公开(公告)号：WO1998003578A1

公开(公告)日：1998-01-29

申请号：PCT/US1997011401

申请日：1997-07-02

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  LUNDGARD, Richard, A. ,  BABINEC, Susan, J. ,  MUSSELL, Robert, D. ,  SEN, Ashish

IPC: C08J03/22

CPC classification number: C08J3/226 ,  C08J2423/00 ,  H01B1/24 ,  Y10S524/901

Abstract: A process for preparing an electronically-conductive thermoplastic composition having at least two phases, which includes (I) combining an amorphous or semi-crystalline thermoplastic polymer or miscible blend of polymers with an electronically-conductive carbon under conditions sufficient to disperse the conductive carbon, thereby forming a mixture having at least one phase, with at least 60 percent of the carbon dispersed in a first phase which comprises at least 90 percent by weight of the mixture; and (II) combining the mixture obtained from step (I) with an amorphous or semi-crystalline thermoplastic polymer or miscible blend of polymers, at least a portion of which is immiscible in the first phase, thereby forming a composition having at least two phases. Compositions prepared by this process are sufficiently conductive to be useful for a variety of applications, such as structural materials for applications requiring electromotively-paintable substrates.

Abstract translation: 一种制备具有至少两相的电子导电热塑性组合物的方法，其包括（I）在足以分散导电碳的条件下将非晶或半结晶热塑性聚合物或可混合的聚合物共混物与电子导电碳组合， 从而形成具有至少一相的混合物，其中至少60％的碳分散在包含至少90重量％混合物的第一相中; 和（II）将从步骤（I）获得的混合物与无定形或半结晶热塑性聚合物或可混合的聚合物混合物组合，其至少一部分在第一相中是不混溶的，由此形成具有至少两相的组合物 。 通过该方法制备的组合物具有足够的导电性，可用于各种应用，例如需要电动涂漆基材的应用的结构材料。

公开(公告)号：WO1998003560A1

公开(公告)日：1998-01-29

申请号：PCT/US1997012288

申请日：1997-07-09

Applicant: THE DOW CHEMICAL COMPANY ,  WELLER, Joseph, P. ,  WILSON, Lawrence, D. ,  ROSENAU, Michele, L. ,  JIMENEZ, Pat ,  LESCURE, Bernard, M.

Inventor： THE DOW CHEMICAL COMPANY

IPC: C08F06/00

CPC classification number: C08F6/28 ,  C08F6/001 ,  Y10S159/04 ,  Y10S159/16

Abstract: A process has been invented for removing contaminants (including solvent) from a flowing polymer, the process, in one aspect, including dissolving a sparingly soluble stripping agent into a flowing polymer, the sparingly soluble stripping agent stripping contaminants from the flowing polymer creating a mixture of contaminants and sparingly soluble stripping agent, which flows out from the flowing polymer, and separating the mixture from the polymer. In one aspect, recyclable sparingly soluble stripping agent is recovered and re-used.

Abstract translation: 已经发明了一种从流动的聚合物中除去污染物（包括溶剂）的方法，该方法在一个方面包括将微溶的汽提剂溶解在流动的聚合物中，微溶的汽提剂从流动的聚合物中汽提污染物产生混合物 的污染物和微溶的汽提剂，其从流动的聚合物流出，并将混合物与聚合物分离。 在一个方面，可回收的微溶的汽提剂被回收并重新使用。

公开(公告)号：WO1998002379A2

公开(公告)日：1998-01-22

申请号：PCT/US1997013465

申请日：1997-07-11

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  MCINTYRE, James, A. ,  PLOWMAN, Keith, R. ,  MOLL, David, J. ,  LANDON, Von, G.

IPC: C01B15/00

CPC classification number: C01B15/029 ,  B01J4/04 ,  B01J12/007 ,  B01J19/2475 ,  B01J2219/00051

Abstract: This invention is a chemical reactor and method for synthesis of hydrogen peroxide from molecular hydrogen and oxygen. The chemical reactor comprises a polymeric solution-diffusion membrane having a hydrogen contact side and an oxygen contact side and chambers for placing the relevant reactants in contact with the membrane. Conditions are provided such that a preferred flux of molecular hydrogen across the polymeric solution-diffusion membrane is at least five times greater than flux of the molecular oxygen across the membrane. The chemical reactor and method may be used to controllably synthesize hydrogen peroxide directly from molecular hydrogen and oxygen outside of the explosive range, without the use of organic solvents or complex equipment for ionic and electrical transport.

Abstract translation: 本发明是从分子氢和氧合成过氧化氢的化学反应器和方法。 化学反应器包括具有氢接触侧和氧接触侧的聚合物溶液 - 扩散膜和用于使相关反应物与膜接触的室。 提供了条件，使得跨聚合物溶液 - 扩散膜的优选的分子氢通量比通过膜的分子氧的通量高至少五倍。 化学反应器和方法可用于直接从分子氢和爆炸范围以外的氧气可控地合成过氧化氢，而不使用有机溶剂或离子和电输送的复杂设备。

公开(公告)号：WO1998001452A2

公开(公告)日：1998-01-15

申请号：PCT/US1997012016

申请日：1997-07-10

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  SHANKAR, Ravi, B. ,  ROMER, Duane, R. ,  PEWS, R., Garth

IPC: C07D513/14

CPC classification number: C07D513/14 ,  A01N43/90

Abstract: Various 5H-pyrrolo(3',4':5,6)(1,4)dithiino-(2,3-C)(1,2,5)thiadiazole-5,7(6H)-diones corresponding to formula (I) wherein R represents -H, benzyl, phenethyl, a C1-C10 straight or branched chain alkyl radical, a C3-C10-cycloalkyl radical, a C1-C10 straight or branched chain alkoxy radical, a C3-C10-cycloalkoxy, an ester of the formula -CH2CH2O-C(O)-R , wherein R represents a C1-C6 straight or branched chain alkyl radical or a C3-C6 cycloalkyl radical or R represents phenyl substituted with from 0-5 halo, C1-C6 straight or branched chain alkyl, cyano, nitro groups, or an ester of the formula -OC(O)-R , wherein R represents a C1-C6 straight or branched chain alkyl radical or a C3-C6 cycloalkyl radical or an amide of the formula -C(O)-N(R )x, wherein each R independently represents a C1-C6 straight or branched chain alkyl radical or a C3-C6 cycloalkyl radical are disclosed. These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.

Abstract translation: 对应于式（5）的各种5H-吡咯并（3'，4'：5,6）（1,4）二硫基 - （2,3-C）（1,2,5）噻二唑-5,7（6H） I）其中R表示-H，苄基，苯乙基，C1-C10直链或支链烷基，C3-C10-环烷基，C1-C10直链或支链烷氧基，C3-C10-环烷氧基， 式-CH 2 CH 2 O-C（O）-R 1的酯，其中R 1表示C 1 -C 6直链或支链烷基或C 3 -C 6环烷基，或R表示被0-5个 卤素，C 1 -C 6直链或支链烷基，氰基，硝基或式-OC（O）-R 1的酯，其中R 1表示C 1 -C 6直链或支链烷基或 C 3 -C 6环烷基或式-C（O）-N（R 2）x的酰胺，其中每个R 2独立地表示C 1 -C 6直链或支链烷基或C 3 -C 6 环烷基。 已经发现这些化合物在工业和商业应用中表现出抗微生物和海洋防污性，并且使用含有这些化合物的组合物。

公开(公告)号：WO1998000415A1

公开(公告)日：1998-01-08

申请号：PCT/US1997011417

申请日：1997-06-30

Applicant: THE DOW CHEMICAL COMPANY ,  CLARK, Howard, J. ,  MAJ, Joseph, J. ,  BOWMAN, Robert, G. ,  BARE, Simon, R. ,  HARTWELL, George, E.

Inventor： THE DOW CHEMICAL COMPANY

IPC: C07D301/10

CPC classification number: B01J23/50 ,  B01J23/52 ,  B01J23/66 ,  B01J29/89 ,  C07D301/04 ,  C07D301/10 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P20/588

Abstract: A process and catalyst for the direct oxidation of an olefin having three or more carbon atoms, such as propylene, by oxygen to an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen under reaction conditions in the presence of hydrogen and a catalyst. The catalyst comprises gold on a support of titanium dispersed on silica. The titanium phase is disorganized and substantially free of crystalline titanium dioxide, as determined by analytical methods, such as high resolution transmission electron microscopy and Raman spectroscopy. Selectivity to olefin oxide is high at good conversions of the olefin. The time between catalyst regenerations is long, and the catalyst is readily regenerated.

Abstract translation: 用于将具有三个或更多个碳原子的烯烃（例如丙烯）通过氧气直接氧化成烯烃氧化物如环氧丙烷的方法和催化剂。 该方法包括在氢气和催化剂存在下，在反应条件下使烯烃与氧接触。 该催化剂包含分散在二氧化硅上的钛载体上的金。 通过分析方法如高分辨率透射电子显微镜和拉曼光谱法测定，钛相是无组织的并且基本上不含结晶二氧化钛。 烯烃氧化物的选择性高，烯烃转化率高。 催化剂再生之间的时间长，催化剂容易再生。

公开(公告)号：WO1997045393A1

公开(公告)日：1997-12-04

申请号：PCT/US1996007694

申请日：1996-05-24

Applicant: THE DOW CHEMICAL COMPANY ,  WALTERS, Marlin, E. ,  KOLONKO, Richard, P. ,  WEHMEYER, Richard, M.

Inventor： THE DOW CHEMICAL COMPANY

IPC: C07C45/36

CPC classification number: C07C49/675

Abstract: A process for the oxidation of a fluorene compound to a corresponding fluorenone compound comprises treating the fluorene compound with an oxidizing gas in the presence of a solid alkali metal or alkaline earth metal oxide or hydroxide or a concentrated aqueous solution thereof in a reaction mixture containing a non-aqueous heterocyclic nitrogenous solvent, wherein the reaction mixture is free of a phase transfer agent, for a time sufficient and at a temperature sufficient to convert the fluorene compound to the fluorenone compound.

Abstract translation: 将芴化合物氧化成相应的芴酮化合物的方法包括在固体碱金属或碱土金属氧化物或氢氧化物或其浓缩水溶液存在下，将氧化气体中的芴化合物在含有 非水性杂环氮溶剂，其中反应混合物不含相转移剂，时间足以在足以将芴化合物转化为芴酮化合物的温度下进行。

公开(公告)号：WO1997036944A1

公开(公告)日：1997-10-09

申请号：PCT/US1997002958

申请日：1997-02-26

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  PRIDDY, Duane, B. ,  LI, Irene, Q.

IPC: C08F279/02

CPC classification number: C07D295/24 ,  C07D207/46 ,  C07D303/24 ,  C07D405/12 ,  C08F279/02 ,  C08F279/04 ,  C08F291/00 ,  C08F293/00 ,  C08F212/08

Abstract: The present invention is a free radical bulk polymerization process for producing a rubber modified polymer from a vinyl aromatic monomer comprising: polymerizing the vinyl aromatic monomer in the presence of a diene rubber having at least one stable free radical group, under polymerization conditions such that a vinyl aromatic-diene block and/or graft copolymer rubber is formed.

Abstract translation: 本发明是一种用于由乙烯基芳族单体制备橡胶改性聚合物的自由基本体聚合方法，包括：在具有至少一个稳定自由基的二烯橡胶的存在下，在聚合条件下聚合乙烯基芳族单体，使得 形成乙烯基芳族二烯嵌段和/或接枝共聚物橡胶。

公开(公告)号：WO1997036937A1

公开(公告)日：1997-10-09

申请号：PCT/US1997004247

申请日：1997-03-20

Applicant: THE DOW CHEMICAL COMPANY

Inventor： THE DOW CHEMICAL COMPANY ,  DEVORE, David, D. ,  TIMMERS, Francis, J. ,  NEITHAMER, David, R.

IPC: C08F04/603

CPC classification number: C08F10/00 ,  C08F4/61908 ,  C08F4/61916 ,  C08F4/6192 ,  C08F4/65908

Abstract: Boratabenzene cocatalysts, especially novel pentafluorophenyl boratabenzenes, are useful cocatalysts or activators with metallocenes. They are less expensive than prior art activators, are soluble and offer more irreversible reactions. Compositions comprise at least one metallocene catalyst and at least one dihydroboratabenzene or anion thereof. Processes include polymerizations with metallocenes in the presence of boratabenzene cocatalyst and activation process including bulk electrolysis techniques.

Abstract translation: 硼化物助催化剂，特别是新的五氟苯基硼苯偶氮，是具有金属茂的有用的助催化剂或活化剂。 它们比现有技术的活化剂便宜，是可溶的并且提供更多的不可逆反应。 组合物包含至少一种金属茂催化剂和至少一种二氢硼烷基或其阴离子。 方法包括在硼烷助催化剂存在下与茂金属的聚合，以及包括大量电解技术的活化方法。

公开(公告)号：WO1997036894A1

公开(公告)日：1997-10-09

申请号：PCT/US1997005098

申请日：1997-03-27

Applicant: THE DOW CHEMICAL COMPANY ,  PRIDDY, Duane, B. ,  KOBATAKE, Seiya

Inventor： THE DOW CHEMICAL COMPANY

IPC: C07D405/12

CPC classification number: C07D295/24 ,  C07D207/46 ,  C07D303/24 ,  C07D405/12 ,  C08F279/02 ,  C08F279/04 ,  C08F291/00 ,  C08F293/00 ,  C08F212/08

Abstract: The present invention is a compound of formula (I) wherein T is a group which will either 1) react with a polydienyl lithium such that the polydiene will be terminated with the compound of formula (I), or 2) be displaced by a polydienyl anion placing the molecule attached to T on the polydiene chain-end, Ar is an aromatic group having 1 or 2 aromatic rings, R, R and R are each independently hydrogen or a C1-6 alkyl group, and R , R , R , R , R and R are each independently phenyl, C1-C6 alkyl, or alternatively, 2 groups selected from R -R may combine such that a 5- or 6-membered ring containing the N of the nitroxyl group is formed.

Abstract translation: 本发明是式（I）化合物，其中T是将与聚二烯基锂反应的基团，使得聚二烯将以式（I）化合物终止，或者2）被聚二烯基 将分子与T连接在聚二烯链端上的阴离子，Ar是具有1或2个芳环的芳基，R 1，R 2和R 2各自独立地为氢或C 1-6烷基， R 3，R 4，R 5，R 6，R 7和R 8各自独立地为苯基，C 1 -C 6烷基，或者选自R 3， -R 8可以结合形成含有硝酰氧基的N的5-或6-元环。

公开(公告)号：WO1997035867A1

公开(公告)日：1997-10-02

申请号：PCT/US1997004884

申请日：1997-03-26

Applicant: THE DOW CHEMICAL COMPANY ,  THE UNIVERSITY OF MICHIGAN ,  TIMMERS, Francis, J. ,  DEVORE, David, D. ,  ASHE, Arthur, J., III ,  AL-AHMAD, Saleem, A. ,  FANG, Xinggao

Inventor： THE DOW CHEMICAL COMPANY ,  THE UNIVERSITY OF MICHIGAN

IPC: C07F17/00

CPC classification number: C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/659 ,  C08F2500/15 ,  C08F210/14

Abstract: Metal complexes, addition polymerisation catalysts containing the same and olefin polymerisation processes using the same comprising a boratabenzene group or divalent derivative thereof are disclosed.

Abstract translation: 公开了金属络合物，含有相同的加成聚合催化剂和使用包含硼代苯基或其二价衍生物的烯烃聚合方法。