公开(公告)号：DK0490507T3

公开(公告)日：1995-03-20

申请号：DK91310737

申请日：1991-11-21

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08

Abstract: Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx (formula 1> where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP2O7.

公开(公告)号：BR9105300A

公开(公告)日：1992-08-18

申请号：BR9105300

申请日：1991-12-09

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  C07C67/40 ,  C07C69/06 ,  C07C69/14

Abstract: Disclosed is a process for making ethyl acetate which comprises reacting in a reaction zone ethyanol and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx(formula 1) where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein said catalyst contains crystalline TiP2O7.

公开(公告)号：NO914824L

公开(公告)日：1992-06-11

申请号：NO914824

申请日：1991-12-06

Applicant: STANDARD OIL CO OHIO

Inventor： LEMANSKI MICHAEL F ,  HAZEN JOSEPH B ,  BLUM PATRICIA R

IPC: B01J27/18 ,  B01J27/185 ,  C07B61/00 ,  C07C51/25 ,  C07C53/08 ,  B01J23/54

Abstract: Disclosed is making acetic acid by reacting in a reaction zone ethylene and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx (formula 1> where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein such catalyst contains crystalline TiP2O7.