公开(公告)号：JP2006037055A

公开(公告)日：2006-02-09

申请号：JP2004223504

申请日：2004-07-30

Applicant: Mitsui Chemicals Inc ,  三井化学株式会社

Inventor： TERADO YUJI ,  WADA MASARU

IPC: C08G69/44 ,  C08G63/60

Abstract: PROBLEM TO BE SOLVED: To provide a copolymerized polyhydroxycarboxylic acid having excellent heat-resistance, high molecular weight and high mechanical strength sufficient for the use as a substitute for general-purpose resins.
SOLUTION: The copolymerized polyhydroxycarboxylic acid is derived from (A) an aliphatic hydroxycarboxylic acid or its derivative, especially preferably a lactide, (B) a cyclic compound especially preferably phenylenediamine and (C) a cyclic compound especially preferably tolylene diisocyanate.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供具有优异的耐热性，高分子量和高机械强度的共聚的聚羟基羧酸，其足以用作通用树脂的替代物。 共聚聚羟基羧酸衍生自（A）脂族羟基羧酸或其衍生物，特别优选丙交酯，（B）环状化合物，特别优选苯二胺和（C）环状化合物，特别优选甲苯二异氰酸酯。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2002030047A

公开(公告)日：2002-01-29

申请号：JP2001219011

申请日：2001-07-19

Applicant: MITSUI CHEMICALS INC

Inventor： NAGATA TERUYUKI ,  KUSUDA CHIYUKI ,  WADA MASARU ,  SATO KENICHI

IPC: C07C209/60 ,  C07B61/00 ,  C07C211/55 ,  C07C211/56 ,  C07C213/02 ,  C07C215/82 ,  C07C217/92

Abstract: PROBLEM TO BE SOLVED: To provide an industrially improved method for obtaining an aromatic secondary amino compound under extremely mild conditions in good yield. SOLUTION: This method for producing the aromatic secondary amino compound comprises reacting cyclohexanone or a nuclear substitution product of the cyclohexanone with amines in the presence of a hydrogen transfer catalyst by adding or without adding an alkali metal compound and/or an alkaline earth metal compound as a cocatalyst in a sulfur-free polar solvent by using a nitro compound corresponding to the amines.

公开(公告)号：JP2001287467A

公开(公告)日：2001-10-16

申请号：JP2000104584

申请日：2000-04-06

Applicant: MITSUI CHEMICALS INC

Inventor： NISHIMURA TAKESHI ,  FURUYA MASAYUKI ,  TANAKA JUNYA ,  WADA MASARU

IPC: B41M5/333 ,  B41M5/30 ,  C07C311/21

Abstract: PROBLEM TO BE SOLVED: To provide the manufacturing method of pulverized electron accepting compound aqueous dispersing liquid of an electron accepting compound, which improves the whiteness of a color non-developing part before recording and is excellent in storage stability in a heat sensitive recording material including the electron accepting compound represented with general formula (1). SOLUTION: In the heat sensitive recording material including an electron accepting compound represented with general formula (1), the manufacturing of pulverized dispersing liquid of the electron accepting compound in executed in the presence of inactive gas, wherein X1 represents a hydrogen atom, a halogen atom an alkyl group, an alkoxy group or a hydroxyl group, Z1 represents an hydrogen atom or an alkyl group, R1 represents an alkyl group allowable with a substituent or an aryl group allowable with a substituent.

公开(公告)号：JP2000256291A

公开(公告)日：2000-09-19

申请号：JP6107299

申请日：1999-03-09

Applicant: MITSUI CHEMICALS INC

Inventor： NISHIMURA TAKESHI ,  TAKEDA FUMINORI ,  WADA MASARU

IPC: C07C227/18 ,  C07B61/00 ,  C07C229/60

Abstract: PROBLEM TO BE SOLVED: To industrially and advantageously produce the subject compound in high yield for a short time by reacting an aromatic nitro compound with an aldehyde compound and hydrogen in the presence of a noble metal catalyst in a solvent under specific conditions. SOLUTION: An aromatic nitro compound (e.g. 3-nitrobenzoic acid) is reacted with (B) an aldehyde compound [e.g. a 37% aqueous solution of formaldehyde (formalin)] in a molar amount of >=2 times, preferably 2-2.2 times based on the component A and (C) hydrogen in the presence of (D) a noble metal catalyst (e.g. a palladium/carbon supported catalyst) in an amount of 0.005-0.5 wt.%, preferably 0.025-0.1 wt.% expressed in terms of a metal atom and based on the raw material used in (E) a solvent (e.g. methanol) at 20-70 deg.C, preferably 40-60 deg.C preferably under an applied hydrogen pressure, e.g. atmospheric pressure to 10 kg/cm2 while successively feeding the components A and B to produce the objective compound (e.g. 3-dimethylaminobenzoic acid).

公开(公告)号：JP2000095740A

公开(公告)日：2000-04-04

申请号：JP27361998

申请日：1998-09-28

Applicant: MITSUI CHEMICALS INC

Inventor： NISHIMURA TAKESHI ,  TAKEDA FUMINORI ,  WADA MASARU ,  KANEMURA YOSHINOBU

IPC: C07C227/18 ,  C07C229/54 ,  C07C229/60

Abstract: PROBLEM TO BE SOLVED: To provide an industrially useful method for producing an N-alkyl substituted aromatic amino compound by which the reaction proceeds in high yield and in an ultrashort reactional time. SOLUTION: An aromatic amino compound is reacted with paraformaldehyde and hydrogen in an organic solvent or further a reducing reaction and a reducing alkylation reaction are carried out in the coexistence of the aromatic nitro compound and the paraformaldehyde in the presence of a noble metal catalyst in the organic solvent to thereby produce an N-alkyl substituted aromatic amino compound.

公开(公告)号：JPH11181074A

公开(公告)日：1999-07-06

申请号：JP34807297

申请日：1997-12-17

Applicant: MITSUI CHEMICALS INC

Inventor： SHIMIZU KOTARO ,  FURUYA MASAYUKI ,  WADA MASARU

IPC: C08G63/90 ,  C08L101/16

Abstract: PROBLEM TO BE SOLVED: To provide a method for isolating a formed polyhydroxycarboxylic acid in a satisfactory form with respect to quality and productivity. SOLUTION: A hydroxycarboxylic acid and/or its oligomer is treated with a haloiminium salt to give a solution of a polyhydroxycarboxylic acid. An organic solvent is removed under reduced pressure while dripping the solution into water to give a water-slurry solution, which is filtered, washed and dried to isolate the objective polyhydroxycarboxylic acid.

公开(公告)号：JPH11171845A

公开(公告)日：1999-06-29

申请号：JP33585797

申请日：1997-12-05

Applicant: MITSUI CHEMICALS INC

Inventor： HIDA JUNKO ,  NAGATOMO AKINORI ,  WADA MASARU

IPC: C11D1/10 ,  C07C231/02 ,  C07C233/47

Abstract: PROBLEM TO BE SOLVED: To obtain a new amino acid derivative with low irritancy and excellent formability, detergency, use feeling and safety, and useful as an ingredient of detergent compositions. SOLUTION: This new compound is an amino acid derivative of formula I (R1 is a 2-21C straight-chain or branched alkyl or alkenyl; R2 is a 1-4C straight-chain or branched alkyl; M1 and M2 are each H, an alkali metal, alkaline earth metal, ammonium or the like), e.g. N-lauroyl-N-carboxyethylalanine of formula II. The amino acid derivative of formula I is obtained, for example, by reaction of a fatty acid halide with an aminopolycarboxylic acid of formula III (M3 and M4 are each H, an alkali metal or alkaline earth metal). For example, the above-illustrated amino acid derivative of formula II is obtained by reaction of lauryl chloride with aminopolycarboxylic acid of formula IV. The other objective detergent composition contains pref. 0.1-99 wt.% of the amino acid derivative of formula I.

公开(公告)号：JPH11158267A

公开(公告)日：1999-06-15

申请号：JP32647597

申请日：1997-11-27

Applicant: MITSUI CHEMICALS INC

Inventor： NAGATOMO AKINORI ,  WADA MASARU ,  SUKEGAWA MAKOTO

IPC: C08J3/24 ,  C08G69/10 ,  C08G69/48 ,  C08G73/00 ,  C08G73/10 ,  C08L101/16

Abstract: PROBLEM TO BE SOLVED: To obtain a crosslinked polysuccinimide as a precursor for a crosslinked polyaspartic acid resin having both high water absorptivity and (bio)degradability in excellent productivity and operability by dissolving a polysuccinimide in a good solvent, adding a crosslinking agent to the solution to introduce pendant groups into the polymer, adding a dispersant to the solution to form a mixture in the state of a dispersion, and subjecting the suspension to a crosslinking reaction in the presence of a base. SOLUTION: The polysuccinimide used is the one having a weight-average molecular weight of 10,000 or above. The good solvent used is, for example, N,N-dimethylformamide. The crosslinking agent used is, for example a polyamine having at least one carboxyl group in the molecule (e.g. lysine or ornithine). Its amount of use is desirably 0.1-30 mol.% based on the monomer units of the main chain of the polysuccinimide. The dispersant used is exemplified by a poor solvent, for example, water or methanol. Its amount of use is 0.5-10 times as large as the weight of the good solvent used. The base used is NaOH or the like. The crosslinking temperature is -10 to 200 deg.C.

公开(公告)号：JPH11158266A

公开(公告)日：1999-06-15

申请号：JP32647397

申请日：1997-11-27

Applicant: MITSUI CHEMICALS INC

Inventor： NAGATOMO AKINORI ,  WADA MASARU ,  SUKEGAWA MAKOTO

IPC: C08J3/24 ,  C08G69/10 ,  C08G69/48 ,  C08G73/00 ,  C08G73/10 ,  C08L101/16

Abstract: PROBLEM TO BE SOLVED: To obtain a crosslinked polysuccinimide as a precursor for a crosslinked polyaspartic acid resin having both high water absorptivity and (bio)degradability in excellent productivity and good operability by simultaneously adding a dispersant and a crosslinking agent to a solution prepared by dissolving a polysuccinimide in a good solvent and subjecting the resultant mixture in the state of a dispersion to a crosslinking reaction. SOLUTION: The polysuccinimide used is the one having a weight-average molecular weight of 10,000 or above. The good solvent used is, for example, N,N-dimethylformamide. The dispersant used is a poor solvent, for example, water or methanol. Its amount of use is 0.5-10 times the weight of the good solvent used. The crosslinking agent is not particularly limited so far as it is a polyfunctional compound reactive with an imide ring. It is exemplified by a polyamine (e.g. hydrazine) or a protein-constituting amino acid (e.g. lysine). Its amount of use is desirably 0.1-30 mol.% based on the monomer units of the main chain of the polysuccinimide. The crosslinking temperature is -10 to 200 deg.C.

公开(公告)号：JPH1112240A

公开(公告)日：1999-01-19

申请号：JP16300797

申请日：1997-06-19

Applicant: MITSUI CHEMICALS INC

Inventor： KAMASHITA TOMOKO ,  WADA MASARU ,  NAGATA TERUYUKI

IPC: C11D1/10 ,  C07C231/02 ,  C07C233/47 ,  C07C233/49

Abstract: PROBLEM TO BE SOLVED: To obtain the subject new compound which is an amide type anionic surfactant, having hydroxyl group and carboxylic acid group and useful as an inexpensive and low-irritating detergent excellent in all the foaming, detergency and feeling of use. SOLUTION: This compound is represented by the formula (R is a 5-21C alkyl or a 5-21C alkenyl; M1 an M2 are each H, an alkali metal, an alkaline earth metal, ammonium, an alkylammonium or an alkenylammonium having 1-22 total number of carbon atoms, an alkyl-or an alkenyl-substituted pyridium having 1-18 total number of carbon atoms, a basic amino acid or a mixture thereof), e.g. N-octanoyl-N-hydroxyethyl-β-alanine. The compound represented by the formula is obtained by adding acrylonitrile to, e.g. monoethanolamine, hydrolyzing the cyano group, thereby providing N-hydroxyethyl-β-alanine and then reacting the resultant compound with a fatty acid chloride.