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公开(公告)号:JPH04327508A
公开(公告)日:1992-11-17
申请号:JP11789791
申请日:1991-04-23
Applicant: TOSOH CORP
Inventor: AMAN SHUNJI , WATANABE HIROYUKI , TSUZUKI KENJI , TAKEMATSU TETSUO
IPC: A01N37/28
Abstract: PURPOSE:To provide an inexpensive disinfectant having a broad antifungal spectrum, usable in a safe manner, thus high in practical value, containing, as active ingredient, a specific carbazate derivative usable as an agricultural/ horticultural disinfectant. CONSTITUTION:The objective disinfectant containing, as active ingredient, a carbazate derivative of formula I (X and Y are each H, lower alkyl, lower alkoxy, halogen-substituted lower alkyl or halogen; m and n are each 1 or 2; however, when Y is lower alkyl, one of Xs is 2- or 4-substituted halogen) [e.g. 4-methoxyphenyl 3-(4-chlorophenyl)carbazate]. The present disinfectant is high in safety, also having a broad antifungal spectrum, thus being very useful. The compound of the formula I can be prepared by reaction e.g. between a compound of formula II and another compound of formula III.
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公开(公告)号:JPH0460468B2
公开(公告)日:1992-09-28
申请号:JP8135585
申请日:1985-04-18
Applicant: TOSOH CORP
Inventor: NAKANISHI AKIRA , AMAN SHUNJI , NONAKA JUJI
IPC: C07C329/14 , C07C67/00 , C07C325/00
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公开(公告)号:JP2004307839A
公开(公告)日:2004-11-04
申请号:JP2004074018
申请日:2004-03-16
Applicant: Tosoh Corp , 東ソー株式会社
Inventor: AMAN SHUNJI , IWABE KAZUHIRO , ODA YOSHIKAZU
Abstract: PROBLEM TO BE SOLVED: To provide an azeotrope-like detergent composition suitable for deterging lead-free solder flux without using a halogen-based solvent, having excellent deterging power to a smudge in a partly denatured or carbonized state because of reflowing the lead-free solder flux at a high temperature, requiring no rinsing, and capable of using even under conditions of being repeatedly recovered by distillation.
SOLUTION: This azeotrope-like detergent composition comprises 3-methoxy-3-methyl-1-butanol and at least one kind of saturated alicyclic hydrocarbons selected among methyldecalin, propylcyclohexane, ethylmethylcyclohexane, trimethylcyclohexane, butylcyclohexane, methylpropylcyclohexane, ethyldimethylcyclohexane, diethylcyclohexane, pentylcyclohexane, hexylcyclohexane and tetrahydrodicyclopentadiene.
COPYRIGHT: (C)2005,JPO&NCIPI-
公开(公告)号:JP2003105313A
公开(公告)日:2003-04-09
申请号:JP2001297991
申请日:2001-09-27
Applicant: TOSOH CORP
Inventor: SHIMIZU TOSHIKI , AMAN SHUNJI , NAGAI YASUYUKI
IPC: A62D3/34 , A62D3/37 , A62D3/38 , A62D101/22 , B09B3/00 , B09C1/02 , B09C1/08 , C02F1/70 , C02F11/00 , C07B37/06 , C07C19/045 , C07C19/05 , C07C21/073 , C07C21/10 , C09K3/00
Abstract: PROBLEM TO BE SOLVED: To provide a treatment for making a treated material which is polluted with an organohalogen compound innoxious, capable of decomposing the organohalogen compound in the soil, sludge, and an aqueous solution in a short time and therefore capable of making the treated material innoxious without generating noxious by-products. SOLUTION: This treatment is used for making the treated material which is polluted with the organohalogen compound innoxious, wherein the treatment comprises graphite and Fe, or the graphite and Fe-Ni, and contains the graphite in an amount of 1-20 wt.%.
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公开(公告)号:JP2002309229A
公开(公告)日:2002-10-23
申请号:JP2001114980
申请日:2001-04-13
Applicant: TOSOH CORP
Inventor: SHIMIZU TOSHIKI , AMAN SHUNJI , NAGAI YASUYUKI
IPC: A62D3/30 , A62D3/34 , A62D101/22 , B09C1/02 , B09C1/08 , C02F1/58 , C02F1/70 , C02F11/00 , C07B35/06 , C07B61/00 , C07C19/05 , C07C21/073 , C07C21/10 , C07C21/12 , C09K3/00 , G01N33/00 , G01N33/18
Abstract: PROBLEM TO BE SOLVED: To provide a detoxifying treatment agent for a substance and a treating method by decomposing an organic halogen compound for a short time without producing a harmful by-product and satisfying a legal restriction. SOLUTION: The detoxifying treatment agent for the substance to contaminated by the organic halogen compound comprises ion-nickel alloy powder. A nickel content of the alloy is 1-38% by weight by a measurement by an induction bonding plasma emission spectral analysis of a steel according to JIS G1258. The treating method using the detoxifying treating agent is provided.
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公开(公告)号:JP2002241735A
公开(公告)日:2002-08-28
申请号:JP2001039798
申请日:2001-02-16
Applicant: TOSOH CORP
Inventor: SHIMIZU TOSHIKI , AMAN SHUNJI
IPC: A62D3/34 , A62D3/37 , A62D101/22 , A62D101/28 , C09K3/00
Abstract: PROBLEM TO BE SOLVED: To obtain a detoxifying treatment agent capable of decomposing organohalogen compound(s) in a short time and enabling the compound(s) to be detoxifyingly treated without forming toxic byproducts, and to provide a detoxifying treatment method using the above agent. SOLUTION: The detoxifying treatment agent for object(s) to-be-treated contaminated with organohalogen compound(s) is such that the carbon content of iron powder composed of iron (Fe) and carbon (C) is 1.0-60 wt.% determined by the high-frequency induction heating oven combustion-infrared-absorbing analysis method in accordance with JIS G 1211 and the cementite (Fe3C) content of the above iron powder is >=15 wt.% determined by X-ray microanalyzer method. The detoxifying treatment method using the above agent is provided.
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公开(公告)号:JPH04178363A
公开(公告)日:1992-06-25
申请号:JP30390290
申请日:1990-11-13
Applicant: TOSOH CORP
Inventor: AMAN SHUNJI , WATANABE HIROYUKI , TSUZUKI KENJI , TAKEMATSU TETSUO
IPC: C07D249/14 , A01N47/30 , A01N47/38 , C07C275/28 , C07C275/38 , C07C275/42 , C07D211/00 , C07D213/56 , C07D231/14 , C07D233/88 , C07D239/28 , C07D241/24 , C07D263/58 , C07D277/20 , C07D277/58 , C07D277/82 , C07D285/135 , C07D295/18
Abstract: NEW MATERIAL:An urea derivative of formula I [A is NR1R2 (R1 is H, alkyl, alkoxy; R2 is alkyl, alkenyl, 4-morpholyl, phenyl, carbamoyl, 5 or 6-membered heterocyclic group or benzo-condensed group thereof, cyclic amino such as piperidyl)]. EXAMPLE:3-(5,6,7,8-Tetrahydro-1-naphthyl)-1,1-diethylurea. USE:A pest-controlling agent. PREPARATION:For example, a compound of formula II is reacted with a compound of formula III to provide the compound of formula I.
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公开(公告)号:JPH03184977A
公开(公告)日:1991-08-12
申请号:JP32257489
申请日:1989-12-14
Applicant: TOSOH CORP
Inventor: AMAN SHUNJI , KAGAWA TAKUMI , TSUZUKI KENJI
IPC: C07D405/12
Abstract: PURPOSE:To industrially obtain the subject compound useful as a herbicide by etherifying 4-(3'-chloro-5'-trifluoromethyl-2'pyridyloxy)phenol in a specific condition and esterifying in reacting with hydrogen halide, etc. CONSTITUTION:A solution of 4-(3'-chloro-5'-trifluoromethyl-2'pyridyloxy)phenol in an aromatic hydrocarbon solvent (e.g. benzene, toluene or xylene) is refluxed at a temperature of 40-80 deg.C in a reduced pressure condition and an aqueous solution dissolving (2S)-2-chloropropionic acid and a hydrogen halide-removing reagent is supplied to said refluxed solution, and simultaneously dehydrating, then a hydrogen halide and tetrahydrofurfuryl alcohol are added to the resultant reacted solution without isolation nor purification to afford optically active (2R)-tetrahydrofurfuryl 2-[4'-(3''-chloro-5''-trifluoromethyl-2''-pyridyloxy)phenoxy] propionate.
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29.
公开(公告)号:JPH02295962A
公开(公告)日:1990-12-06
申请号:JP11598489
申请日:1989-05-11
Applicant: TOSOH CORP
Inventor: TAKEMATSU TETSUO , AMAN SHUNJI , FUJIWARA MASAHISA , WATANABE HIROYUKI , TSUZUKI KENJI
IPC: A01N47/24 , C07C281/02
Abstract: NEW MATERIAL:A compound expressed by formula I (X is H, lower alkyl, etc.; Y is H, halogen, lower alkyl, etc.; Z is halogen, lower alkyl, lower alkoxy, etc.; n is 0-2; R is H or lower alkyl). EXAMPLE:2-Methylphenyl 3-phenylcarbazate. USE:A germicide for agriculture and horticulture safely usable to an useful crop such as rice or wheat. PREPARATION:According to the reaction formula, a compound expressed by formula II is reacted with a compound expressed by formula III in a solvent such as hexane or heptane or without solvent in the presence or absence of a base such as triethylamine, preferably at 0-150 deg.C, further preferably 20-100 deg.C to provide the compound expressed by formula I.
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30.
公开(公告)号:JPH02152954A
公开(公告)日:1990-06-12
申请号:JP30682088
申请日:1988-12-06
Applicant: TOSOH CORP
Inventor: TAKEMATSU TETSUO , AMAN SHUNJI , FUJIWARA MASAHISA , WATANABE HIROYUKI , TSUZUKI KENJI
IPC: C07D277/82 , A01N47/24 , C07C281/02
Abstract: NEW MATERIAL:A compound expressed by formula I [X is halogen-substituted lower alkyl, naphthyl, formula II (R1 and R2 are H, halogen or lower alkyl, provided that R1 and R2 are not simultaneously H); Y is benzothiazolyl or formula III (R3 is H, halogen or lower alkyl)]. EXAMPLE:2,2,2-Trichloroethyl 3-chloroacetyl-3-phenylcarbazate. USE:An agricultural and horticultural germicide, having germicidal power especially on molds and useful for blast of rice plant, downy mildew of cucumber, late blight of tomato, etc. PREPARATION:A carbazate derivative expressed by formula IV is reacted with chloroacetyl chloride in a solvent (e.g. dichloromethane), as necessary, using a dehydrohalogenating agent (e.g. pyridine) at 0-100 deg.C for 1-24hr to afford the compound expressed by formula I.
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