开(公告)日：1995-07-11

申请号：JP32238693

申请日：1993-12-21

Applicant: KAO CORP

Inventor： YUI KOJI ,  ODA TAKU ,  YOSHIMATSU AKIRA

IPC: A61K8/02 ,  A61K8/89 ,  A61K8/91 ,  C08L83/04 ,  C08L83/10 ,  C09D183/04 ,  A61K7/00

Abstract: PURPOSE:To obtain a polyorganosiloxane gel composition which is useful for cosmetics, etc., readily rinsable and excellent in application feeling, stability, smoothness and lubricity by allowing an organopolysiloxane oil to gel under specific conditions. CONSTITUTION:The organopolysiloxane gel composition is prepared by gelatinizing an organopolysiloxane with a graft copolymer from poly(N- acylalkyleneimine) chains of formula I (R is a 1 to 22 C alkyl, phenyl; x is 2, 3) and organopolysiloxane chains having the structural units of formulas II and III (R , R are a 1 to 22 C alkyl, phenyl; R is formula IV).

公开(公告)号：JPH05156022A

公开(公告)日：1993-06-22

申请号：JP32315591

申请日：1991-12-06

Applicant: KAO CORP

Inventor： MAMADA AKIRA ,  KATSUKI JUNKO ,  ODA TAKU ,  YOSHIMATSU AKIRA

IPC: C08G77/385 ,  C08G77/06 ,  C08G77/22 ,  C08G77/28 ,  C08G77/388

Abstract: PURPOSE:To provide a new fluoroorganopolysiloxane having specific substituents in the organopolysiloxane chain, useful as a durable skin-protecting agent because of being excellent in the water repellency, oil repellency and film-forming property, and capable of being readily produced. CONSTITUTION:The objective polymer has substituents of formula I [R is 1-20C perfluoroalkyl; R , R are 1-10C hydrocarbon; R is H. CO(CH2)9 R ; R is H, group of formula II; (a) is 0-10; (b) is 0, 1]. This polymer is produced by reacting an amino-modified polysiloxane having substituents of formula III (R is H, R -NH2) at the end and/or side chains of an organopolysiloxane chain with a carboxylic acid (derivative) of formula IV preferably at 40-120 deg.C for 2-24hrs. Trifluorotoluene, etc., are preferable as the reaction solvent.

公开(公告)号：JPH0551461A

公开(公告)日：1993-03-02

申请号：JP21211691

申请日：1991-08-23

Applicant: KAO CORP

Inventor： KATSUKI JUNKO ,  MAMADA AKIRA ,  ODA TAKU ,  YOSHIMATSU AKIRA

IPC: C08G77/24 ,  C08G77/22 ,  C08G77/38 ,  C08G77/385

Abstract: PURPOSE:To obtain a new fluoroorganopolysiloxane useful as a skin-protecting agent having durability because of excellent water repellency and oil repellency. CONSTITUTION:The objective polymer containing a substituent group shown by formula I P is 1-12C perfluoroalkyl; Y is spacer group comprising main chain contain hetero atom; R is H or methyl) at the end and/or side chain of organopolysiloxane chain. The polymer is obtained by reacting a hydrosilyl- containing organopolysiloxane with a fluorine-containing unsaturated compound shown by formula II in the presence of a metal of the group VH of the periodic table or its metal compound (preferably chloroplatinic acid) preferably at 20-100 deg.C for 1-24 hours. A compound shown by formula III is preferable as the raw material organopolysiloxane. The raw material organopolysiloxane, for example, is obtained by subjecting octamethylcyclotetrasiloxane and tetramethylhydrogen tetrasiloxane to ring-opening equilibration polymerization.