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21.发明授权ADDITION POLYMERIZATION CATALYSTS COMPRISING REDUCED OXIDATION STATE METAL COMPLEXES 无效用于加成聚合催化剂，其金属在还原的氧化络合物化合物含有
公开(公告)号：EP0632819B1
公开(公告)日：1998-09-02
申请号：EP93907617.0
申请日：1993-03-19
Applicant: THE DOW CHEMICAL COMPANY
Inventor： ROSEN, Robert, K. , NICKIAS, Peter, N. , DEVORE, David, D. , STEVENS, James, C. , TIMMERS, Francis, J.
CPC classification number: C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y10S526/943 , C08F4/65922
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公开(公告)号：EP0608369B1
公开(公告)日：1997-05-28
申请号：EP92922757.7
申请日：1992-10-15
Applicant: THE DOW CHEMICAL COMPANY
Inventor： LAI, Shih-Yaw , WILSON, John, R. , KNIGHT, Georges, W. , STEVENS, James, C.
CPC classification number: C08G83/003 , B29C47/00 , B29C47/0004 , B29C47/0009 , B29C47/02 , B29K2995/0022 , B32B27/08 , B32B27/322 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/00 , C08F110/02 , C08F210/16 , C08J5/18 , C08J2303/08 , C08J2323/08 , C08L23/02 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L23/16 , C08L2205/02 , C08L2314/06 , Y10S526/943 , Y10T428/2913 , Y10T442/30 , Y10T442/60 , C08L2666/04 , C08F2500/08 , C08F2500/09 , C08F2500/11 , C08F2500/12 , C08F2500/05 , C08F2500/07 , C08F2500/03 , C08F2500/19 , C08F2500/17 , C08F210/14 , C08F2500/26
Abstract: Elastic substantially linear olefin polymers are disclosed which have processability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE). The polymers have processing indices (PI's) less than or equal to 70 percent of those of a comparative linear olefin polymer and a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a traditional linear olefin polymer at about the same I2 and Mw?Mn. The novel polymers can also have from 0.01 to 3 long chain branches/1000 carbons along the polymer backbone and have higher low/zero shear viscosity and lower high shear viscosity than comparative linear olefin polymers. The novel polymers can also be characterized as having a melt flow ratio, I10/I2, » 5.63, a molecular weight distribution, Mw/Mn, defined by the equation: Mw/Mn « (I10/I2) - 4.63, and a critical shear stress at onset of gross melt fracture greater than 4 x 10?6¿ dyne/cm2.
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23.发明授权SULFONATED SUBSTANTIALLY RANDOM INTERPOLYMERS, BLENDS THEREWITH AND ARTICLES MADE THEREFROM 有权这一点，其对象MADE磺化ALMOST统计INTER聚合物混合工
公开(公告)号：EP1045882B1
公开(公告)日：2002-12-04
申请号：EP98953845.9
申请日：1998-10-21
Applicant: THE DOW CHEMICAL COMPANY
Inventor： CHEUNG, Yunwa, W. , HAHN, Stephen, F. , STEVENS, James, C. , TIMMERS, Francis, J. , SCHMIDT, Gregory, F. , HO, Thoi, H. , TERBRUEGGEN, Robert, H.
IPC: C08L25/00 , C08L23/00 , C08F8/36 , C08F210/00 , C08F212/00
CPC classification number: F16F9/48 , C08F8/36 , C08F8/44 , C08F212/00 , C08F2800/10 , C08F2800/20 , C08F2810/50 , C08L23/00 , C08L23/02 , C08L23/08 , C08L23/0815 , C08L23/0838 , C08L23/0876 , C08L23/32 , C08L23/34 , C08L25/18 , C08L77/00 , C08L2205/08 , F16F9/0209 , C08L2666/04 , C08L2666/20 , C08L2666/02 , C08F210/02 , C08F212/08
Abstract: The present invention pertains to sulfonated substantially random interpolymers made from monomer components comprising from 1 to 65 mole percent of (a) at least one vinyl or vinylidene aromatic monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinylidene monomer, or (c) a combination of at least one vinyl or vinylidene aromatic monomer and at least one hindered aliphatic or cycloaliphatic vinylidene monomer, and from 35 to 99 mole percent of at least one aliphatic α-olefin having from 2 to 20 carbon atoms; and optionally, from 0 to 20 mole percent of a diene containing from 4 to 20 carbon atoms; wherein the sufonated interpolymer contains at least one mer (or moiety) of a group represented by the formula -SO3-M where M is hydrogen or a group 1, 7 or 12 metal in ionic form or combination thereof. The present invention also pertains to blends of these polymers with polyamides and polyolefins. These blends are useful as materials which can be formed into a wide variety of plastic articles which take advantage of the combination of toughness, heat resistance, and solvent resistance. The present invention also pertains to articles prepared from substantially random interpolymers which are surface sulfonated.
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24.发明授权SUBSTITUTED INDENYL CONTAINING METAL COMPLEXES AND OLEFIN POLYMERIZATION PROCESS 失效取代茚含铬金属络合物和OLEFINPOLYMERISIERUNGSVERFAHREN。
公开(公告)号：EP0874860B1
公开(公告)日：2002-11-13
申请号：EP96936227.6
申请日：1996-10-03
Applicant: THE DOW CHEMICAL COMPANY
Inventor： NICKIAS, Peter, N. , MCADON, Mark, H. , PATTON, Jasson, T. , FRIEDRICHSEN, Bernard, P. , SOTO, Jorge , STEVENS, James, C. , VANDERLENDE, Daniel, D.
CPC classification number: C07F17/00 , C08F4/65908 , C08F4/6592 , C08F10/00
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25.发明授权
公开(公告)号：EP0914353B1
公开(公告)日：2002-09-04
申请号：EP97935016.2
申请日：1997-07-18
Applicant: THE DOW CHEMICAL COMPANY
Inventor： ROSEN, Robert, K. , STEVENS, James, C.
CPC classification number: B01J31/1805 , B01J31/14 , B01J31/2295 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/943 , C08F210/14
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Patent Agency Ranking
公开(公告)号：EP0782589B1
公开(公告)日：2001-06-20
申请号：EP95932349.4
申请日：1995-08-29
Applicant: THE DOW CHEMICAL COMPANY
Inventor： LAI, Shih-Yaw , WILSON, John, R. , KNIGHT, George, W. , STEVENS, James, C. , CHUM, Pak-Wing, S.
IPC: C08F210/16 , C08F4/603 , C08L23/04 , C08J5/18
CPC classification number: C08F10/00 , B29C47/00 , B29C47/0016 , B29C47/0021 , B29C47/0026 , C08F4/61908 , C08F4/61912 , C08F4/6192 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F110/02 , C08F210/16 , C08J5/18 , C08J2323/04 , C08L23/0815 , C08F2500/12 , C08F2500/09 , C08F2500/11 , C08F2500/19 , C08F2500/03 , C08F210/14
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公开(公告)号：EP1019415A1
公开(公告)日：2000-07-19
申请号：EP98947065.3
申请日：1998-09-16
Applicant: THE DOW CHEMICAL COMPANY
Inventor： CARNAHAN, Edmund, M. , CHEN, Eugene, Y. , JACOBSEN, Grant, B. , STEVENS, James, C.
CPC classification number: C08F10/00 , C07F5/068 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F210/16 , C08F4/6428 , C08F4/65912 , C08F4/642 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F210/08
Abstract: A catalyst activator particularly adapted for use in the activation of metal complexes of metals of Group 3-10 for polymerization of ethylenically unsaturated polymerizable monomers, especially olefins, comprising: a composition comprising a mixture of aluminum containing Lewis acids said mixture corresponding to the formula: [(-AlQ1-O-)z (-AlArf-O-)z'](Arfz''Al2Q16-z'') where Q1 independently each occurrence is selected from C¿1-20? alkyl; Ar?f¿ is a fluorinated aromatic hydrocarbyl moiety of from 6 to 30 carbon atoms; z is a number from 1 to 50, preferably from 1.5 to 40, more preferably from 2 to 30, and the moiety (-AlQ1-O-) is a cyclic or linear oligomer with a repeat unit of 2-30; z' is a number from 1 to 50, preferably from 1.5 to 40, more preferably from 2 to 30, and the moiety (-AlArf-O-) is a cyclic or linear oligomer with a repeat unit of 2-30; and z'' is a number from 0 to 6, and the moiety (Arfz''Al2Q16-z'') is either tri(fluoroarylaluminum), trialkylaluminum, or an adduct of tri(fluoroarylaluminum) with a sub-stoichiometric to super-stoichiometric amount of a trialkylaluminum.
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公开(公告)号：EP0775148B1
公开(公告)日：1999-08-25
申请号：EP95926280.9
申请日：1995-07-14
Applicant: THE DOW CHEMICAL COMPANY
Inventor： TIMMERS, Francis, J. , DEVORE, David, D. , STEVENS, James, C. , ROSEN, Robert, K. , PATTON, Jasson, T. , NEITHAMER, David, R.
CPC classification number: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F10/00 , Y10S526/901 , Y10S526/943
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公开(公告)号：EP0775148A1
公开(公告)日：1997-05-28
申请号：EP95926280.0
申请日：1995-07-14
Applicant: THE DOW CHEMICAL COMPANY
Inventor： TIMMERS, Francis, J. , DEVORE, David, D. , STEVENS, James, C. , ROSEN, Robert, K. , PATTON, Jasson, T. , NEITHAMER, David, R.
CPC classification number: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F10/00 , Y10S526/901 , Y10S526/943
Abstract: Biscyclopentadienyl, Group 4 transition metal complexes are formed by contacting a biscyclopentadienyl Group 4 metal halide, hydrocarbyl, hydrocarbyloxy or amide complex with a conjugated diene. Uniquely, the ansa-rac diastereomer is selectively isolated and may be reconverted to the halide form if desired. When combined with standard activating cocatalysts or activated with an activating technique, the complexes form catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.
Abstract translation: 双环戊二烯基，第4族过渡金属络合物通过使双环戊二烯基第4族金属卤化物，烃基，烃氧基或酰胺络合物与共轭二烯接触而形成。 独特地，ansa-rac非对映异构体被选择性地分离并且如果需要可以被重新转化为卤化物形式。 当与标准活化助催化剂结合或用活化技术活化时，络合物形成用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂。
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30.发明公开
公开(公告)号：EP0767795A1
公开(公告)日：1997-04-16
申请号：EP95923977.0
申请日：1995-06-19
Applicant: THE DOW CHEMICAL COMPANY
Inventor： DEVORE, David, D. , TIMMERS, Francis, J. , STEVENS, James, C. , ROSEN, Robert, K.
CPC classification number: C07F17/00 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F10/02 , Y10S526/943
Abstract: Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, π-bonded group wherein the metal is in the + 4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent anionic ligand group; catalytic derivatives of such complexes including novel zwiterionic complexes; and the use thereof as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.
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