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公开(公告)号:CA1094979A
公开(公告)日:1981-02-03
申请号:CA276869
申请日:1977-04-25
Applicant: SOLVAY
Inventor: BOURGEOIS LOUIS
Abstract: L'invention concerne une cellule d'électrolyse à diaphragme, comprenant une chambre anodique et une chambre cathodique séparées par un diaphragme perméable, une conduite d'admission et une conduite d'extraction d'un électrolyte, un organe de réglage du débit d'électrolyte, un conduit d'évacuation d'un gaz produit dans la chambre anodique ou dans la chambre cathodique et une valve à ouverture réglable, montée dans le conduit d'évacuation du gaz. La cellule selon l'invention est caractérisée en ce qu'elle est pourvue en outre d'un organe de manoeuvre de la valve, comprenant un flotteur relié à la valve par un organe de couplage et logé dans une enceinte qui est en communication, à sa partie supérieure, avec le conduit d'évacuation du gaz, en amont de la valve et, à sa partie inférieure, avec la chambre raccordée au conduit de gaz, l'enceinte, le flotteur et l'organe de couplage étant agencés de manière telle que, d'une part, pendant le fonctionnement normal de la cellule, l'enceinte soit partiellement remplie d'électrolyte et la valve soit partiellement ouverte et, d'autre part, un déplacement progressif ascendant, respectivement descendant du flotteur dans l'enceinte provoque une fermeture progressive, respectivement une ouverture progressive de la valve. Cette cellule peut être utilisée pour l'électrolyse du chlorure de sodium en solution aqueuse de manière à assurer la constance du rapport entre la densité de courant et le débit de liquide à travers le diaphragme.
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公开(公告)号:PT64698B
公开(公告)日:1977-08-10
申请号:PT6469876
申请日:1976-01-15
Applicant: SOLVAY
Inventor: NICOLAS EDGARD , BOURGEOIS LOUIS
Abstract: A diaphragm cell for use in the electrolysis of an aqueous solution of alkali metal chloride. The cell is provided with a chamber divided by a diaphragm into an anode compartment having at least one anode therein and a cathode compartment having at least one cathode therein. The cathode has a catalytic surface different from the active surface of the anode. The cathode surface is made of a material which catalyses the decomposition of hypochlorite ions.
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公开(公告)号:AU3179771A
公开(公告)日:1973-02-01
申请号:AU3179771
申请日:1971-07-29
Applicant: SOLVAY
Inventor: DEGUELDRE LOUIS , GOBILLON YVES , CLERBOIS LUCIEN , BOURGEOIS LOUIS
Abstract: An electrode coating having the formula A2BO6, where A represents trivalent elements having anionic radius comprised between 0.50 and 0.73 Angstrom and where B represents hexavalent elements having an ionic radius comprised between 0.50 and 0.70.
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公开(公告)号:AU3179071A
公开(公告)日:1973-02-01
申请号:AU3179071
申请日:1971-07-29
Applicant: SOLVAY
Inventor: DEGUELDRE LOUIS , GOBILLON YVES , CLERBOIS LUCIEN , BOURGEOIS LOUIS
Abstract: 1358926 Electrocatalysts; coated electrodes SOLVAY ET CIE 29 July 1971 [29 July 1970] 35747/71 Headings B1E and B2E [Also in Divisions C7 and H1] Electrodes comprise a coating of catalytic material on a support made at least superficially of titanium or a titanium alloy, the catalytic material comprising one or more elements of the platinum group in the metallic and/or oxidised state and tellurium in the oxidised state. The tellurium may be partially replaced by molybdenum or tungsten and the catalytic material may also comprise chromium lead, bismuth, antimony, tin, cadmium, titanium, tantalum and/or niobium in the oxidised state. In the examples the compounds of the catalytic elements are applied in solution in an organic solvent to form a coating and the coated structure is heat-treated. The electrodes are tested in the electrolysis of brine with a flowing mercury cathode to produce chlorine. They can also be used in cathodic protection, water purification, other electrolytic processes and as fuel cell electrodes.
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公开(公告)号:AU3178871A
公开(公告)日:1973-02-01
申请号:AU3178871
申请日:1971-07-29
Applicant: SOLVAY
Inventor: BOURGEOIS LOUIS , DEGUELDRE LOUIS , GOBILLON YVES , CLERBOIS LUCIEN
Abstract: 1306057 Electrode for sodium chloride cell SOLVAY ET CIE 29 July 1971 [29 July 1970] 35745/71 Heading C7B [Also in Divisions C1 and H1] An anodic surface in the electrolysis of NaCl comprises a new compound of the formula Rh 2 Te O 6 which exhibits an electrical conductivity of 10 -4 (ohm, cm) -1
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公开(公告)号:NO306773B1
公开(公告)日:1999-12-20
申请号:NO930845
申请日:1993-03-08
Applicant: SOLVAY
Inventor: BOURGEOIS LOUIS
Abstract: Process for the manufacture of sodium hydroxide, according to which an electrodialysis cell is used, water or an aqueous sodium hydroxide solution (10, 10') is introduced into a chamber (6, 6') of the cell, defined between a cationic membrane (2, 2') and an anionic face (8, 8') of a bipolar membrane (3, 3'), an aqueous sodium carbonate solution (11, 11') is introduced into a chamber (7, 7') defined between a cationic face (9, 9') of the bipolar membrane (3, 3') and another cationic membrane (2', 2''), an alkaline pH is maintained in the chamber (7, 7') which is supplied with the sodium carbonate solution (11, 11') and an aqueous sodium hydroxide solution (12, 12') is drawn off from the chamber (6, 6') containing the anionic face (8, 8') of the bipolar membrane (3, 3').
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公开(公告)号:NO180326C
公开(公告)日:1997-04-02
申请号:NO932432
申请日:1993-07-02
Applicant: SOLVAY
Inventor: BOURGEOIS LOUIS
Abstract: Process for the manufacture of an aqueous solution of sodium hydroxide by electrodialysis of an aqueous solution (15) of a sodium salt derived from an acid of pK lower than the pK of carbonic acid, obtained by circulating an aqueous solution of the said acid (14) and an aqueous solution of sodium carbonate (13) on either side of a cationic membrane (12).
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公开(公告)号:AT132836T
公开(公告)日:1996-01-15
申请号:AT93200530
申请日:1993-02-25
Applicant: SOLVAY
Inventor: BOURGEOIS LOUIS
Abstract: Process for the manufacture of sodium hydroxide, according to which an electrodialysis cell is used, water or an aqueous sodium hydroxide solution (10, 10') is introduced into a chamber (6, 6') of the cell, defined between a cationic membrane (2, 2') and an anionic face (8, 8') of a bipolar membrane (3, 3'), an aqueous sodium carbonate solution (11, 11') is introduced into a chamber (7, 7') defined between a cationic face (9, 9') of the bipolar membrane (3, 3') and another cationic membrane (2', 2''), an alkaline pH is maintained in the chamber (7, 7') which is supplied with the sodium carbonate solution (11, 11') and an aqueous sodium hydroxide solution (12, 12') is drawn off from the chamber (6, 6') containing the anionic face (8, 8') of the bipolar membrane (3, 3').
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公开(公告)号:HU210311B
公开(公告)日:1995-03-28
申请号:HU9301940
申请日:1993-07-02
Applicant: SOLVAY
Inventor: BOURGEOIS LOUIS
Abstract: Process for the manufacture of an aqueous solution of sodium hydroxide by electrodialysis of an aqueous solution (15) of a sodium salt derived from an acid of pK lower than the pK of carbonic acid, obtained by circulating an aqueous solution of the said acid (14) and an aqueous solution of sodium carbonate (13) on either side of a cationic membrane (12).
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公开(公告)号:SK67593A3
公开(公告)日:1994-01-12
申请号:SK67593
申请日:1993-06-28
Applicant: SOLVAY
Inventor: BOURGEOIS LOUIS
Abstract: Process for the manufacture of an aqueous solution of sodium hydroxide by electrodialysis of an aqueous solution (15) of a sodium salt derived from an acid of pK lower than the pK of carbonic acid, obtained by circulating an aqueous solution of the said acid (14) and an aqueous solution of sodium carbonate (13) on either side of a cationic membrane (12).
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