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21.
公开(公告)号:GB2203446B
公开(公告)日:1991-03-27
申请号:GB8806036
申请日:1988-03-14
Applicant: STANDARD OIL CO OHIO
Inventor: MAZANEC TERRY J , CABLE THOMAS L
IPC: B01D53/32 , B01D71/02 , B01J4/04 , B01J8/00 , B01J12/00 , B01J19/00 , B01J19/24 , C01B3/36 , C01B3/38 , C01B13/02 , C01C3/02 , C01G45/00 , C01G49/00 , C01G51/00 , C25B3/23 , C25B5/00 , H01M8/12
Abstract: An electrocatalytic process is described for producing unsaturated hydrocarbon compounds from saturated hydrocarbon compounds. The process is conducted in an electrogenerative cell and generally comprises the steps of (A) providing a fuel cell comprising a solid electrolyte having a first surface coated with conductive metal, metal oxide or mixtures thereof capable of catalyzing the reduction of oxygen to oxygen ions, and a second surface coated with metal, metal oxide or mixtures thereof, the two conductive coatings being connected by an external circuit, (B) passing an oxygen-containing gas in contact with the first conductive coating while, (C) passing the saturated hydrocarbon compound-containing feed gas in contact with the second conductive coating, and (D) recovering unsaturated hydrocarbons. In a preferred embodiment, the conductive metal coating on the first and second surfaces comprises a silver-containing metal composition. In another preferred embodiment, the invention comprises a continuous process for the oxidative dehydrogenation of ethane to ethylene and acetylene while generating electricity in an electrogenerative reactor.
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公开(公告)号:ZA887472B
公开(公告)日:1989-06-28
申请号:ZA887472
申请日:1988-10-05
Applicant: STANDARD OIL CO OHIO
Inventor: JOHN G FRYE JR , MAZANEC TERRY J , TERRY J MAZANEC , CABLE THOMAS L , THOMAS L CABLE , FRYE JOHN G JR
Abstract: An electrocatalytic process is described for producing synthesis gas from light hydrocarbons such as methane or natural gas. The process generally comprises the steps of (A) providing an electrochemical cell comprising a solid electrolyte having a first surface coated with conductive metal, metal oxide or mixtures thereof capable of facilitating the reduction of oxygen to oxygen ions, and a second surface coated with conductive metal, metal oxide or mixtures thereof, provided that both coatings are stable at the operating temperatures, (B) heating the cell to a temperature of at least 1000 DEG C, (C) passing an oxygen-containing gas in contact with the first conductive coating, (D) passing methane, natural gas or other light hydrocarbons in contact with the second conductive coating, and (E) recovering synthesis gas.
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公开(公告)号:NO884430L
公开(公告)日:1989-04-06
申请号:NO884430
申请日:1988-10-05
Applicant: STANDARD OIL CO OHIO
Inventor: MAZANEC TERRY J , CABLE THOMAS L , FRYE JOHN G JR
Abstract: An electrocatalytic process is described for producing synthesis gas from light hydrocarbons such as methane or natural gas. The process generally comprises the steps of (A) providing an electrochemical cell comprising a solid electrolyte having a first surface coated with conductive metal, metal oxide or mixtures thereof capable of facilitating the reduction of oxygen to oxygen ions, and a second surface coated with conductive metal, metal oxide or mixtures thereof, provided that both coatings are stable at the operating temperatures, (B) heating the cell to a temperature of at least 1000 DEG C, (C) passing an oxygen-containing gas in contact with the first conductive coating, (D) passing methane, natural gas or other light hydrocarbons in contact with the second conductive coating, and (E) recovering synthesis gas.
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24.
公开(公告)号:GB2203446A
公开(公告)日:1988-10-19
申请号:GB8806036
申请日:1988-03-14
Applicant: STANDARD OIL CO OHIO
Inventor: MAZANEC TERRY J , CABLE THOMAS L
IPC: B01D53/32 , B01D71/02 , B01J4/04 , B01J8/00 , B01J12/00 , B01J19/00 , B01J19/24 , C01B3/36 , C01B3/38 , C01B13/02 , C01C3/02 , C01G45/00 , C01G49/00 , C01G51/00 , C25B3/23 , C25B5/00 , H01M8/12 , C07C5/32 , C25B3/02
Abstract: An electrocatalytic process is described for producing unsaturated hydrocarbon compounds from saturated hydrocarbon compounds. The process is conducted in an electrogenerative cell and generally comprises the steps of (A) providing a fuel cell comprising a solid electrolyte having a first surface coated with conductive metal, metal oxide or mixtures thereof capable of catalyzing the reduction of oxygen to oxygen ions, and a second surface coated with metal, metal oxide or mixtures thereof, the two conductive coatings being connected by an external circuit, (B) passing an oxygen-containing gas in contact with the first conductive coating while, (C) passing the saturated hydrocarbon compound-containing feed gas in contact with the second conductive coating, and (D) recovering unsaturated hydrocarbons. In a preferred embodiment, the conductive metal coating on the first and second surfaces comprises a silver-containing metal composition. In another preferred embodiment, the invention comprises a continuous process for the oxidative dehydrogenation of ethane to ethylene and acetylene while generating electricity in an electrogenerative reactor.
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公开(公告)号:AU3833197A
公开(公告)日:1999-04-01
申请号:AU3833197
申请日:1997-09-17
Applicant: STANDARD OIL CO OHIO
Inventor: MAZANEC TERRY J , CABLE THOMAS L
IPC: B01D71/02
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公开(公告)号:ES2100877T3
公开(公告)日:1997-07-01
申请号:ES90314083
申请日:1990-12-20
Applicant: STANDARD OIL CO OHIO
Inventor: CABLE THOMAS L , FRYE JOHN G JR , KLIEWER WAYNE R , MAZANEC TERRY J
IPC: B01D53/32 , B01D71/02 , B01J4/04 , B01J8/00 , B01J12/00 , B01J19/00 , B01J19/24 , B01J23/86 , C01B3/36 , C01B3/38 , C01B13/02 , C01C3/02 , C01G45/00 , C01G49/00 , C01G51/00 , C25B3/23 , C25B5/00 , H01M4/86 , H01M8/02 , H01M8/12 , H01M8/10 , C25B3/00 , C25B1/00
Abstract: An element for use in an electrochemical cell has a first zone for introducing an oxygen-containing gas and a second zone separated from first zone by the element, which has a membrane with first and second surfaces, conducts oxygen ions therebetween, and has a catalyst exposed to at least the first zone. The element may be used to separate oxygen.
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公开(公告)号:DE69030651D1
公开(公告)日:1997-06-12
申请号:DE69030651
申请日:1990-12-20
Applicant: STANDARD OIL CO OHIO
Inventor: CABLE THOMAS L , FRYE JOHN G , KLIEWER WAYNE R , MAZANEC TERRY J
IPC: B01D53/32 , B01D71/02 , B01J4/04 , B01J8/00 , B01J12/00 , B01J19/00 , B01J19/24 , B01J23/86 , C01B3/36 , C01B3/38 , C01B13/02 , C01C3/02 , C01G45/00 , C01G49/00 , C01G51/00 , C25B5/00 , H01M4/86 , H01M8/02 , H01M8/12 , H01M8/10 , C25B3/00 , C25B1/00
Abstract: An element for use in an electrochemical cell has a first zone for introducing an oxygen-containing gas and a second zone separated from first zone by the element, which has a membrane with first and second surfaces, conducts oxygen ions therebetween, and has a catalyst exposed to at least the first zone. The element may be used to separate oxygen.
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公开(公告)号:DE3854757T2
公开(公告)日:1996-04-25
申请号:DE3854757
申请日:1988-09-29
Applicant: STANDARD OIL CO OHIO
Inventor: CABLE THOMAS L , MAZANEC TERRY J , FRYE JOHN G
Abstract: An electrocatalytic process is described for producing synthesis gas from light hydrocarbons such as methane or natural gas. The process generally comprises the steps of (A) providing an electrochemical cell comprising a solid electrolyte having a first surface coated with conductive metal, metal oxide or mixtures thereof capable of facilitating the reduction of oxygen to oxygen ions, and a second surface coated with conductive metal, metal oxide or mixtures thereof, provided that both coatings are stable at the operating temperatures, (B) heating the cell to a temperature of at least 1000 DEG C, (C) passing an oxygen-containing gas in contact with the first conductive coating, (D) passing methane, natural gas or other light hydrocarbons in contact with the second conductive coating, and (E) recovering synthesis gas.
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公开(公告)号:CA2158607A1
公开(公告)日:1996-03-24
申请号:CA2158607
申请日:1995-09-19
Applicant: STANDARD OIL CO OHIO
Inventor: MAZANEC TERRY J , CABLE THOMAS L
IPC: B01D53/22 , B01D53/32 , B01D71/02 , B01J8/00 , B01J19/00 , B01J19/24 , C01B3/38 , C01B13/02 , C01G51/00 , C01G53/00 , C04B35/01
Abstract: The present invention relates to novel solid state mixed conductor membranes and their use for separating oxygen from oxygen-containing feeds at elevated temperatures. The membranes comprise a multicomponent metallic oxide of substantially cubic perovskite structure, stable in air over the temperature range of 25-950.degree.C, having no connected through porosity wherein the membrane is of a composition represented by the formula ¢A1-xA'x!¢Co1-y-zByB'z!O3-.delta., where A - Ca, Sr, Ba, and mixtures thereof; A' - La, Y, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, U, and mixtures thereof; B = Fe, Mn, Cr, V, Ti, and mixtures thereof; B' - Cu, Ni, and mixtures thereof; ?0.0001 ?0.0005 metals.
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公开(公告)号:NO905556L
公开(公告)日:1991-06-28
申请号:NO905556
申请日:1990-12-21
Applicant: STANDARD OIL CO OHIO
Inventor: MAZANEC TERRY J , CABLE THOMAS L , FRYE JOHN G JR , KLIEWER WAYNE R
IPC: B01D53/32 , B01D71/02 , B01J4/04 , B01J8/00 , B01J12/00 , B01J19/00 , B01J19/24 , B01J23/86 , C01B3/36 , C01B3/38 , C01B13/02 , C01C3/02 , C01G45/00 , C01G49/00 , C01G51/00 , C25B3/23 , C25B5/00 , H01M4/86 , H01M8/02 , H01M8/12 , C25B13/04
Abstract: An element for use in an electrochemical cell has a first zone for introducing an oxygen-containing gas and a second zone separated from first zone by the element, which has a membrane with first and second surfaces, conducts oxygen ions therebetween, and has a catalyst exposed to at least the first zone. The element may be used to separate oxygen.
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