公开(公告)号：WO2003040201A1

公开(公告)日：2003-05-15

申请号：PCT/US2002/014158

申请日：2002-05-06

Applicant: THE DOW CHEMICAL COMPANY ,  STEVENS, James, C. ,  VANDERLENDE, Daniel, D.

Inventor： STEVENS, James, C. ,  VANDERLENDE, Daniel, D.

IPC: C08F210/06

CPC classification number: C08J5/18 ,  B32B27/32 ,  C07B2200/11 ,  C07F7/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C08J2323/12 ,  C08J2323/14 ,  C08J2367/02 ,  C08L23/02 ,  C08L23/10 ,  C08L23/12 ,  C08L23/142 ,  C08L23/147 ,  C08L23/16 ,  C08L101/00 ,  C08L2205/02 ,  C08L2314/06 ,  C09K3/10 ,  C09K2200/0617 ,  C09K2200/062 ,  D01F6/06 ,  D01F6/30 ,  D01F6/46 ,  Y10T428/31909 ,  C08F4/659 ,  C08F4/65904 ,  C08F4/64144 ,  C08L2666/04 ,  C08L2666/06 ,  C08F2500/12 ,  C08F2500/20 ,  C08F2500/15 ,  C08F2500/24 ,  C08F2500/26 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2/001

Abstract: Unique copolymers comprising propylene, ethylene and/or one or more unsaturated comonomers are characterized as having: at least one, preferably more than one, of the following properties: (i) ?13¿C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt%, (iii) a skewness index, S¿ix?, greater than about -1.20, (iv) a DSC curve with a T¿me? that remains essentially the same and a T¿max? that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta catalyst. These polypropylene polymers are made using a nonmetallocene, metal-centered, heteroaryl ligand catalyst. These polymers can be blended with other polymers, and are useful in the manufacture of films, sheets, foams, fibers and molded articles.

Abstract translation: 包含丙烯，乙烯和/或一种或多种不饱和共聚单体的独特共聚物的特征在于具有以下特性中的至少一个，优选多于一个：（i）对应于约 14.6和约15.7ppm，当共聚物的共聚单体含量为至少约3重量％时，约等于强度的峰，（ii）B值大于约1.4，（iii）偏度指数S ，大于约-1.20，（iv）具有Tmeme的DSC曲线 这基本上保持不变，而T？max？ 随着共聚物中共聚单体的量的增加而降低，和（v）比用齐格勒 - 纳塔催化剂制备的可比共聚物报告更多的γ型晶体的X射线衍射图。 这些聚丙烯聚合物是使用非茂金属，以金属为中心的杂芳基配体催化剂制成的。 这些聚合物可以与其它聚合物共混，并且可用于制造薄膜，片材，泡沫，纤维和模制品。

公开(公告)号：WO1994021717A1

公开(公告)日：1994-09-29

申请号：PCT/US1994002361

申请日：1994-03-04

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  PARK, Chung, P. ,  STEVENS, James, C. ,  KNIGHT, George, W.

IPC: C08J09/00

CPC classification number: C08J9/14 ,  C08J2323/16 ,  Y10S526/943

Abstract: Disclosed is an ethylenic polymer foam structure comprising an ethylenic polymer material. The ethylenic polymer material contains a substantially linear ethylenic polymer having: a) a melt flow ratio, l10/l2 >/= 5.63; b) a molecular weight distribution, Mw/Mn, defined by the equation Mw/Mn

Abstract translation: 公开了一种含烯属聚合物材料的乙烯聚合物泡沫结构。 烯属聚合物材料包含基本上线性的乙烯性聚合物，其具有：a）熔体流动比，l10 / l2> = 5.63; b）由方程式Mw / Mn定义的分子量分布Mw / Mn，（10/12）-4.63; 和c）在具有大约相同的l2和Mw / Mn的线性烯烃聚合物的表面熔融断裂开始时，表面熔融断裂开始时的临界剪切速率比临界剪切速率大至少50％。 泡沫结构具有类似于由常规LLDPE形成的那些的韧性和弹性，而没有与这些结构相关联的差的尺寸稳定性和泡沫质量。 泡沫结构的泡沫质量与常规LDPE制成的泡沫质量相似，但具有增强的韧性和弹性。 进一步公开的是制造上述泡沫结构并使其成泡沫珠形式的方法。 进一步公开的是制造泡沫珠的制品的方法。

公开(公告)号：WO2002074817A2

公开(公告)日：2002-09-26

申请号：PCT/US2002/008121

申请日：2002-03-15

Applicant: THE DOW CHEMICAL COMPANY ,  STEVENS, James, C. ,  VANDERLENDE, Daniel, D.

Inventor： STEVENS, James, C. ,  VANDERLENDE, Daniel, D.

IPC: C08F10/00

CPC classification number: C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08L23/04 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2207/07 ,  C08L2314/02 ,  C08L2314/06 ,  Y02P20/52 ,  Y10S526/943 ,  C08F2/001 ,  C08F4/65904 ,  C08F2/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/01 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/02 ,  C08F2/00 ,  C08F2500/08 ,  C08F2500/05 ,  C08F2500/17 ,  C08F2500/26

Abstract: A polymerization process comprises contacting one or more olefinic comonomers in the presence of at least a high molecular weight catalyst and at least a low molecular weight catalyst in a single reactor; and effectuating the polymerization of the olefinic comonomers in the reactor to obtain an olefin polymer. Preferably, both catalysts have the ability to incorporate a substantially similar amount of comonomers in the olefin polymer. The polymers produced by the process may have a relatively higher level of long chain branching while maintaining a relatively narrow molecular weight distribution, i.e., MWD less than about 6. These interpolymers may exhibit processability similar to or better than LDPE but have physical properties similar to metallocene catalyzed polymers.

Abstract translation: 聚合方法包括在单个反应器中在至少一种高分子量催化剂和至少一种低分子量催化剂存在下使一种或多种烯属共聚单体接触; 并且在反应器中实现烯烃共聚单体的聚合以获得烯烃聚合物。 优选地，两种催化剂具有在烯烃聚合物中引入基本相似量的共聚单体的能力。 通过该方法生产的聚合物可以具有相对较高水平的长链支化，同时保持相对窄的分子量分布，即MWD小于约6.这些互聚物可以表现出与LDPE相似或优于LDPE的加工性能，但具有类似于 茂金属催化聚合物。

公开(公告)号：WO2002074816A2

公开(公告)日：2002-09-26

申请号：PCT/US2002/007919

申请日：2002-03-15

Applicant: THE DOW CHEMICAL COMPANY ,  DEGROOT, Alexander, W. ,  STEVENS, James, C. ,  DESJARDINS, Sylvie, Y. ,  WEINHOLD, Jeffrey ,  CARNAHAN, Edmund ,  GILLESPIE, David ,  VANDERLENDE, Daniel, D.

Inventor： DEGROOT, Alexander, W. ,  STEVENS, James, C. ,  DESJARDINS, Sylvie, Y. ,  WEINHOLD, Jeffrey ,  CARNAHAN, Edmund ,  GILLESPIE, David ,  VANDERLENDE, Daniel, D.

IPC: C08F10/00

CPC classification number: C08F210/16 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08L23/04 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2207/07 ,  C08L2314/02 ,  C08L2314/06 ,  Y02P20/52 ,  Y10S526/943 ,  C08F2/001 ,  C08F4/65904 ,  C08F2/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/01 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/02 ,  C08F2/00 ,  C08F2500/08 ,  C08F2500/05 ,  C08F2500/17 ,  C08F2500/26

Abstract: A polymer composition comprises: (a) a high molecular weight, branched component; and (b) a low molecular weight, branched component. Some polymer compositions are characterized by a substantial absent of amyl or methyl branches and a melt strength (MS) that satisfies the following relationship, formula (I), where x is greater than or equal to about 12.5 and y is greater than or equal to about 3. Some polymers are characterized by a melt strength (MS) that satisfies the following relationship, formula (II), where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. A process for making polymers is also disclosed.

Abstract translation: 聚合物组合物包含：（a）高分子量的支化组分; 和（b）低分子量支化组分。 一些聚合物组合物的特征在于基本上不存在戊基或甲基支链，以及满足以下关系式（I）的熔体强度（MS），其中x大于或等于约12.5，y大于或等于 一些聚合物的特征在于满足以下关系式（II）的熔体强度（MS），其中x大于或等于约3，y大于或等于约4.5，分子量分布 大于3.还公开了制备聚合物的方法。

公开(公告)号：WO1998003558A1

公开(公告)日：1998-01-29

申请号：PCT/US1997012649

申请日：1997-07-18

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  ROSEN, Robert, K. ,  STEVENS, James, C.

IPC: C08F04/642

CPC classification number: B01J31/1805 ,  B01J31/14 ,  B01J31/2295 ,  B01J2531/40 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  Y10S526/943 ,  C08F210/14

Abstract: Catalyst compositions that are highly tolerant of catalyst poisons comprising a catalytic derivative of a Group 4 metal complex and a Group 13 metal compound according to the formula R 2Me(NR 2), wherein R and R independently each occurrence is a hydrocarbyl, silyl, halocarbyl, halohydrocarbyl, hydrocarbyl-substituted silyl, halocarbyl-substituted silyl, or halohydrocarbyl-substituted silyl group, said R and R having from 1 to 30 carbon, silicon, or mixtures of carbon and silicon atoms, and Me is a Group 13 metal, the molar ratio of complex to Group 13 compound being from 1:0.1 to 1:100.

Abstract translation: 催化剂组合物高度耐受催化剂毒物，其包含第4族金属络合物的催化剂衍生物和根据式R 1 M 2（NR 2）的第13族金属化合物，其中R 1和R 2， 独立地，每次出现的是烃基，甲硅烷基，卤代烃基，卤代烃基，烃基取代的甲硅烷基，卤代烃基取代的甲硅烷基或卤代烃基取代的甲硅烷基，所述R 1和R 2具有1至30个碳，硅 ，或碳和硅原子的混合物，Me是13族金属，络合物与13族化合物的摩尔比为1:0.1至1:100。

公开(公告)号：WO1996000734A1

公开(公告)日：1996-01-11

申请号：PCT/US1995007776

申请日：1995-06-19

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  DEVORE, David, D. ,  TIMMERS, Francis, J. ,  STEVENS, James, C. ,  ROSEN, Robert, K.

IPC: C07F17/00

CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65916 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  Y10S526/943

Abstract: Novel Group 4 metal complexes containing one and only one cyclic delocalized, anionic, pi -bonded group wherein the metal is in the + 4 formal oxidation state and having a bridged ligand structure, also referred to as constrained geometry complexes and a conjugated diene divalent anionic ligand group; catalytic derivatives of such complexes including novel zwiterionic complexes; and the use thereof as catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers.

Abstract translation: 含有一个且仅一个环离域，阴离子，π键合基团的新型4族金属络合物，其中金属处于+ 4正式氧化态并具有桥连配体结构，也称为约束几何配合物和共轭二烯二价阴离子 配体基团 这种络合物的催化衍生物，包括新型的三嗪配合物; 以及其作为用于聚合烯烃，二烯烃和/或炔属不饱和单体的催化剂的用途。

公开(公告)号：WO1995027755A1

公开(公告)日：1995-10-19

申请号：PCT/US1995004314

申请日：1995-04-12

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  PARK, Chung, P. ,  CLINGERMAN, George, P. ,  TIMMERS, Francis, J. ,  STEVENS, James, C. ,  HENTON, David, E.

IPC: C08L25/08

CPC classification number: C08L23/06 ,  C08L23/00 ,  C08L23/04 ,  C08L25/02 ,  C08L25/06 ,  C08L2205/02 ,  C08L2666/04

Abstract: A polymer blend composition comprising: (a) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of an aliphatic alpha -olefin homopolymer or interpolymer, or an interpolymer of an alpha -olefin and a non-aromatic monomer interpolymerizable therewith; (b) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a homopolymer or interpolymer of monovinylidene aromatic monomers, or an interpolymer of monovinylidene aromatic monomer and a monomer interpolymerizable therewith other than an aliphatic alpha -olefin; and (c) from 0.5 to 99 percent by weight, based on the total weight of (a), (b), and (c), of a substantially random interpolymer comprising an alpha -olefin and a vinylidene aromatic monomer. An expandable composition, comprising such polymer blend composition and an expanding agent; a foamed composition obtained by subjecting such an expandable composition to a foaming process; an article of manufacture molded from such a polymer blend composition; and a method of packaging using such a polymer blend composition.

Abstract translation: 一种聚合物共混物组合物，其包含：（a）基于（a），（b）和（c）的脂肪族α-烯烃均聚物或互聚物的总重量的0.5〜99重量％ 可与其共聚的α-烯烃和非芳族单体; （b）基于单亚乙烯基芳族单体的均聚物或互聚物或单亚乙烯基芳族单体和单体的互聚物（a），（b）和（c））的总重量为0.5-99重量％ 除脂肪族α-烯烃以外可与其进行聚合; 和（c）基于包含α-烯烃和亚乙烯基芳族单体的基本上无规共聚体的（a），（b）和（c））的总重量的0.5至99重量％。 包含这种聚合物共混物组合物和膨胀剂的可发性组合物; 通过将这样的可发性组合物进行发泡处理获得的发泡组合物; 由这种聚合物共混组合物模制的制品; 以及使用这种聚合物共混组合物的包装方法。

公开(公告)号：WO1995000526A1

公开(公告)日：1995-01-05

申请号：PCT/US1994006834

申请日：1994-06-16

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  DEVORE, David, D. ,  CRAWFORD, Lenore, H. ,  STEVENS, James, C. ,  TIMMERS, Francis, J. ,  MUSSELL, Robert, D. ,  WILSON, David, R. ,  ROSEN, Robert, K.

IPC: C07F17/00

CPC classification number: C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/02 ,  C08F210/16 ,  C08F210/18 ,  Y10S526/901 ,  Y10S526/905 ,  Y10S526/943 ,  C08F212/08 ,  C08F2500/12 ,  C08F210/14 ,  C08F210/06 ,  C08F2500/17 ,  C08F236/20 ,  C08F2500/25

Abstract: Novel titanium or zirconium complexes containing one and only one cyclic delocalized, anionic, pi -bonded, group, said complexes corresponding to formula (I), wherein: M is titanium or zirconium in the +2 formal oxidation state; L is a group containing a cyclic, delocalized, anionic, pi -system through which the group is bound to M, and which group is also bound to Z; Z is a moiety bound to M via a sigma -bond, comprising boron, or a member of Group 14 of the Periodic Table of the Elements, and also comprising nitrogen, phosphorus, sulfur or oxygen, said moiety having up to 60 non-hydrogen atoms; and X is a neutral, conjugated or nonconjugated diene, optionally substituted with one or more hydrocarbyl groups, said X having up to 40 carbon atoms and forming a pi -complex with M; are catalytically activated for use as addition polymerization catalysts. Preferably, L is an optionally substituted cyclopentadienyl or fused ring cyclopentadienyl group.

Abstract translation: 所述新型钛或锆络合物含有一个且仅一个环状离域阴离子，π键合的基团，所述络合物对应于式（I），其中：M是+2形式氧化态的钛或锆; L是含有环，离域，阴离子，π-系统的基团，其中该基团与M结合，并且该基团也与Z结合; Z是通过σ键与M结合的部分，包括硼，或元素周期表第14族的成员，并且还包含氮，磷，硫或氧，所述部分具有至多60个非氢 原子; 并且X是任选被一个或多个烃基取代的中性，共轭或非共轭二烯，所述X具有至多40个碳原子并与M形成π-复合物; 被催化活化用作加成聚合催化剂。 优选地，L是任选取代的环戊二烯基或稠环环戊二烯基。

公开(公告)号：WO1993023412A1

公开(公告)日：1993-11-25

申请号：PCT/US1993003250

申请日：1993-04-07

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  NEITHAMER, David, R. ,  STEVENS, James, C.

IPC: C07F17/00

CPC classification number: C07F17/00 ,  C07F7/28 ,  C08F4/65908 ,  C08F4/6592 ,  C08F10/00 ,  Y10S526/943

Abstract: Cationic Group 4 or Lanthanide metal catalysts containing a single, delocalized PI -bonded group are prepared by contacting a metal complex with a carbonium salt of a compatible, non-coordinating anion.

Abstract translation: 通过使金属络合物与相容的非配位阴离子的碳鎓盐接触，制备含有单个离域PI键合基团的阳离子4族或镧系元素金属催化剂。

公开(公告)号：WO1997035892A1

公开(公告)日：1997-10-02

申请号：PCT/US1997003932

申请日：1997-03-12

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  SPENCER, Lee ,  VANDERLENDE, Daniel, D. ,  STEVENS, James, C.

IPC: C08F04/603

CPC classification number: C08F10/00 ,  C08F4/61908 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/6192 ,  C08F14/06 ,  C08F210/16 ,  C08F2420/02 ,  C08F2/06 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12

Abstract: A dispersible ionic catalyst activator, comprising an insoluble substrate material having a correlated settling rate less than 0.03 cm/sec, and from 0.001 to 10 mmol/g of an ionic catalyst activator deposited thereon which is particularly adapted for use in a continuous, solution polymerization process.

Abstract translation: 一种可分散的离子催化剂活化剂，其包含具有小于0.03cm / sec的相关沉降速率的不溶性底物材料和沉积在其上的离子催化剂活化剂0.001至10mmol / g，其特别适用于连续溶液聚合 处理。